Chlorine pentafluoride

Chlorine pentafluoride is an interhalogen compound with formula ClF5. This colourless gas is a strong oxidant that was once a candidate oxidizer for rockets. The molecule adopts a square pyramidal structure with C4v symmetry, as confirmed by its high-resolution 19F NMR spectrum. It was first synthesized in 1963. Wikipedia

Emergency Response Guide No. 124

Data from the Hazardous Materials Table

Source: 49 CFR §172 (2018/07)

(3) Hazard Class

2.3
Poisonous gas

(4) Identification number

UN 2548

(5) Packing Group

n/a

(6) Labels

(7) Special Provisions (§172.102)

×Note:
Special provisions may be very complex. The extracts are taken from 49 CFR §172.102. Please be careful with the information, as necessary, additional conditions may be applied that are not written here. Please check the original source and report bugs.

1	This material is poisonous by inhalation (see §171.8 of this subchapter) in Hazard Zone A (see §173.116(a) or §173.133(a) of this subchapter), and must be described as an inhalation hazard under the provisions of this subchapter. Browse special provision 1
B7	Safety relief devices are not authorized on multi-unit tank car tanks. Openings for safety relief devices on multi-unit tank car tanks shall be plugged or blank flanged. Browse special provision B7
B9	Bottom outlets are not authorized. Browse special provision B9
B14	Each bulk packaging, except a tank car or a multi-unit-tank car tank, must be insulated with an insulating material so that the overall thermal conductance at 15.5 °C (60 °F) is no more than 1.5333 kilojoules per hour per square meter per degree Celsius (0.075 Btu per hour per square foot per degree Fahrenheit) temperature differential. Insulating materials must not promote corrosion to steel when wet. Browse special provision B14
N86	UN pressure receptacles made of aluminum alloy are not authorized. Browse special provision N86

(8) Packing Authorizations (§173.***)

(8A) Exceptions	None
(8B) Non-bulk	304	see 49 CFR §173.304
(8C) Bulk	314	see 49 CFR §173.314

(9) Quantity Limits

(9A) Passenger aircraft/rail	Forbidden
(9B) Cargo aircraft only	Forbidden

(10) Vessel stowage

(10A) Location

Stowage category “D” means the material must be stowed “on deck only” on a cargo vessel or on a passenger vessel carrying a number of passengers limited to not more than the larger of 25 passengers or one passenger per each 3 m of overall vessel length, but the material is prohibited on a passenger vessel in which the limiting number of passengers is exceeded.

Source: 49 CFR §172.101(k)

(10B) Other

40	Stow “clear of living quarters”.
89	Segregation same as for oxidizers.
90	Stow “separated from” radioactive materials.

Source: 49 CFR §176.84

Segregation Chart for Load, Transport, Storage

In this table a statement is contained for each hazard class whether the loading, transport or storage with other hazard classes is allowed, is not permitted or is restricted. The table is based on U.S.-Code 49 CFR §177.848.

Note: In this segregation and separation chart are HazMat of hazard class 2.3 considered depending on their poisonousness by inhalation (Hazard zone A). See special provision 1 and PHMSA Interpretation #09-0252.

Hazard Class	8	7	6.1	5.2	5.1	4.3	4.2	4.1	3	2.3B	2.3A	2.2	2.1	1.6	1.5	1.4	1.3	1.1/1.2
1.1/1.2
1.3
1.4
1.5
1.6
2.1
2.2
2.3A
2.3B
3
4.1
4.2
4.3
5.1
5.2
6.1
7
8

	May not be loaded, transported, or stored together in the same transport vehicle or storage facility.
	Load, transport, storage together is not restricted.
	Load, transport, storage together is allowed under restrictions.

Substances with similar name

UN-Number	Name	Hazard Class
UN 3485	Calcium hypochlorite, dry, corrosive or Calcium hypochlorite mixture, dry, corrosive with more than 39% available chlorine (8.8% available oxygen)	5.1
UN 1748	Calcium hypochlorite, dry or Calcium hypochlorite mixture dry with more than 39% available chlorine (8.8% available oxygen)	5.1
UN 3486	Calcium hypochlorite mixture, dry, corrosive with more than 10% but not more than 39% available chlorine	5.1
UN 2208	Calcium hypochlorite mixture, dry, with more than 10% but not more than 39% available chlorine	5.1
UN 1017	Chlorine	2.3
UN 3520	Chlorine, adsorbed	2.3
	Chlorine azide	Forbidden
	Chlorine dioxide (not hydrate)	Forbidden
NA 9191	Chlorine dioxide, hydrate, frozen	5.1
UN 2548	Chlorine pentafluoride	2.3
UN 1749	Chlorine trifluoride	2.3
UN 2996	Organochlorine pesticides, liquid, toxic	6.1
UN 2995	Organochlorine pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C	6.1
UN 2761	Organochlorine pesticides, solid, toxic	6.1
UN 2762	Organochlorine pesticides liquid, flammable, toxic, flash point less than 23 degrees C	3
	Trichloro-s-triazinetrione dry, with more than 39 percent available chlorine, see Trichloroisocyanuric acid, dry