Allyl bromide

Allyl bromide (3-bromopropene) is an organic halide. It is an alkylating agent used in synthesis of polymers, pharmaceuticals, perfumes and other organic compounds. Allyl bromide is a colorless liquid, although commercial samples appear yellow or brown. It is an irritant and a potentially dangerous alkylating agent. Wikipedia

Substance Data

Source: TOXNET

CAS-Number

106-95-6

Flash Point

n/a

Boiling Point

n/a

Emergency Response Guide No. 131

Data from the Hazardous Materials Table

Source: 49 CFR §172 (2018/07)

(3) Hazard Class

3
Flammable liquids

(4) Identification number

UN 1099

(5) Packing Group

(6) Labels

Cargo Aircraft Only (Cargo Aircraft Only)

(7) Special Provisions (§172.102)

×Note:
Special provisions may be very complex. The extracts are taken from 49 CFR §172.102. Please be careful with the information, as necessary, additional conditions may be applied that are not written here. Please check the original source and report bugs.

T14	see 49 CFR §172.102
TP2	a. The maximum degree of filling must not exceed the degree of filling determined by the following: Where: t_r is the maximum mean bulk temperature during transport, t_f is the temperature in degrees celsius of the liquid during filling, and α is the mean coefficient of cubical expansion of the liquid between the mean temperature of the liquid during filling (t_f) and the maximum mean bulk temperature during transportation (t_r) both in degrees celsius. b. For liquids transported under ambient conditions α may be calculated using the formula: Where: d₁₅ and d₅₀ are the densities (in units of mass per unit volume) of the liquid at 15 °C (59 °F) and 50 °C (122 °F), respectively. Browse special provision TP2
TP13	Self-contained breathing apparatus must be provided when this hazardous material is transported by sea. Browse special provision TP13

(8) Packing Authorizations (§173.***)

(8A) Exceptions	None
(8B) Non-bulk	201	see 49 CFR §173.201
(8C) Bulk	243	see 49 CFR §173.243

(9) Quantity Limits

(9A) Passenger aircraft/rail	Forbidden
(9B) Cargo aircraft only	30 L

(10) Vessel stowage

(10A) Location

Stowage category “B” means

(i) The material may be stowed “on deck” or “under deck” on a cargo vessel and on a passenger vessel carrying a number of passengers limited to not more than the larger of 25 passengers, or one passenger per each 3 m of overall vessel length; and
(ii) “On deck only” on passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this section is exceeded.

Source: 49 CFR §172.101(k)

(10B) Other

40	Stow “clear of living quarters”.

Source: 49 CFR §176.84

Segregation Chart for Load, Transport, Storage

In this table a statement is contained for each hazard class whether the loading, transport or storage with other hazard classes is allowed, is not permitted or is restricted. The table is based on U.S.-Code 49 CFR §177.848.

Hazard Class	8	7	6.1	5.2	5.1	4.3	4.2	4.1	3	2.3B	2.3A	2.2	2.1	1.6	1.5	1.4	1.3	1.1/1.2
1.1/1.2
1.3
1.4
1.5
1.6
2.1
2.2
2.3A
2.3B
3
4.1
4.2
4.3
5.1
5.2
6.1
7
8

	May not be loaded, transported, or stored together in the same transport vehicle or storage facility.
	Load, transport, storage together is not restricted.
	Load, transport, storage together is allowed under restrictions.

Substances with similar name

UN-Number	Name	Hazard Class
UN 1716	Acetyl bromide	8
UN 2580	Aluminum bromide, solution	8
UN 1555	Arsenic bromide	6.1
UN 1889	Cyanogen bromide	6.1
	Diethylgold bromide	Forbidden
UN 1770	Diphenylmethyl bromide	8
UN 1891	Ethyl bromide	6.1
UN 1605	Ethylene dibromide	6.1
	Hydrobromic acid, anhydrous, see Hydrogen bromide, anhydrous
UN 1048	Hydrogen bromide, anhydrous	2.3
UN 1647	Methyl bromide and ethylene dibromide mixtures, liquid	6.1
UN 1928	Methyl magnesium bromide, in ethyl ether	4.3
	n-Butyl bromide, see 1-Bromobutane
UN 1939	Phosphorus oxybromide	8
UN 2576	Phosphorus oxybromide, molten	8
UN 2691	Phosphorus pentabromide	8
UN 1085	Vinyl bromide, stabilized	2.1
UN 3417	Xylyl bromide, solid	6.1