Lithium hydride

Lithium hydride is an inorganic compound with the formula LiH. This alkali metal hydride is a colorless solid, although commercial samples are grey. Characteristic of a salt-like (ionic) hydride, it has a high melting point, and it is not soluble but reactive with all protic organic solvents. It is soluble and nonreactive with certain molten salts such as lithium fluoride, lithium borohydride, and sodium hydride. Wikipedia

Substance Data

Source: TOXNET

CAS-Number

7580-67-8

Flash Point

n/a

Boiling Point

n/a

Emergency Response Guide No. 138

Data from the Hazardous Materials Table

Source: 49 CFR §172 (2018/07)

(3) Hazard Class

4.3
Dangerous when wet materials

(4) Identification number

UN 1414

(5) Packing Group

(6) Labels

Cargo Aircraft Only (Cargo Aircraft Only)

(7) Special Provisions (§172.102)

×Note:
Special provisions may be very complex. The extracts are taken from 49 CFR §172.102. Please be careful with the information, as necessary, additional conditions may be applied that are not written here. Please check the original source and report bugs.

A19	Combination packagings consisting of outer fiber drums or plywood drums, with inner plastic packagings, are not authorized for transportation by aircraft. Browse special provision A19
N40	This material is not authorized in the following packagings: a. A combination packaging consisting of a 4G fiberboard box with inner receptacles of glass or earthenware; b. A single packaging of a 4C2 sift-proof, natural wood box; or c. A composite packaging 6PG2 (glass, porcelain or stoneware receptacles within a fiberboard box). Browse special provision N40
W32	see 49 CFR §172.102

(8) Packing Authorizations (§173.***)

(8A) Exceptions	None
(8B) Non-bulk	211	see 49 CFR §173.211
(8C) Bulk	242	see 49 CFR §173.242

(9) Quantity Limits

(9A) Passenger aircraft/rail	Forbidden
(9B) Cargo aircraft only	15 kg

(10) Vessel stowage

(10A) Location

Stowage category “E” means the material may be stowed “on deck” or “under deck” on a cargo vessel or on a passenger vessel carrying a number of passengers limited to not more than the larger of 25 passengers, or one passenger per each 3 m of overall vessel length, but is prohibited from carriage on a passenger vessel in which the limiting number of passengers is exceeded.

Source: 49 CFR §172.101(k)

(10B) Other

13	Keep as dry as reasonably practicable.
52	Stow “separated from” acids.¹ ²
148	see 49 CFR §176.84

¹For waste cyanides or waste cyanide mixtures or solutions, refer to §173.12(e) of this subchapter.

² Class 8 materials in PG II or III that otherwise are required to be segregated from one another may be transported in the same cargo transport unit, whether in the same packaging or not, provided the substances do not react dangerously with each other to cause combustion and/or evolution of considerable heat, or of flammable, toxic or asphyxiant gases, or the formation of corrosive or unstable substances; and the package does not contain more than 30 L (7.8 gallons) for liquids or 30 kg (66 lbs.) for solids.

Source: 49 CFR §176.84

Segregation Chart for Load, Transport, Storage

In this table a statement is contained for each hazard class whether the loading, transport or storage with other hazard classes is allowed, is not permitted or is restricted. The table is based on U.S.-Code 49 CFR §177.848.

Hazard Class	8	7	6.1	5.2	5.1	4.3	4.2	4.1	3	2.3B	2.3A	2.2	2.1	1.6	1.5	1.4	1.3	1.1/1.2
1.1/1.2
1.3
1.4
1.5
1.6
2.1
2.2
2.3A
2.3B
3
4.1
4.2
4.3
5.1
5.2
6.1
7
8

	May not be loaded, transported, or stored together in the same transport vehicle or storage facility.
	Load, transport, storage together is not restricted.
	Load, transport, storage together is allowed under restrictions.

Substances with similar name

UN-Number	Name	Hazard Class
UN 1415	Lithium	4.3
	Lithium acetylide ethylenediamine complex, see Water reactive solid etc
UN 1410	Lithium aluminum hydride	4.3
UN 1411	Lithium aluminum hydride, ethereal	4.3
UN 1413	Lithium borohydride	4.3
UN 2830	Lithium ferrosilicon	4.3
UN 1414	Lithium hydride	4.3
UN 2805	Lithium hydride, fused solid	4.3
UN 2680	Lithium hydroxide	8
UN 2679	Lithium hydroxide, solution	8
UN 1471	Lithium hypochlorite, dry or Lithium hypochlorite mixture	5.1
UN 3480	Lithium ion batteries including lithium ion polymer batteries	9
UN 3481	Lithium ion batteries packed with equipment including lithium ion polymer batteries	9
UN 3091	Lithium metal batteries packed with equipment including lithium alloy batteries	9
UN 1472	Lithium peroxide	5.1