HazMat Tool — substance information

Thiophosphoryl chloride

HMT May 2026

UN / ID: UN 1837
Hazard class: 8
Packing group: II
ERG guide: ERG 157
Special provisions: SP A3, SP A7, SP B2, SP B8, SP B25, SP IB2, SP N34, SP T7, more…
Source: 49 CFR §172 (2026/05)

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Thiophosphoryl chloride

Thiophosphoryl chloride is an inorganic compound with the chemical formula PSCl3. It is a colorless pungent smelling liquid that fumes in air. It is synthesized from phosphorus chloride and used to thiophosphorylate organic compounds, such as to produce insecticides. Wikipedia

Substance Data

Source: PubChem

CAS-Number

3982-91-0

Flash Point

n/a

Boiling Point

n/a

Emergency Response Guide No. 157

Hazardous Materials Table

Source: 49 CFR §172 (2026/05)

(3) Hazard Class

8
Corrosive liquids

(4) Identification number

UN 1837

(5) Packing Group

(6) Labels

Cargo Aircraft Only (Cargo Aircraft Only)

(7) Special Provisions (§172.102)

×Note:
Special provisions may be very complex. The extracts are taken from 49 CFR §172.102. Please be careful with the information, as necessary, additional conditions may be applied that are not written here. Please check the original source and report bugs.

For combination packagings, if glass inner packagings (including ampoules) are used, they must be packed with absorbent material in tightly closed rigid and leakproof receptacles before packing in outer packagings.

Browse special provision A3

Steel packagings must be corrosion-resistant or have protection against corrosion.

Browse special provision A7

MC 300, MC 301, MC 302, MC 303, MC 305, and MC 306 and DOT 406 cargo tanks are not authorized.

Browse special provision B2

Packagings shall be made of nickel, stainless steel, or steel with nickel, stainless steel, lead or other suitable corrosion resistant metallic lining.

Browse special provision B8

B25

Packagings must be made from monel or nickel or monel-lined or nickel-lined steel.

Browse special provision B25

IB2

Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1).
Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 °C (1.1 bar at 122 °F), or 130 kPa at 55 °C (1.3 bar at 131 °F) are authorized.

Browse special provision IB2

N34

Aluminum construction materials are not authorized for any part of a packaging which is normally in contact with the hazardous material.

Browse special provision N34

Minimum test pressure (bar)	4
Minimum shell thickness	§ 178.274(d)(2)
Pressure-relief requirements	Normal
Bottom opening requirements	§ 178.275(d)(3)

Browse special provision T7

TP2

a. The maximum degree of filling must not exceed the degree of filling determined by the following:
TP2a

Where:
t_r is the maximum mean bulk temperature during transport,
t_f is the temperature in degrees celsius of the liquid during filling, and
α is the mean coefficient of cubical expansion of the liquid between the mean temperature of the liquid during filling (t_f) and the maximum mean bulk temperature during transportation (t_r) both in degrees celsius.
b. For liquids transported under ambient conditions α may be calculated using the formula:
TP2b

Where:
d₁₅ and d₅₀ are the densities (in units of mass per unit volume) of the liquid at 15 °C (59 °F) and 50 °C (122 °F), respectively.

Browse special provision TP2

(8) Packing Authorizations (§173.***)

(8A) Exceptions	154	see 49 CFR §173.154
(8B) Non-bulk	202	see 49 CFR §173.202
(8C) Bulk	242	see 49 CFR §173.242

(9) Quantity Limits

(9A) Passenger aircraft/rail	Forbidden
(9B) Cargo aircraft only	30 L

(10) Vessel stowage

(10A) Location

Stowage category “C” means the material must be stowed “on deck only” on a cargo vessel or on a passenger vessel.

Source: 49 CFR §172.101(k)

(10B) Other

40	see 49 CFR §176.84
53	see 49 CFR §176.84
58	see 49 CFR §176.84

Source: 49 CFR §176.84

Segregation chart for load, transport, and storage

This chart shows whether loading, transport, or storage with other hazard classes is permitted, prohibited, or restricted. Based on 49 CFR §177.848.

Note: In this segregation and separation chart are HazMat of hazard class 8 considered depending if there are liquid. Currently HazMat Tool is not able to to check if a HazMat is liquid or not. Therefore it is assumed as liquid. See PHMSA Interpretation #09-0252.

Hazard class	8	7	6.1	5.2	5.1	4.3	4.2	4.1	3	2.3B	2.3A	2.2	2.1	1.6	1.5	1.4	1.3	1.1/1.2
1.1/1.2
1.3
1.4
1.5
1.6
2.1
2.2
2.3A
2.3B
3
4.1
4.2
4.3
5.1
5.2
6.1
7
8

	Must not be loaded, transported, or stored together in the same vehicle or facility.
	May be loaded, transported, or stored together.
	May be loaded, transported, or stored together only with restrictions.

Similar substances

UN / ID	Proper shipping name	Hazard class
UN 2751	Diethylthiophosphoryl chloride	8
UN 2267	Dimethyl thiophosphoryl chloride	6.1
	Dimethyl chlorothiophosphate, see Dimethyl thiophosphoryl chloride