Toxic liquids, oxidizing, n.o.s.

Toxic or poisonous material is a material, other than a gas, known to be so toxic to humans that it presents a health hazard during transportation. More Information

Emergency Response Guide No. 142

Data from the Hazardous Materials Table

Source: 49 CFR §172 (2018/07)

Packing Group I
Packing Group II

(3) Hazard Class

6.1
Poisonous Material

This entry is signed with "G". The letter "G" identifies proper shipping names for which one or more technical names of the hazardous material must be entered in parentheses, in association with the basic description. (See §172.203(k)).

(7) Special Provisions (§172.102)

×Note:
Special provisions may be very complex. The extracts are taken from 49 CFR §172.102. Please be careful with the information, as necessary, additional conditions may be applied that are not written here. Please check the original source and report bugs.

A4	Liquids having an inhalation toxicity of Packing Group I are not permitted on aircraft. Browse special provision A4

(8) Packing Authorizations (§173.***)

(8A) Exceptions	None
(8B) Non-bulk	201	see 49 CFR §173.201
(8C) Bulk	243	see 49 CFR §173.243

(9) Quantity Limits

(9A) Passenger aircraft/rail	Forbidden
(9B) Cargo aircraft only	2.5 L

(10) Vessel stowage

(10A) Location	C Stowage category “C” means the material must be stowed “on deck only” on a cargo vessel or on a passenger vessel. Source: 49 CFR §172.101(k)
(10B) Other	n/a

(3) Hazard Class

6.1
Poisonous Material

(4) Identification number

UN 3122

(5) Packing Group

Comparison View of PG

(6) Labels

(1) Symbols

(7) Special Provisions (§172.102)

IB2	Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 [deg]C (1.1 bar at 122 [deg]F), or 130 kPa at 55 [deg]C (1.3 bar at 131 [deg]F) are authorized. Browse special provision IB2

(8) Packing Authorizations (§173.***)

(8A) Exceptions	153	see 49 CFR §173.153
(8B) Non-bulk	202	see 49 CFR §173.202
(8C) Bulk	243	see 49 CFR §173.243

(9) Quantity Limits

(9A) Passenger aircraft/rail	1 L
(9B) Cargo aircraft only	5 L

(10) Vessel stowage

(10A) Location	C Stowage category “C” means the material must be stowed “on deck only” on a cargo vessel or on a passenger vessel. Source: 49 CFR §172.101(k)
(10B) Other	n/a

Comparison View of Different Packing Groups

More than one packing group is indicated for this entry. Criteria for assignment see 49 CFR §173 Subpart D. You can find specific details in the tabs above. Differences are highlighted.

	PG I	PG II
1	G	G
2	Toxic liquids, oxidizing, n.o.s.	Toxic liquids, oxidizing, n.o.s.
3	6.1	6.1
4	UN 3122	UN 3122
5	I	II
6	6.1, 5.1	6.1, 5.1
7	A4	IB2
8A	None	153
8B	201	202
8C	243	243
9A	Forbidden	1 L
9B	2.5 L	5 L
10A	C	C
10B	n/a	n/a

Segregation Chart for Load, Transport, Storage

In this table a statement is contained for each hazard class whether the loading, transport or storage with other hazard classes is allowed, is not permitted or is restricted. The table is based on U.S.-Code 49 CFR §177.848.

Note: The HMR prohibit only those Division 6.1 liquids that meet the definition of a Packing Group (PG) I and Hazard Zone A. See special provision 1 and PHMSA Interpretation #09-0252.

Packages with POISON or POISON INHALATION HAZARD labels, or a POISON label displaying “PG III,” or “PG III” marked next to a POISON label may not be transported with foodstuffs, feed or any other edible material, intended for humans or animals. For exceptions see 49 CFR §177.841(e).

There are no restrictions with hazardous materials, as pointed out in the instructions for using the Segregation Table (see 49 CFR §177.848(e)). But please, refer to following requirements in 49 CFR §177 Subpart B (Loading and Unloading):

§177.834 - General requirements
§177.835 - Class 1 materials
§177.837 - Class 3 materials
§177.838 - Class 4 (flammable solid) materials, Class 5 (oxidizing) materials, and Division 4.2 (pyroforic liquid) materials.
§177.839 - Class 8 (corrosive) materials
§177.840 - Class 2 (gases) materials
§177.841 - Division 6.1 and Division 2.3 materials
§177.842 - Class 7 (radioactive) material
§177.843 - Contamination of vehicles.

Substances with similar name

UN-Number	Name	Hazard Class
	Chloropicrin mixture, flammable (pressure not exceeding 14.7 psia at 115 degrees F flash point below 100 degrees F) see Toxic liquids, flammable, etc
UN 2920	Corrosive liquids, flammable, n.o.s.	8
UN 1760	Corrosive liquids, n.o.s.	8
UN 2922	Corrosive liquids, toxic, n.o.s.	8
UN 3094	Corrosive liquids, water-reactive, n.o.s	8
UN 3473	Fuel cell cartridges or Fuel cell cartridges contained in equipment or Fuel cell cartridges packed with equipment, containing flammable liquids	3
	Isopentanoic acid, see Corrosive liquids, n.o.s.
UN 2845	Pyrophoric liquids, organic, n.o.s	4.2
UN 0250	Rocket motors with hypergolic liquids with or without an expelling charge	1.3L
UN 2810	Toxic, liquids, organic, n.o.s.	6.1
UN 2927	Toxic liquids, corrosive, organic, n.o.s.	6.1
	Valeric acid, see Corrosive liquids, n.o.s.
UN 2591	Xenon, refrigerated liquid (cryogenic liquids)	2.2