Pesticides, liquid, flammable, toxic, flash point less than 23 degrees C

Data from the Hazardous Materials Table

Source: 49 CFR §172 (2018/07)

Packing Group I
Packing Group II

(3) Hazard Class

This entry is signed with "G". The letter "G" identifies proper shipping names for which one or more technical names of the hazardous material must be entered in parentheses, in association with the basic description. (See §172.203(k)).

(7) Special Provisions (§172.102)

×Note:
Special provisions may be very complex. The extracts are taken from 49 CFR §172.102. Please be careful with the information, as necessary, additional conditions may be applied that are not written here. Please check the original source and report bugs.

B5	Only ammonium nitrate solutions with 35 percent or less water that will remain completely in solution under all conditions of transport at a maximum lading temperature of 116 °C (240 °F) are authorized for transport in the following bulk packagings: MC 307, MC 312, DOT 407 and DOT 412 cargo tanks with at least 172 kPa (25 psig) design pressure. The packaging shall be designed for a working temperature of at least 121 °C (250 °F). Only Specifications MC 304, MC 307 or DOT 407 cargo tank motor vehicles are authorized for transportation by vessel. Browse special provision B5
T14	see 49 CFR §172.102
TP2	a. The maximum degree of filling must not exceed the degree of filling determined by the following: Where: t_r is the maximum mean bulk temperature during transport, t_f is the temperature in degrees celsius of the liquid during filling, and α is the mean coefficient of cubical expansion of the liquid between the mean temperature of the liquid during filling (t_f) and the maximum mean bulk temperature during transportation (t_r) both in degrees celsius. b. For liquids transported under ambient conditions α may be calculated using the formula: Where: d₁₅ and d₅₀ are the densities (in units of mass per unit volume) of the liquid at 15 °C (59 °F) and 50 °C (122 °F), respectively. Browse special provision TP2
TP13	Self-contained breathing apparatus must be provided when this hazardous material is transported by sea. Browse special provision TP13
TP27	A portable tank having a minimum test pressure of 4 bar (400 kPa) may be used provided the calculated test pressure is 4 bar or less based on the MAWP of the hazardous material, as defined in §178.275 of this subchapter, where the test pressure is 1.5 times the MAWP. Browse special provision TP27

(8) Packing Authorizations (§173.***)

(8A) Exceptions	None
(8B) Non-bulk	201	see 49 CFR §173.201
(8C) Bulk	243	see 49 CFR §173.243

(9) Quantity Limits

(9A) Passenger aircraft/rail	Forbidden
(9B) Cargo aircraft only	30 L

(10) Vessel stowage

(10A) Location

Stowage category “B” means

(i) The material may be stowed “on deck” or “under deck” on a cargo vessel and on a passenger vessel carrying a number of passengers limited to not more than the larger of 25 passengers, or one passenger per each 3 m of overall vessel length; and
(ii) “On deck only” on passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this section is exceeded.

Source: 49 CFR §172.101(k)

(10B) Other

40	Stow “clear of living quarters”.

Source: 49 CFR §176.84

(3) Hazard Class

3
Flammable liquids

(4) Identification number

UN 3021

(5) Packing Group

Comparison View of PG

(6) Labels

(1) Symbols

(7) Special Provisions (§172.102)

IB2	Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 [deg]C (1.1 bar at 122 [deg]F), or 130 kPa at 55 [deg]C (1.3 bar at 131 [deg]F) are authorized. Browse special provision IB2
T11	see 49 CFR §172.102
TP2	a. The maximum degree of filling must not exceed the degree of filling determined by the following: Where: t_r is the maximum mean bulk temperature during transport, t_f is the temperature in degrees celsius of the liquid during filling, and α is the mean coefficient of cubical expansion of the liquid between the mean temperature of the liquid during filling (t_f) and the maximum mean bulk temperature during transportation (t_r) both in degrees celsius. b. For liquids transported under ambient conditions α may be calculated using the formula: Where: d₁₅ and d₅₀ are the densities (in units of mass per unit volume) of the liquid at 15 °C (59 °F) and 50 °C (122 °F), respectively. Browse special provision TP2
TP13	Self-contained breathing apparatus must be provided when this hazardous material is transported by sea. Browse special provision TP13
TP27	A portable tank having a minimum test pressure of 4 bar (400 kPa) may be used provided the calculated test pressure is 4 bar or less based on the MAWP of the hazardous material, as defined in §178.275 of this subchapter, where the test pressure is 1.5 times the MAWP. Browse special provision TP27

