Arsenic compounds, liquid, n.o.s. inorganic, including arsenates, n.o.s.; arsenites, n.o.s.; arsenic sulfides, n.o.s.; and organic compounds of arsenic, n.o.s

Arsenic is a chemical element; it has symbol As and atomic number 33. It is a metalloid and one of the pnictogens, and therefore shares many properties with its group 15 neighbors phosphorus and antimony. Arsenic is notoriously toxic. It occurs naturally in many minerals, usually in combination with sulfur and metals, but also as a pure elemental crystal. Wikipedia

Emergency Response Guide No. 152

Data from the Hazardous Materials Table

Source: 49 CFR §172 (2018/07)

Packing Group I
Packing Group II
Packing Group III

(3) Hazard Class

6.1
Poisonous Material

(4) Identification number

UN 1556

(5) Packing Group

Comparison View of PG

(6) Labels

(1) Symbols

This entry is signed with "G". The letter "G" identifies proper shipping names for which one or more technical names of the hazardous material must be entered in parentheses, in association with the basic description. (See §172.203(k)).

(7) Special Provisions (§172.102)

×Note:
Special provisions may be very complex. The extracts are taken from 49 CFR §172.102. Please be careful with the information, as necessary, additional conditions may be applied that are not written here. Please check the original source and report bugs.

T14	see 49 CFR §172.102
TP2	a. The maximum degree of filling must not exceed the degree of filling determined by the following: Where: t_r is the maximum mean bulk temperature during transport, t_f is the temperature in degrees celsius of the liquid during filling, and α is the mean coefficient of cubical expansion of the liquid between the mean temperature of the liquid during filling (t_f) and the maximum mean bulk temperature during transportation (t_r) both in degrees celsius. b. For liquids transported under ambient conditions α may be calculated using the formula: Where: d₁₅ and d₅₀ are the densities (in units of mass per unit volume) of the liquid at 15 °C (59 °F) and 50 °C (122 °F), respectively. Browse special provision TP2
TP13	Self-contained breathing apparatus must be provided when this hazardous material is transported by sea. Browse special provision TP13
TP27	A portable tank having a minimum test pressure of 4 bar (400 kPa) may be used provided the calculated test pressure is 4 bar or less based on the MAWP of the hazardous material, as defined in §178.275 of this subchapter, where the test pressure is 1.5 times the MAWP. Browse special provision TP27

(8) Packing Authorizations (§173.***)

(8A) Exceptions	None
(8B) Non-bulk	201	see 49 CFR §173.201
(8C) Bulk	243	see 49 CFR §173.243

(9) Quantity Limits

(9A) Passenger aircraft/rail	1 L
(9B) Cargo aircraft only	30 L

(10) Vessel stowage

(10A) Location

Stowage category “B” means

(i) The material may be stowed “on deck” or “under deck” on a cargo vessel and on a passenger vessel carrying a number of passengers limited to not more than the larger of 25 passengers, or one passenger per each 3 m of overall vessel length; and
(ii) “On deck only” on passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this section is exceeded.

Source: 49 CFR §172.101(k)

(10B) Other

40	Stow “clear of living quarters”.
137	For arsenic sulphides, Stow “separated from” acids.

Source: 49 CFR §176.84

(3) Hazard Class

6.1
Poisonous Material

(4) Identification number

UN 1556

(5) Packing Group

Comparison View of PG

(6) Labels

(1) Symbols

(7) Special Provisions (§172.102)

