Vanadium compound, n.o.s

Vanadium is a chemical element with the symbol V and atomic number 23. It is a hard, silvery-grey, ductile, malleable transition metal. The elemental metal is rarely found in nature, but once isolated artificially, the formation of an oxide layer (passivation) somewhat stabilizes the free metal against further oxidation. Andrés Manuel del Río discovered compounds of vanadium in 1801 in Mexico by analyzing a new lead-bearing mineral he called "brown lead", and presumed its qualities were due to the presence of a new element, which he named erythronium (derived from "ἐρυθρόν", greek word for "red") since upon heating most of the salts turned red. Four years later, he was (erroneously) convinced by other scientists that erythronium was identical to chromium. Wikipedia

Emergency Response Guide No. 151

Data from the Hazardous Materials Table

Source: 49 CFR §172 (2018/07)

Packing Group I
Packing Group II
Packing Group III

(3) Hazard Class

6.1
Poisonous Material

(4) Identification number

UN 3285

(5) Packing Group

Comparison View of PG

(6) Labels

(1) Symbols

This entry is signed with "G". The letter "G" identifies proper shipping names for which one or more technical names of the hazardous material must be entered in parentheses, in association with the basic description. (See §172.203(k)).

(7) Special Provisions (§172.102)

×Note:
Special provisions may be very complex. The extracts are taken from 49 CFR §172.102. Please be careful with the information, as necessary, additional conditions may be applied that are not written here. Please check the original source and report bugs.

IB7	Authorized IBCs: Metal (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B and 31N); Rigid plastics (11H1, 11H2, 21H1, 21H2, 31H1 and 31H2); Composite (11HZ1, 11HZ2, 21HZ1, 21HZ2 and 31HZ1); Wooden (11C, 11D and 11F). Additional Requirement: Liners of wooden IBCs must be sift-proof. Browse special provision IB7
IP1	IBCs must be packed in closed freight containers or a closed transport vehicle. Browse special provision IP1
T6	see 49 CFR §172.102
TP33	The portable tank instruction assigned for this substance applies for granular and powdered solids and for solids which are filled and discharged at temperatures above their melting point which are cooled and transported as a solid mass. Solid substances transported or offered for transport above their melting point are authorized for transportation in portable tanks conforming to the provisions of portable tank instruction T4 for solid substances of packing group III or T7 for solid substances of packing group II, unless a tank with more stringent requirements for minimum shell thickness, maximum allowable working pressure, pressure-relief devices or bottom outlets are assigned in which case the more stringent tank instruction and special provisions shall apply. Filling limits must be in accordance with portable tank special provision TP3. Solids meeting the definition of an elevated temperature material must be transported in accordance with the applicable requirements of this subchapter. Browse special provision TP33

(8) Packing Authorizations (§173.***)

(8A) Exceptions	None
(8B) Non-bulk	211	see 49 CFR §173.211
(8C) Bulk	242	see 49 CFR §173.242

(9) Quantity Limits

(9A) Passenger aircraft/rail	5 kg
(9B) Cargo aircraft only	50 kg

(10) Vessel stowage

(10A) Location	B Stowage category “B” means (i) The material may be stowed “on deck” or “under deck” on a cargo vessel and on a passenger vessel carrying a number of passengers limited to not more than the larger of 25 passengers, or one passenger per each 3 m of overall vessel length; and (ii) “On deck only” on passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this section is exceeded. Source: 49 CFR §172.101(k)
(10B) Other	n/a

(3) Hazard Class

6.1
Poisonous Material

(4) Identification number

UN 3285

(5) Packing Group

Comparison View of PG

(6) Labels

(1) Symbols

(7) Special Provisions (§172.102)

IB8	Authorized IBCs: Metal (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B and 31N); Rigid plastics (11H1, 11H2, 21H1, 21H2, 31H1 and 31H2 ); Composite (11HZ1, 11HZ2, 21HZ1, 21HZ2 and 31HZ1); Fiberboard (11G); Wooden (11C, 11D and 11F); Flexible (13H1, 13H2, 13H3, 13H4, 13H5, 13L1, 13L2, 13L3, 13L4, 13M1 or 13M2). Browse special provision IB8
IP2	When IBCs other than metal or rigid plastics IBCs are used, they must be offered for transportation in a closed freight container or a closed transport vehicle. Browse special provision IP2
IP4	Flexible, fiberboard or wooden IBCs must be sift-proof and water-resistant or be fitted with a sift-proof and water-resistant liner. Browse special provision IP4
T3	see 49 CFR §172.102
TP33	The portable tank instruction assigned for this substance applies for granular and powdered solids and for solids which are filled and discharged at temperatures above their melting point which are cooled and transported as a solid mass. Solid substances transported or offered for transport above their melting point are authorized for transportation in portable tanks conforming to the provisions of portable tank instruction T4 for solid substances of packing group III or T7 for solid substances of packing group II, unless a tank with more stringent requirements for minimum shell thickness, maximum allowable working pressure, pressure-relief devices or bottom outlets are assigned in which case the more stringent tank instruction and special provisions shall apply. Filling limits must be in accordance with portable tank special provision TP3. Solids meeting the definition of an elevated temperature material must be transported in accordance with the applicable requirements of this subchapter. Browse special provision TP33

(8) Packing Authorizations (§173.***)

