Barium peroxide

Barium peroxide is an inorganic compound with the formula BaO2. This white solid (gray when impure) is one of the most common inorganic peroxides, and it was the first peroxide compound discovered. Being an oxidizer and giving a vivid green colour upon ignition (as do all barium compounds), it finds some use in fireworks; historically, it was also used as a precursor for hydrogen peroxide. Wikipedia

Substance Data

Source: TOXNET

CAS-Number

1304-29-6

Flash Point

n/a

Boiling Point

n/a

Emergency Response Guide No. 141

Data from the Hazardous Materials Table

Source: 49 CFR §172 (2018/07)

(3) Hazard Class

5.1
Oxidizers

(4) Identification number

UN 1449

(5) Packing Group

(6) Labels

(7) Special Provisions (§172.102)

×Note:
Special provisions may be very complex. The extracts are taken from 49 CFR §172.102. Please be careful with the information, as necessary, additional conditions may be applied that are not written here. Please check the original source and report bugs.

A9	For combination packagings, if plastic bags are used, they must be packed in tightly closed metal receptacles before packing in outer packagings. Browse special provision A9
IB6	Authorized IBCs: Metal (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B and 31N); Rigid plastics (11H1, 11H2, 21H1, 21H2, 31H1 and 31H2); Composite (11HZ1, 11HZ2, 21HZ1, 21HZ2 and 31HZ1). Additional Requirement: Composite IBCs 11HZ2 and 21HZ2 may not be used when the hazardous materials being transported may become liquid during transport. Browse special provision IB6
IP2	When IBCs other than metal or rigid plastics IBCs are used, they must be offered for transportation in a closed freight container or a closed transport vehicle. Browse special provision IP2
T3	see 49 CFR §172.102
TP33	The portable tank instruction assigned for this substance applies for granular and powdered solids and for solids which are filled and discharged at temperatures above their melting point which are cooled and transported as a solid mass. Solid substances transported or offered for transport above their melting point are authorized for transportation in portable tanks conforming to the provisions of portable tank instruction T4 for solid substances of packing group III or T7 for solid substances of packing group II, unless a tank with more stringent requirements for minimum shell thickness, maximum allowable working pressure, pressure-relief devices or bottom outlets are assigned in which case the more stringent tank instruction and special provisions shall apply. Filling limits must be in accordance with portable tank special provision TP3. Solids meeting the definition of an elevated temperature material must be transported in accordance with the applicable requirements of this subchapter. Browse special provision TP33
W100	see 49 CFR §172.102

(8) Packing Authorizations (§173.***)

(8A) Exceptions	152	see 49 CFR §173.152
(8B) Non-bulk	212	see 49 CFR §173.212
(8C) Bulk	242	see 49 CFR §173.242

(9) Quantity Limits

(9A) Passenger aircraft/rail	5 kg
(9B) Cargo aircraft only	25 kg

(10) Vessel stowage

(10A) Location

Stowage category “C” means the material must be stowed “on deck only” on a cargo vessel or on a passenger vessel.

Source: 49 CFR §172.101(k)

(10B) Other

13	Keep as dry as reasonably practicable.
52	Stow “separated from” acids.¹ ²
66	Stow “separated from” flammable solids.
75	Stow “separated from” permanganates.
148	see 49 CFR §176.84

¹For waste cyanides or waste cyanide mixtures or solutions, refer to §173.12(e) of this subchapter.

² Class 8 materials in PG II or III that otherwise are required to be segregated from one another may be transported in the same cargo transport unit, whether in the same packaging or not, provided the substances do not react dangerously with each other to cause combustion and/or evolution of considerable heat, or of flammable, toxic or asphyxiant gases, or the formation of corrosive or unstable substances; and the package does not contain more than 30 L (7.8 gallons) for liquids or 30 kg (66 lbs.) for solids.

Source: 49 CFR §176.84

Segregation Chart for Load, Transport, Storage

In this table a statement is contained for each hazard class whether the loading, transport or storage with other hazard classes is allowed, is not permitted or is restricted. The table is based on U.S.-Code 49 CFR §177.848.

Hazard Class	8	7	6.1	5.2	5.1	4.3	4.2	4.1	3	2.3B	2.3A	2.2	2.1	1.6	1.5	1.4	1.3	1.1/1.2
1.1/1.2
1.3
1.4
1.5
1.6
2.1
2.2
2.3A
2.3B
3
4.1
4.2
4.3
5.1
5.2
6.1
7
8

	May not be loaded, transported, or stored together in the same transport vehicle or storage facility.
	Load, transport, storage together is not restricted.
	Load, transport, storage together is allowed under restrictions.

Substances with similar name

UN-Number	Name	Hazard Class
UN 1854	Barium alloys, pyrophoric	4.2
UN 0224	Barium azide, dry or wetted with less than 50 percent water, by mass	1.1A
UN 1571	Barium azide, wetted with not less than 50 percent water, by mass	4.1
UN 2719	Barium bromate	5.1
UN 1445	Barium chlorate, solid	5.1
UN 1564	Barium compounds, n.o.s	6.1
UN 2741	Barium hypochlorite with more than 22 percent available chlorine	5.1
UN 1884	Barium oxide	6.1
UN 3406	Barium perchlorate, solution	5.1
UN 1448	Barium permanganate	5.1
UN 1449	Barium peroxide	5.1
	Barium selenate, see Selenates or Selenites