IB2	Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 [deg]C (1.1 bar at 122 [deg]F), or 130 kPa at 55 [deg]C (1.3 bar at 131 [deg]F) are authorized. Browse special provision IB2
T11	see 49 CFR §172.102
TP2	a. The maximum degree of filling must not exceed the degree of filling determined by the following: Where: t_r is the maximum mean bulk temperature during transport, t_f is the temperature in degrees celsius of the liquid during filling, and α is the mean coefficient of cubical expansion of the liquid between the mean temperature of the liquid during filling (t_f) and the maximum mean bulk temperature during transportation (t_r) both in degrees celsius. b. For liquids transported under ambient conditions α may be calculated using the formula: Where: d₁₅ and d₅₀ are the densities (in units of mass per unit volume) of the liquid at 15 °C (59 °F) and 50 °C (122 °F), respectively. Browse special provision TP2
TP13	Self-contained breathing apparatus must be provided when this hazardous material is transported by sea. Browse special provision TP13
TP27	A portable tank having a minimum test pressure of 4 bar (400 kPa) may be used provided the calculated test pressure is 4 bar or less based on the MAWP of the hazardous material, as defined in §178.275 of this subchapter, where the test pressure is 1.5 times the MAWP. Browse special provision TP27

(8) Packing Authorizations (§173.***)

(8A) Exceptions	153	see 49 CFR §173.153
(8B) Non-bulk	202	see 49 CFR §173.202
(8C) Bulk	243	see 49 CFR §173.243

(9) Quantity Limits

(9A) Passenger aircraft/rail	5 L
(9B) Cargo aircraft only	60 L

(10) Vessel stowage

(10A) Location

Stowage category “B” means

(i) The material may be stowed “on deck” or “under deck” on a cargo vessel and on a passenger vessel carrying a number of passengers limited to not more than the larger of 25 passengers, or one passenger per each 3 m of overall vessel length; and
(ii) “On deck only” on passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this section is exceeded.

Source: 49 CFR §172.101(k)

(10B) Other

40	Stow “clear of living quarters”.
137	For arsenic sulphides, Stow “separated from” acids.

Source: 49 CFR §176.84

(3) Hazard Class

6.1
Poisonous Material

(4) Identification number

UN 1556

(5) Packing Group

III

Comparison View of PG

(6) Labels

(1) Symbols

(7) Special Provisions (§172.102)

IB3	Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1 and 31HA2, 31HB2, 31HN2, 31HD2 and 31HH2). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 [deg]C (1.1 bar at 122 [deg]F), or 130 kPa at 55 [deg]C (1.3 bar at 131 [deg]F) are authorized, except for UN2672 (also see Special Provision IP8 for UN2672). Browse special provision IB3
T7	see 49 CFR §172.102
TP2	a. The maximum degree of filling must not exceed the degree of filling determined by the following: Where: t_r is the maximum mean bulk temperature during transport, t_f is the temperature in degrees celsius of the liquid during filling, and α is the mean coefficient of cubical expansion of the liquid between the mean temperature of the liquid during filling (t_f) and the maximum mean bulk temperature during transportation (t_r) both in degrees celsius. b. For liquids transported under ambient conditions α may be calculated using the formula: Where: d₁₅ and d₅₀ are the densities (in units of mass per unit volume) of the liquid at 15 °C (59 °F) and 50 °C (122 °F), respectively. Browse special provision TP2
TP28	A portable tank having a minimum test pressure of 2.65 bar (265 kPa) may be used provided the calculated test pressure is 2.65 bar or less based on the MAWP of the hazardous material, as defined in §178.275 of this subchapter, where the test pressure is 1.5 times the MAWP. Browse special provision TP28

(8) Packing Authorizations (§173.***)

(8A) Exceptions	153	see 49 CFR §173.153
(8B) Non-bulk	203	see 49 CFR §173.203
(8C) Bulk	241	see 49 CFR §173.241

(9) Quantity Limits

(9A) Passenger aircraft/rail	60 L
(9B) Cargo aircraft only	220 L

(10) Vessel stowage

(10A) Location

Stowage category “B” means

(i) The material may be stowed “on deck” or “under deck” on a cargo vessel and on a passenger vessel carrying a number of passengers limited to not more than the larger of 25 passengers, or one passenger per each 3 m of overall vessel length; and
(ii) “On deck only” on passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this section is exceeded.

Source: 49 CFR §172.101(k)

(10B) Other

40	Stow “clear of living quarters”.
137	For arsenic sulphides, Stow “separated from” acids.

Source: 49 CFR §176.84

Comparison View of Different Packing Groups

More than one packing group is indicated for this entry. Criteria for assignment see 49 CFR §173 Subpart D. You can find specific details in the tabs above. Differences are highlighted.