(8A) Exceptions	153	see 49 CFR §173.153
(8B) Non-bulk	212	see 49 CFR §173.212
(8C) Bulk	242	see 49 CFR §173.242

(9) Quantity Limits

(9A) Passenger aircraft/rail	25 kg
(9B) Cargo aircraft only	100 kg

(10) Vessel stowage

(10A) Location	B Stowage category “B” means (i) The material may be stowed “on deck” or “under deck” on a cargo vessel and on a passenger vessel carrying a number of passengers limited to not more than the larger of 25 passengers, or one passenger per each 3 m of overall vessel length; and (ii) “On deck only” on passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this section is exceeded. Source: 49 CFR §172.101(k)
(10B) Other	n/a

(3) Hazard Class

6.1
Poisonous Material

(4) Identification number

UN 3285

(5) Packing Group

III

Comparison View of PG

(6) Labels

(1) Symbols

(7) Special Provisions (§172.102)

IB8	Authorized IBCs: Metal (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B and 31N); Rigid plastics (11H1, 11H2, 21H1, 21H2, 31H1 and 31H2 ); Composite (11HZ1, 11HZ2, 21HZ1, 21HZ2 and 31HZ1); Fiberboard (11G); Wooden (11C, 11D and 11F); Flexible (13H1, 13H2, 13H3, 13H4, 13H5, 13L1, 13L2, 13L3, 13L4, 13M1 or 13M2). Browse special provision IB8
IP3	Flexible IBCs must be sift-proof and water- resistant or must be fitted with a sift- proof and water-resistant liner. Browse special provision IP3
T1	see 49 CFR §172.102
TP33	The portable tank instruction assigned for this substance applies for granular and powdered solids and for solids which are filled and discharged at temperatures above their melting point which are cooled and transported as a solid mass. Solid substances transported or offered for transport above their melting point are authorized for transportation in portable tanks conforming to the provisions of portable tank instruction T4 for solid substances of packing group III or T7 for solid substances of packing group II, unless a tank with more stringent requirements for minimum shell thickness, maximum allowable working pressure, pressure-relief devices or bottom outlets are assigned in which case the more stringent tank instruction and special provisions shall apply. Filling limits must be in accordance with portable tank special provision TP3. Solids meeting the definition of an elevated temperature material must be transported in accordance with the applicable requirements of this subchapter. Browse special provision TP33

(8) Packing Authorizations (§173.***)

(8A) Exceptions	153	see 49 CFR §173.153
(8B) Non-bulk	213	see 49 CFR §173.213
(8C) Bulk	240	see 49 CFR §173.240

(9) Quantity Limits

(9A) Passenger aircraft/rail	100 kg
(9B) Cargo aircraft only	200 kg

(10) Vessel stowage

(10A) Location	n/a see
(10B) Other	n/a

Comparison View of Different Packing Groups

More than one packing group is indicated for this entry. Criteria for assignment see 49 CFR §173 Subpart D. You can find specific details in the tabs above. Differences are highlighted.

	PG I	PG II	PG III
1	G	G	G
2	Vanadium compound, n.o.s	Vanadium compound, n.o.s	Vanadium compound, n.o.s
3	6.1	6.1	6.1
4	UN 3285	UN 3285	UN 3285
5	I	II	III
6	6.1	6.1	6.1
7	IB7, IP1, T6, TP33	IB8, IP2, IP4, T3, TP33	IB8, IP3, T1, TP33
8A	None	153	153
8B	211	212	213
8C	242	242	240
9A	5 kg	25 kg	100 kg
9B	50 kg	100 kg	200 kg
10A	B	B	n/a
10B	n/a	n/a	n/a

Segregation Chart for Load, Transport, Storage

In this table a statement is contained for each hazard class whether the loading, transport or storage with other hazard classes is allowed, is not permitted or is restricted. The table is based on U.S.-Code 49 CFR §177.848.

Note: The HMR prohibit only those Division 6.1 liquids that meet the definition of a Packing Group (PG) I and Hazard Zone A. See special provision 1 and PHMSA Interpretation #09-0252.

Packages with POISON or POISON INHALATION HAZARD labels, or a POISON label displaying “PG III,” or “PG III” marked next to a POISON label may not be transported with foodstuffs, feed or any other edible material, intended for humans or animals. For exceptions see 49 CFR §177.841(e).

There are no restrictions with hazardous materials, as pointed out in the instructions for using the Segregation Table (see 49 CFR §177.848(e)). But please, refer to following requirements in 49 CFR §177 Subpart B (Loading and Unloading):

§177.834 - General requirements
§177.835 - Class 1 materials
§177.837 - Class 3 materials
§177.838 - Class 4 (flammable solid) materials, Class 5 (oxidizing) materials, and Division 4.2 (pyroforic liquid) materials.
§177.839 - Class 8 (corrosive) materials
§177.840 - Class 2 (gases) materials
§177.841 - Division 6.1 and Division 2.3 materials
§177.842 - Class 7 (radioactive) material
§177.843 - Contamination of vehicles.

Substances with similar name

UN-Number	Name	Hazard Class
UN 2864	Potassium metavanadate	6.1
UN 2863	Sodium ammonium vanadate	6.1
UN 2443	Vanadium oxytrichloride	8
UN 2862	Vanadium pentoxide, non-fused form	6.1
UN 2475	Vanadium trichloride	8
UN 2931	Vanadyl sulfate	6.1