HazMat Tool

Load, Transport und Storage of Hazardous Materials
regarding U.S-Hazardous Materials Regulations (49 CFR)

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Bromine solutions  
( Comments)

Substance data

CAS-Number
:

7726-95-6

Flash Point:

n/a

Boiling Point:

59.47 ° C

Source: TOXNET (HSDB), (16.05.2014)

Data from the Hazardous Materials Table

Source: Title 49 CFR 172.101 - Hazardous Materials Table (January 2014)

(3) Hazard Class

8
Corrosive liquids

(4)
Identification number

UN 1744

(5)
Packing Group

I

More than one packing group is indicated for this entry. Criteria for assignment see 49 CFR §173 Subpart D

(6)
Labels

(8)
(6.1)

(1)
Symbols

This entry is signed with plus (+). The plus (+) sign fixes the proper shipping name, hazard class and packing group for that entry without regard to whether the material meets the definition of that class, packing group or any other hazard class definition. When the plus sign is assigned, it means that the material is known to pose a risk to humans. When a plus sign is assigned to mixtures or solutions containing a material where the hazard to humans is significantly different from that of the pure material or where no hazard to humans is posed, the material may be described using an alternative shipping name that represents the hazards posed by the material. An appropriate alternate proper shipping name and hazard class may be authorized by the Associate Administrator.

(7)
Special Provisions (§172.102)

Note:
Special provisions may be very complex. The extracts are taken from 49 CFR §172.102. Please be careful with the information, as necessary, additional conditions may be applied that are not written here. Please check the original source and report bugs.

1This material is poisonous by inhalation (see §171.8 of this subchapter) in Hazard Zone A (see §173.116(a) or §173.133(a) of this subchapter), and must be described as an inhalation hazard under the provisions of this subchapter.

Browse special provision 1

B9Bottom outlets are not authorized.

Browse special provision B9

B64see 49 CFR §172.102
B85Cargo tanks must be marked with the name of the lading in accordance with the requirements of §172.302(b).

Browse special provision B85

N34Aluminum construction materials are not authorized for any part of a packaging which is normally in contact with the hazardous material.

Browse special provision N34

N43Metal drums are permitted as single packagings only if constructed of nickel or monel.

Browse special provision N43

T22see 49 CFR §172.102
TP2a. The maximum degree of filling must not exceed the degree of filling determined by the following:

Where:
tr is the maximum mean bulk temperature during transport,
tf is the temperature in degrees celsius of the liquid during filling, and α is the mean coefficient of cubical expansion of the liquid between the mean temperature of the liquid during filling (t) and the maximum mean bulk temperature during transportation (tr) both in degrees celsius.
b. For liquids transported under ambient conditions α may be calculated using the formula:
Where:
d15 and d50 are the densities (in units of mass per unit volume) of the liquid at 15 °C (59 °F) and 50 °C (122 °F), respectively.

Browse special provision TP2

TP10The portable tank must be fitted with a lead lining at least 5 mm (0.2 inches) thick. The lead lining must be tested annually to ensure that it is intact and functional. Another suitable lining material may be used if approved by the Associate Administrator.

Browse special provision TP10

TP12This material is considered highly corrosive to steel.

Browse special provision TP12

TP13Self-contained breathing apparatus must be provided when this hazardous material is transported by sea.

Browse special provision TP13

 

(8)
Packing Authorizations (§173.***)

(8A) ExceptionsNone
(8B) Non-bulk226see 49 CFR §173.226
(8C) Bulk249see 49 CFR §173.249

(9)
Quantity Limits

(9A) Passenger aircraft/railForbidden
(9B) Cargo aircraft onlyForbidden

(10)
Vessel stowage

(10A) Location

D

Stowage category “D” means the material must be stowed “on deck only” on a cargo vessel or on a passenger vessel carrying a number of passengers limited to not more than the larger of 25 passengers or one passenger per each 3 m of overall vessel length, but the material is prohibited on a passenger vessel in which the limiting number of passengers is exceeded.

Source: 49 CFR §172.101(k)

(10B) Other
12Keep as cool as reasonably practicable.
40Stow “clear of living quarters”.
66Stow “separated from” flammable solids.
74Stow “separated from” oxidizers.
89Segregation same as for oxidizers.
90Stow “separated from” radioactive materials.

Source: 49 CFR §176.84


Bromine solutions #2  
( Comments)

Data from the Hazardous Materials Table

Source: Title 49 CFR 172.101 - Hazardous Materials Table (January 2014)

(3) Hazard Class

8
Corrosive liquids

(4)
Identification number

UN 1744

(5)
Packing Group

I

More than one packing group is indicated for this entry. Criteria for assignment see 49 CFR §173 Subpart D

(6)
Labels

(8)
(6.1)

(1)
Symbols

This entry is signed with plus (+). The plus (+) sign fixes the proper shipping name, hazard class and packing group for that entry without regard to whether the material meets the definition of that class, packing group or any other hazard class definition. When the plus sign is assigned, it means that the material is known to pose a risk to humans. When a plus sign is assigned to mixtures or solutions containing a material where the hazard to humans is significantly different from that of the pure material or where no hazard to humans is posed, the material may be described using an alternative shipping name that represents the hazards posed by the material. An appropriate alternate proper shipping name and hazard class may be authorized by the Associate Administrator.

