Liquefied gas, toxic, corrosive, n.o.s. Inhalation Hazard Zone C

Liquefied gas (sometimes referred to as liquid gas) is a gas that has been turned into a liquid by cooling or compressing it. Examples of liquefied gases include liquid air, liquefied natural gas, and liquefied petroleum gas. Wikipedia

Emergency Response Guide No. 123

Data from the Hazardous Materials Table

Source: 49 CFR §172 (2018/07)

(3) Hazard Class

2.3
Poisonous gas

(4) Identification number

UN 3308

(5) Packing Group

n/a

(6) Labels

(1) Symbols

This entry is signed with "G". The letter "G" identifies proper shipping names for which one or more technical names of the hazardous material must be entered in parentheses, in association with the basic description. (See §172.203(k)).
This entry is signed with "I". The letter "I" identifies proper shipping names which are appropriate for describing materials in international transportation. An alternate proper shipping name may be selected when only domestic transportation is involved.

(7) Special Provisions (§172.102)

×Note:
Special provisions may be very complex. The extracts are taken from 49 CFR §172.102. Please be careful with the information, as necessary, additional conditions may be applied that are not written here. Please check the original source and report bugs.

3	This material is poisonous by inhalation (see §171.8 of this subchapter) in Hazard Zone C (see §173.116(a) of this subchapter), and must be described as an inhalation hazard under the provisions of this subchapter. Browse special provision 3
B14	Each bulk packaging, except a tank car or a multi-unit-tank car tank, must be insulated with an insulating material so that the overall thermal conductance at 15.5 °C (60 °F) is no more than 1.5333 kilojoules per hour per square meter per degree Celsius (0.075 Btu per hour per square foot per degree Fahrenheit) temperature differential. Insulating materials must not promote corrosion to steel when wet. Browse special provision B14

(8) Packing Authorizations (§173.***)

(8A) Exceptions	None
(8B) Non-bulk	304	see 49 CFR §173.304
(8C) Bulk	314, 315	see 49 CFR §173.314, 315

(9) Quantity Limits

(9A) Passenger aircraft/rail	Forbidden
(9B) Cargo aircraft only	Forbidden

(10) Vessel stowage

(10A) Location

Stowage category “D” means the material must be stowed “on deck only” on a cargo vessel or on a passenger vessel carrying a number of passengers limited to not more than the larger of 25 passengers or one passenger per each 3 m of overall vessel length, but the material is prohibited on a passenger vessel in which the limiting number of passengers is exceeded.

Source: 49 CFR §172.101(k)

(10B) Other

40	Stow “clear of living quarters”.

Source: 49 CFR §176.84

Segregation Chart for Load, Transport, Storage

In this table a statement is contained for each hazard class whether the loading, transport or storage with other hazard classes is allowed, is not permitted or is restricted. The table is based on U.S.-Code 49 CFR §177.848.

Note: In this segregation and separation chart are HazMat of hazard class 2.3 considered depending on their poisonousness by inhalation (Hazard zone A/B). See PHMSA Interpretation #09-0252.

There are no restrictions with hazardous materials, as pointed out in the instructions for using the Segregation Table (see 49 CFR §177.848(e)). But please, refer to following requirements in 49 CFR §177 Subpart B (Loading and Unloading):

§177.834 - General requirements
§177.835 - Class 1 materials
§177.837 - Class 3 materials
§177.838 - Class 4 (flammable solid) materials, Class 5 (oxidizing) materials, and Division 4.2 (pyroforic liquid) materials.
§177.839 - Class 8 (corrosive) materials
§177.840 - Class 2 (gases) materials
§177.841 - Division 6.1 and Division 2.3 materials
§177.842 - Class 7 (radioactive) material
§177.843 - Contamination of vehicles.

Substances with similar name

UN-Number	Name	Hazard Class
UN 3512	Adsorbed gas, toxic, n.o.s. Inhalation hazard zone A	2.3
UN 3304	Compressed gas, toxic, corrosive, n.o.s. Inhalation Hazard Zone A	2.3
UN 3305	Compressed gas, toxic, flammable, corrosive, n.o.s. Inhalation Hazard Zone A	2.3
UN 1955	Compressed gas, toxic, n.o.s. Inhalation Hazard Zone A	2.3
UN 3306	Compressed gas, toxic, oxdizing, corrosive, n.o.s. Inhalation Hazard Zone A	2.3
UN 3355	Insecticide gases, toxic, flammable, n.o.s. Inhalation hazard Zone A	2.3
UN 3308	Liquefied gas, toxic, corrosive, n.o.s. Inhalation Hazard Zone A	2.3
UN 3162	Liquefied gas, toxic, n.o.s. Inhalation Hazard Zone A	2.3
UN 3309	Liquefied gas toxic, flammable, corrosive, n.o.s. Inhalation Hazard Zone B	2.3
UN 3390	Toxic by inhalation liquid, corrosive, n.o.s. with an LC50 lower than or equal to 1000 ml/m3 and saturated vapor concentration greater than or equal to 10 LC50	6.1
UN 3489	Toxic by inhalation liquid, flammable, corrosive, n.o.s. with an LC50 lower than or equal to 1000 ml/m3 and saturated vapor concentration greater than or equal to 10 LC50	6.1
UN 3382	Toxic by inhalation liquid, n.o.s. with an LC50 lower than or equal to 1000 ml/m3 and saturated vapor concentration greater than or equal to 10 LC50	6.1
UN 3490	Toxic by inhalation liquid, water-reactive, flammable, n.o.s. with an LC50 lower than or equal to 200 ml/m3 and saturated vapor concentration greater than or equal to 500 LC50	6.1
UN 3386	Toxic by inhalation liquid, water-reactive, n.o.s. with an LC50 lower than or equal to 1000 ml/m3 and saturated vapor concentration greater than or equal to 10 LC50	6.1