Ammonium arsenate

Ammonium arsenate is an inorganic compound with the formula ((NH4)3AsO4, typically encountered as a trihydrate, (NH4)3AsO4·3H2O. It is a colorless, water-soluble crystalline solid that decomposes upon heating, releasing ammonia and forming arsenic-containing residues. Classified as an IARC Group 1 carcinogen, it is highly toxic and poses significant health and environmental risks. Historically used in pesticides and analytical chemistry, its applications are now limited due to toxicity concerns. Ammonium arsenate occurs rarely in nature and is primarily synthesized for research or industrial purposes. Wikipedia

Emergency Response Guide No. 151

Data from the Hazardous Materials Table

Source: 49 CFR §172 (2018/07)

(3) Hazard Class

6.1
Poisonous Material

(4) Identification number

UN 1546

(5) Packing Group

(6) Labels

(7) Special Provisions (§172.102)

×Note:
Special provisions may be very complex. The extracts are taken from 49 CFR §172.102. Please be careful with the information, as necessary, additional conditions may be applied that are not written here. Please check the original source and report bugs.

IB8	Authorized IBCs: Metal (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B and 31N); Rigid plastics (11H1, 11H2, 21H1, 21H2, 31H1 and 31H2 ); Composite (11HZ1, 11HZ2, 21HZ1, 21HZ2 and 31HZ1); Fiberboard (11G); Wooden (11C, 11D and 11F); Flexible (13H1, 13H2, 13H3, 13H4, 13H5, 13L1, 13L2, 13L3, 13L4, 13M1 or 13M2). Browse special provision IB8
IP2	When IBCs other than metal or rigid plastics IBCs are used, they must be offered for transportation in a closed freight container or a closed transport vehicle. Browse special provision IP2
IP4	Flexible, fiberboard or wooden IBCs must be sift-proof and water-resistant or be fitted with a sift-proof and water-resistant liner. Browse special provision IP4
T3	see 49 CFR §172.102
TP33	The portable tank instruction assigned for this substance applies for granular and powdered solids and for solids which are filled and discharged at temperatures above their melting point which are cooled and transported as a solid mass. Solid substances transported or offered for transport above their melting point are authorized for transportation in portable tanks conforming to the provisions of portable tank instruction T4 for solid substances of packing group III or T7 for solid substances of packing group II, unless a tank with more stringent requirements for minimum shell thickness, maximum allowable working pressure, pressure-relief devices or bottom outlets are assigned in which case the more stringent tank instruction and special provisions shall apply. Filling limits must be in accordance with portable tank special provision TP3. Solids meeting the definition of an elevated temperature material must be transported in accordance with the applicable requirements of this subchapter. Browse special provision TP33

(8) Packing Authorizations (§173.***)

(8A) Exceptions	153	see 49 CFR §173.153
(8B) Non-bulk	212	see 49 CFR §173.212
(8C) Bulk	242	see 49 CFR §173.242

(9) Quantity Limits

(9A) Passenger aircraft/rail	25 kg
(9B) Cargo aircraft only	100 kg

(10) Vessel stowage

(10A) Location

Stowage category “A” means the material may be stowed “on deck” or “under deck” on a cargo vessel or on a passenger vessel.

Source: 49 CFR §172.101(k)

(10B) Other

53	Stow “separated from” alkaline compounds.²

² Class 8 materials in PG II or III that otherwise are required to be segregated from one another may be transported in the same cargo transport unit, whether in the same packaging or not, provided the substances do not react dangerously with each other to cause combustion and/or evolution of considerable heat, or of flammable, toxic or asphyxiant gases, or the formation of corrosive or unstable substances; and the package does not contain more than 30 L (7.8 gallons) for liquids or 30 kg (66 lbs.) for solids.

Source: 49 CFR §176.84

Segregation Chart for Load, Transport, Storage

In this table a statement is contained for each hazard class whether the loading, transport or storage with other hazard classes is allowed, is not permitted or is restricted. The table is based on U.S.-Code 49 CFR §177.848.

Note: The HMR prohibit only those Division 6.1 liquids that meet the definition of a Packing Group (PG) I and Hazard Zone A. See special provision 1 and PHMSA Interpretation #09-0252.

Packages with POISON or POISON INHALATION HAZARD labels, or a POISON label displaying “PG III,” or “PG III” marked next to a POISON label may not be transported with foodstuffs, feed or any other edible material, intended for humans or animals. For exceptions see 49 CFR §177.841(e).

There are no restrictions with hazardous materials, as pointed out in the instructions for using the Segregation Table (see 49 CFR §177.848(e)). But please, refer to following requirements in 49 CFR §177 Subpart B (Loading and Unloading):

§177.834 - General requirements
§177.835 - Class 1 materials
§177.837 - Class 3 materials
§177.838 - Class 4 (flammable solid) materials, Class 5 (oxidizing) materials, and Division 4.2 (pyroforic liquid) materials.
§177.839 - Class 8 (corrosive) materials
§177.840 - Class 2 (gases) materials
§177.841 - Division 6.1 and Division 2.3 materials
§177.842 - Class 7 (radioactive) material
§177.843 - Contamination of vehicles.

Substances with similar name

UN-Number	Name	Hazard Class
	Ammonium bifluoride solution, see Ammonium hydrogen difluoride, solution
UN 1439	Ammonium dichromate	5.1
UN 1843	Ammonium dinitro-o-cresolate, solid	6.1
UN 2854	Ammonium fluorosilicate	6.1
	Ammonium fulminate	Forbidden
UN 1727	Ammonium hydrogendifluoride, solid	8
	Ammonium hydrosulfide, solution, see Ammonium sulfide solution
UN 2426	Ammonium nitrate, liquid (hot concentrated solution)	5.1
UN 0222	Ammonium nitrate, with more than 0.2 percent combustible substances, including any organic substance calculated as carbon, to the exclusion of any other added substance	1.1D
UN 1942	Ammonium nitrate, with not more than 0.2% combustible substances, including any organic substance calculated as carbon, to the exclusion of any other added substance	5.1
NA 0331	Ammonium nitrate-fuel oil mixture containing only prilled ammonium nitrate and fuel oil	1.5D
UN 2067	Ammonium nitrate based fertilizer	5.1
UN 3375	Ammonium nitrate emulsion or Ammonium nitrate suspension or Ammonium nitrate gel, intermediate for blasting explosives	5.1
UN 0402	Ammonium perchlorate	1.1D
UN 1310	Ammonium picrate, wetted with not less than 10 percent water, by mass	4.1
UN 2818	Ammonium polysulfide, solution	8
	Di-(beta-nitroxyethyl) ammonium nitrate	Forbidden
UN 2687	Dicyclohexylammonium nitrite	4.1
UN 1630	Mercury ammonium chloride	6.1
UN 2863	Sodium ammonium vanadate	6.1
	Tetraethylammonium perchlorate (dry)	Forbidden
UN 1835	Tetramethylammonium hydroxide solution	8
UN 1512	Zinc ammonium nitrite	5.1