(7)
Special Provisions (§172.102)

Note:
Special provisions may be very complex. The extracts are taken from 49 CFR §172.102. Please be careful with the information, as necessary, additional conditions may be applied that are not written here. Please check the original source and report bugs.

2This material is poisonous by inhalation (see §171.8 of this subchapter) in Hazard Zone B (see §173.116(a) or §173.133(a) of this subchapter), and must be described as an inhalation hazard under the provisions of this subchapter.

Browse special provision 2

B9Bottom outlets are not authorized.

Browse special provision B9

B64see 49 CFR §172.102
B85Cargo tanks must be marked with the name of the lading in accordance with the requirements of §172.302(b).

Browse special provision B85

N34Aluminum construction materials are not authorized for any part of a packaging which is normally in contact with the hazardous material.

Browse special provision N34

N43Metal drums are permitted as single packagings only if constructed of nickel or monel.

Browse special provision N43

T22see 49 CFR §172.102
TP2a. The maximum degree of filling must not exceed the degree of filling determined by the following:

Where:
tr is the maximum mean bulk temperature during transport,
tf is the temperature in degrees celsius of the liquid during filling, and α is the mean coefficient of cubical expansion of the liquid between the mean temperature of the liquid during filling (t) and the maximum mean bulk temperature during transportation (tr) both in degrees celsius.
b. For liquids transported under ambient conditions α may be calculated using the formula:
Where:
d15 and d50 are the densities (in units of mass per unit volume) of the liquid at 15 °C (59 °F) and 50 °C (122 °F), respectively.

Browse special provision TP2

TP10The portable tank must be fitted with a lead lining at least 5 mm (0.2 inches) thick. The lead lining must be tested annually to ensure that it is intact and functional. Another suitable lining material may be used if approved by the Associate Administrator.

Browse special provision TP10

TP12This material is considered highly corrosive to steel.

Browse special provision TP12

TP13Self-contained breathing apparatus must be provided when this hazardous material is transported by sea.

Browse special provision TP13

 

(8)
Packing Authorizations (§173.***)

(8A) ExceptionsNone
(8B) Non-bulk227see 49 CFR §173.227
(8C) Bulk249see 49 CFR §173.249

(9)
Quantity Limits

(9A) Passenger aircraft/railForbidden
(9B) Cargo aircraft onlyForbidden

(10)
Vessel stowage

(10A) Location

D

Stowage category “D” means the material must be stowed “on deck only” on a cargo vessel or on a passenger vessel carrying a number of passengers limited to not more than the larger of 25 passengers or one passenger per each 3 m of overall vessel length, but the material is prohibited on a passenger vessel in which the limiting number of passengers is exceeded.

Source: 49 CFR §172.101(k)

(10B) Other
12Keep as cool as reasonably practicable.
40Stow “clear of living quarters”.
66Stow “separated from” flammable solids.
74Stow “separated from” oxidizers.
89Segregation same as for oxidizers.
90Stow “separated from” radioactive materials.

Source: 49 CFR §176.84

Segregation and Separation Chart for Load, Transport, Storage

In this table a statement is contained for each hazard class whether the loading, transport or storage with other hazard classes is allowed, is not permitted or is restricted. The table is based on U.S.-Code 49 CFR § 177.848.

Note: In this segregation and separation chart are HazMat of hazard class 8 considered depending if there are liquid. Currently HazMat Tool is not able to to check if a HazMat is liquid or not. Therefore it is assumed as liquid. See PHMSA Interpretation #09-0252.

Hazard Class
8
7
6.1
5.2
5.1
4.3
4.2
4.1
3
2.3B
2.3A
2.2
2.1
1.6
1.5
1.4
1.3
1.1/1.2
1.1/1.2
                  
1.3
                 
1.4
                
1.5
               
1.6
              
2.1
             
2.2
            
2.3A
           
2.3B
          
3
         
4.1
        
4.2
       
4.3
      
5.1
     
5.2
    
6.1
   
7
  
8
 

  May not be loaded, transported, or stored together in the same transport vehicle or storage facility.
  Load, transport, storage together is not restricted.
  Load, transport, storage together is allowed under restrictions.










Substances with similar name

UN-NumberNameHazard Class
Bromine azideForbidden
UN 2901Bromine chloride2.3
UN 1745Bromine pentafluoride5.1
UN 1744Bromine solutions8
UN 1746Bromine trifluoride5.1

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