Calcium carbide
HMT 15 June 2026Calcium carbide
Calcium carbide, also known as calcium acetylide, is a chemical compound with the chemical formula of CaC2. Its main use industrially is in the production of acetylene and calcium cyanamide. The pure material is colorless, while pieces of technical-grade calcium carbide are grey or brown and consist of about 80–85% of CaC2 (the rest is CaO (calcium oxide), Ca3P2 (calcium phosphide), CaS (calcium sulfide), Ca3N2 (calcium nitride), SiC (silicon carbide), C (carbon), etc.). In the presence of trace moisture, technical-grade calcium carbide emits an unpleasant odor reminiscent of garlic. Applications of calcium carbide include manufacture of acetylene gas, generation of acetylene in carbide lamps, manufacture of chemicals for fertilizer, and steelmaking Wikipedia
Substance Data
Source: PubChem (HSDB, 06.12.2019)CAS-Number75-20-7 |
Flash Point— | Boiling Point— |
| Emergency Response Guide No. 138 |
Hazardous Materials Table
Source: 49 CFR §172 (15 June 2026)(3) Hazard class4.3Dangerous when wet materials |
(4) Identification number |
(5) Packing Group |
||||||||||||||||||||||
(6) Labels |
||||||||||||||||||||||||
(7) Special Provisions (§172.102)
|
||||||||||||||||||||||||
| A1 | |
|---|---|
| A8 | |
| B55 | |
| B59 | |
| IB4 | |
| IP1 | |
| N34 | |
| T9 | |
| TP7 | |
| TP33 | |
| W31 |
(8) Packing Authorizations (§173.***) 
| (8A) Exceptions | None | |
|---|---|---|
| (8B) Non-bulk | 211 | see 49 CFR §173.211 |
| (8C) Bulk | 242 | see 49 CFR §173.242 |
(9) Quantity Limits 
| (9A) Passenger aircraft/rail | Forbidden |
|---|---|
| (9B) Cargo aircraft only | 15 kg |
(10) Vessel stowage 
| (10A) Location | |
|---|---|
| (10B) Other |
(3) Hazard class4.3Dangerous when wet materials |
(4) Identification number |
(5) Packing Group |
||||||||||||||||||||||||
(6) Labels |
||||||||||||||||||||||||||
(7) Special Provisions (§172.102)
|
||||||||||||||||||||||||||
| A1 | |
|---|---|
| A8 | |
| B55 | |
| B59 | |
| IB7 | |
| IP2 | |
| IP21 | |
| N34 | |
| T3 | |
| TP33 | |
| W31 | |
| W40 |
(8) Packing Authorizations (§173.***) 
| (8A) Exceptions | 151 | see 49 CFR §173.151 |
|---|---|---|
| (8B) Non-bulk | 212 | see 49 CFR §173.212 |
| (8C) Bulk | 241 | see 49 CFR §173.241 |
(9) Quantity Limits 
| (9A) Passenger aircraft/rail | 15 kg |
|---|---|
| (9B) Cargo aircraft only | 50 kg |
(10) Vessel stowage 
| (10A) Location | |
|---|---|
| (10B) Other |
(3) Hazard class4.3Dangerous when wet materials |
(4) Identification number |
(5) Packing Group |
||||||||||||||
(6) Labels |
||||||||||||||||
(7) Special Provisions (§172.102)
|
||||||||||||||||
| A1 | |
|---|---|
| A19 | |
| IB8 | |
| IP4 | |
| T1 | |
| TP33 | |
| W31 |
(8) Packing Authorizations (§173.***) 
| (8A) Exceptions | 151 | see 49 CFR §173.151 |
|---|---|---|
| (8B) Non-bulk | 213 | see 49 CFR §173.213 |
| (8C) Bulk | 241 | see 49 CFR §173.241 |
(9) Quantity Limits 
| (9A) Passenger aircraft/rail | 25 kg |
|---|---|
| (9B) Cargo aircraft only | 100 kg |
(10) Vessel stowage 
| (10A) Location | |
|---|---|
| (10B) Other |
Packing group comparison
Multiple packing groups apply to this entry. See assignment criteria in 49 CFR §173 Subpart D. Details are in the tabs above; differences are highlighted.
| PG I | PG II | PG III | |
|---|---|---|---|
| 1 | |||
| 2 | Calcium carbide | Calcium carbide | Calcium cyanamide with more than 0.1 percent of calcium carbide |
| 3 | 4.3 | 4.3 | 4.3 |
| 4 | UN 1402 | UN 1402 | UN 1403 |
| 5 | I | II | III |
| 6 | 4.3 | 4.3 | 4.3 |
| 7 | A1, A8, B55, B59, IB4, IP1, N34, T9, TP7, TP33, W31 | A1, A8, B55, B59, IB7, IP2, IP21, N34, T3, TP33, W31, W40 | A1, A19, IB8, IP4, T1, TP33, W31 |
| 8A | None | 151 | 151 |
| 8B | 211 | 212 | 213 |
| 8C | 242 | 241 | 241 |
| 9A | Forbidden | 15 kg | 25 kg |
| 9B | 15 kg | 50 kg | 100 kg |
| 10A | B | B | A |
| 10B | 13, 52, 148 | 13, 52, 148 | 13, 52, 148 |
Segregation chart for load, transport, and storage
This chart shows whether loading, transport, or storage with other hazard classes is permitted, prohibited, or restricted. Based on 49 CFR §177.848.
| Hazard class | 8![]() | 7![]() | 6.1![]() | 5.2![]() | 5.1![]() | 4.3![]() | 4.2![]() | 4.1![]() | 3![]() | 2.3B![]() | 2.3A![]() | 2.2![]() | 2.1![]() | 1.6![]() | 1.5![]() | 1.4![]() | 1.3![]() | 1.1/1.2![]() |
1.1/1.2 ![]() | ||||||||||||||||||
1.3 ![]() | ||||||||||||||||||
1.4 ![]() | ||||||||||||||||||
1.5 ![]() | ||||||||||||||||||
1.6 ![]() | ||||||||||||||||||
2.1 ![]() | ||||||||||||||||||
2.2 ![]() | ||||||||||||||||||
2.3A ![]() | ||||||||||||||||||
2.3B ![]() | ||||||||||||||||||
3 ![]() | ||||||||||||||||||
4.1 ![]() | ||||||||||||||||||
4.2 ![]() | ||||||||||||||||||
4.3 ![]() | ||||||||||||||||||
5.1 ![]() | ||||||||||||||||||
5.2 ![]() | ||||||||||||||||||
6.1 ![]() | ||||||||||||||||||
7 ![]() | ||||||||||||||||||
8 ![]() |
| Must not be loaded, transported, or stored together in the same vehicle or facility. | |
| May be loaded, transported, or stored together. | |
| May be loaded, transported, or stored together only with restrictions. |