(8) Packing Authorizations (§173.***)

(8A) Exceptions	150	see 49 CFR §173.150
(8B) Non-bulk	202	see 49 CFR §173.202
(8C) Bulk	243	see 49 CFR §173.243

(9) Quantity Limits

(9A) Passenger aircraft/rail	1 L
(9B) Cargo aircraft only	60 L

(10) Vessel stowage

(10A) Location

Stowage category “B” means

(i) The material may be stowed “on deck” or “under deck” on a cargo vessel and on a passenger vessel carrying a number of passengers limited to not more than the larger of 25 passengers, or one passenger per each 3 m of overall vessel length; and
(ii) “On deck only” on passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this section is exceeded.

Source: 49 CFR §172.101(k)

(10B) Other

40	Stow “clear of living quarters”.

Source: 49 CFR §176.84

Comparison View of Different Packing Groups

More than one packing group is indicated for this entry. Criteria for assignment see 49 CFR §173 Subpart D. You can find specific details in the tabs above. Differences are highlighted.

	PG I	PG II
1	G	G
2	Pesticides, liquid, flammable, toxic, flash point less than 23 degrees C	Pesticides, liquid, flammable, toxic, flash point less than 23 degrees C
3	3	3
4	UN 3021	UN 3021
5	I	II
6	3, 6.1	3, 6.1
7	B5, T14, TP2, TP13, TP27	IB2, T11, TP2, TP13, TP27
8A	None	150
8B	201	202
8C	243	243
9A	Forbidden	1 L
9B	30 L	60 L
10A	B	B
10B	40	40

Segregation Chart for Load, Transport, Storage

In this table a statement is contained for each hazard class whether the loading, transport or storage with other hazard classes is allowed, is not permitted or is restricted. The table is based on U.S.-Code 49 CFR §177.848.

Hazard Class	8	7	6.1	5.2	5.1	4.3	4.2	4.1	3	2.3B	2.3A	2.2	2.1	1.6	1.5	1.4	1.3	1.1/1.2
1.1/1.2
1.3
1.4
1.5
1.6
2.1
2.2
2.3A
2.3B
3
4.1
4.2
4.3
5.1
5.2
6.1
7
8

	May not be loaded, transported, or stored together in the same transport vehicle or storage facility.
	Load, transport, storage together is not restricted.
	Load, transport, storage together is allowed under restrictions.

Substances with similar name

UN-Number	Name	Hazard Class
UN 3048	Aluminum phosphide pesticides	6.1
UN 2776	Copper based pesticides, liquid, flammable, toxic, flash point less than 23 degrees C	3
UN 3010	Copper based pesticides, liquid, toxic	6.1
UN 3009	Copper based pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C	6.1
UN 2775	Copper based pesticides, solid, toxic	6.1
UN 3026	Coumarin derivative pesticides, liquid, toxic	6.1
UN 3027	Coumarin derivative pesticides, solid, toxic	6.1
UN 2778	Mercury based pesticides, liquid, flammable, toxic, flash point less than 23 degrees C	3
UN 3012	Mercury based pesticides, liquid, toxic	6.1
UN 3011	Mercury based pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C	6.1
UN 2996	Organochlorine pesticides, liquid, toxic	6.1
UN 2995	Organochlorine pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C	6.1
UN 3018	Organophosphorus pesticides, liquid, toxic	6.1
UN 2783	Organophosphorus pesticides, solid, toxic	6.1
UN 2787	Organotin pesticides, liquid, flammable, toxic, flash point less than 23 degrees C	3
UN 3020	Organotin pesticides, liquid, toxic	6.1
UN 2786	Organotin pesticides, solid, toxic	6.1
UN 3021	Pesticides, liquid, flammable, toxic, flash point less than 23 degrees C	3
UN 2903	Pesticides, liquid, toxic, flammable, n.o.s. flash point not less than 23 degrees C	6.1
UN 2902	Pesticides, liquid, toxic, n.o.s.	6.1
UN 2588	Pesticides, solid, toxic, n.o.s.	6.1
UN 3348	Phenoxyacetic acid derivative pesticide, liquid, toxic	6.1
UN 3345	Phenoxyacetic acid derivative pesticide, solid, toxic	6.1
UN 3014	Substituted nitrophenol pesticides, liquid, toxic	6.1
UN 2764	Triazine pesticides, liquid, flammable, toxic, flash point less than 23 degrees C	3