	PG I	PG II	PG III
1	G	G	G
2	Arsenic compounds, liquid, n.o.s. inorganic, including arsenates, n.o.s.; arsenites, n.o.s.; arsenic sulfides, n.o.s.; and organic compounds of arsenic, n.o.s	Arsenic compounds, liquid, n.o.s. inorganic, including arsenates, n.o.s.; arsenites, n.o.s.; arsenic sulfides, n.o.s.; and organic compounds of arsenic, n.o.s	Arsenic compounds, liquid, n.o.s. inorganic, including arsenates, n.o.s.; arsenites, n.o.s.; arsenic sulfides, n.o.s.; and organic compounds of arsenic, n.o.s
3	6.1	6.1	6.1
4	UN 1556	UN 1556	UN 1556
5	I	II	III
6	6.1	6.1	6.1
7	T14, TP2, TP13, TP27	IB2, T11, TP2, TP13, TP27	IB3, T7, TP2, TP28
8A	None	153	153
8B	201	202	203
8C	243	243	241
9A	1 L	5 L	60 L
9B	30 L	60 L	220 L
10A	B	B	B
10B	40, 137	40, 137	40, 137

Segregation Chart for Load, Transport, Storage

In this table a statement is contained for each hazard class whether the loading, transport or storage with other hazard classes is allowed, is not permitted or is restricted. The table is based on U.S.-Code 49 CFR §177.848.

Note: The HMR prohibit only those Division 6.1 liquids that meet the definition of a Packing Group (PG) I and Hazard Zone A. See special provision 1 and PHMSA Interpretation #09-0252.

Packages with POISON or POISON INHALATION HAZARD labels, or a POISON label displaying “PG III,” or “PG III” marked next to a POISON label may not be transported with foodstuffs, feed or any other edible material, intended for humans or animals. For exceptions see 49 CFR §177.841(e).

There are no restrictions with hazardous materials, as pointed out in the instructions for using the Segregation Table (see 49 CFR §177.848(e)). But please, refer to following requirements in 49 CFR §177 Subpart B (Loading and Unloading):

§177.834 - General requirements
§177.835 - Class 1 materials
§177.837 - Class 3 materials
§177.838 - Class 4 (flammable solid) materials, Class 5 (oxidizing) materials, and Division 4.2 (pyroforic liquid) materials.
§177.839 - Class 8 (corrosive) materials
§177.840 - Class 2 (gases) materials
§177.841 - Division 6.1 and Division 2.3 materials
§177.842 - Class 7 (radioactive) material
§177.843 - Contamination of vehicles.

Substances with similar name

UN-Number	Name	Hazard Class
	1,3,2-Benzodioxaborole
UN 2456	2-Chloropropene	3
UN 2822	2-Chloropyridine	6.1
UN 2378	2-Dimethylaminoacetonitrile	3
UN 3302	2-Dimethylaminoethyl acrylate	6.1
UN 2276	2-Ethylhexylamine	3
UN 2390	2-Iodobutane	3
UN 3023	2-Methyl-2-heptanethiol	6.1
UN 1956	Compressed gas, n.o.s	2.2
	Consumer commodity	ORM-D
UN 1585	Copper acetoarsenite	6.1
UN 1587	Copper cyanide	6.1
	Copper tetramine nitrate	Forbidden
UN 1363	Copra	4.2
UN 0065	Cord, detonating, flexible	1.1D
UN 0066	Cord, igniter	1.4G
	Cordite, see Powder, smokeless
UN 1760	Corrosive liquids, n.o.s.	8
NA 1365	Cotton	9
UN 1365	Cotton, wet	4.2
UN 1026	Cyanogen	2.3
UN 2046	Cymenes	3
UN 1868	Decaborane	4.1
	Diazonium perchlorates (dry)	Forbidden
UN 1166	Dioxolane	3