Butyl nitrites

In organic chemistry, butyl is a four-carbon alkyl radical or substituent group with general chemical formula −C4H9, derived from either of the two isomers (n-butane and isobutane) of butane. The isomer n-butane can connect in two ways, giving rise to two "-butyl" groups: If it connects at one of the two terminal carbon atoms, it is normal butyl or n-butyl: −CH2−CH2−CH2−CH3 (preferred IUPAC name: butyl) If it connects at one of the non-terminal (internal) carbon atoms, it is secondary butyl or sec-butyl: −CH(CH3)−CH2−CH3 (preferred IUPAC name: butan-2-yl) The second isomer of butane, isobutane, can also connect in two ways, giving rise to two additional groups: If it connects at one of the three terminal carbons, it is isobutyl: −CH2−CH(CH3)2 (preferred IUPAC name: 2-methylpropyl) If it connects at the central carbon, it is tertiary butyl, tert-butyl or t-butyl: −C(CH3)3 (preferred IUPAC name: tert-butyl) Wikipedia

Hazardous Materials Table

• Packing group I
• Packing group II
• Packing group III

(3) Hazard Class 3 Flammable liquids	(4) Identification number UN 2351	(5) Packing Group I Comparison View of PG
(6) Labels
(7) Special Provisions (§172.102) ×Note: Special provisions may be very complex. The extracts are taken from 49 CFR §172.102. Please be careful with the information, as necessary, additional conditions may be applied that are not written here. Please check the original source and report bugs. T11 Minimum test pressure (bar) 6 Minimum shell thickness § 178.274(d)(2) Pressure-relief requirements Normal Bottom opening requirements § 178.275(d)(3) Browse special provision T11 TP1 The maximum degree of filling must not exceed the degree of filling determined by the following: Where: tr is the maximum mean bulk temperature during transport, and tf is the temperature in degrees celsius of the liquid during filling. Browse special provision TP1 TP8 A portable tank having a minimum test pressure of 1.5 bar (150 kPa) may be used when the flash point of the hazardous material transported is greater than 0 °C (32 °F). Browse special provision TP8 TP27 A portable tank having a minimum test pressure of 4 bar (400 kPa) may be used provided the calculated test pressure is 4 bar or less based on the MAWP of the hazardous material, as defined in § 178.275 of this subchapter, where the test pressure is 1.5 times the MAWP. Browse special provision TP27
(8) Packing Authorizations (§173.***) (8A) Exceptions 150 see 49 CFR §173.150 (8B) Non-bulk 201 see 49 CFR §173.201 (8C) Bulk 243 see 49 CFR §173.243
(9) Quantity Limits (9A) Passenger aircraft/rail 1 L (9B) Cargo aircraft only 30 L
(10) Vessel stowage (10A) Location E Stowage category “E” means the material may be stowed “on deck” or “under deck” on a cargo vessel or on a passenger vessel carrying a number of passengers limited to not more than the larger of 25 passengers, or one passenger per each 3 m of overall vessel length, but is prohibited from carriage on a passenger vessel in which the limiting number of passengers is exceeded. Source: 49 CFR §172.101(k) (10B) Other 40 see 49 CFR §176.84 Source: 49 CFR §176.84

(3) Hazard Class 3 Flammable liquids	(4) Identification number UN 2351	(5) Packing Group II Comparison View of PG
(6) Labels
(7) Special Provisions (§172.102) ×Note: Special provisions may be very complex. The extracts are taken from 49 CFR §172.102. Please be careful with the information, as necessary, additional conditions may be applied that are not written here. Please check the original source and report bugs. IB2 Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 °C (1.1 bar at 122 °F), or 130 kPa at 55 °C (1.3 bar at 131 °F) are authorized. Browse special provision IB2 T4 Minimum test pressure (bar) 2.65 Minimum shell thickness § 178.274(d)(2) Pressure-relief requirements Normal Bottom opening requirements § 178.275(d)(3) Browse special provision T4 TP1 The maximum degree of filling must not exceed the degree of filling determined by the following: Where: tr is the maximum mean bulk temperature during transport, and tf is the temperature in degrees celsius of the liquid during filling. Browse special provision TP1
(8) Packing Authorizations (§173.***) (8A) Exceptions 150 see 49 CFR §173.150 (8B) Non-bulk 202 see 49 CFR §173.202 (8C) Bulk 242 see 49 CFR §173.242
(9) Quantity Limits (9A) Passenger aircraft/rail 5 L (9B) Cargo aircraft only 60 L
(10) Vessel stowage (10A) Location B Stowage category “B” means (i) The material may be stowed “on deck” or “under deck” on a cargo vessel and on a passenger vessel carrying a number of passengers limited to not more than the larger of 25 passengers, or one passenger per each 3 m of overall vessel length; and (ii) “On deck only” on passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this section is exceeded. Source: 49 CFR §172.101(k) (10B) Other 40 see 49 CFR §176.84 Source: 49 CFR §176.84

(3) Hazard Class 3 Flammable liquids	(4) Identification number UN 2351	(5) Packing Group III Comparison View of PG
(6) Labels
(7) Special Provisions (§172.102) ×Note: Special provisions may be very complex. The extracts are taken from 49 CFR §172.102. Please be careful with the information, as necessary, additional conditions may be applied that are not written here. Please check the original source and report bugs. B1 If the material has a flash point at or above 38 °C (100 °F) and below 93 °C (200 °F), then the bulk packaging requirements of § 173.241 of this subchapter are applicable. If the material has a flash point of less than 38 °C (100 °F), then the bulk packaging requirements of § 173.242 of this subchapter are applicable. Browse special provision B1 IB3 Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1 and 31HA2, 31HB2, 31HN2, 31HD2 and 31HH2). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 °C (1.1 bar at 122 °F), or 130 kPa at 55 °C (1.3 bar at 131 °F) are authorized, except for UN2672 (also see special provision IP8 in Table 2 for UN2672). Browse special provision IB3 T2 Minimum test pressure (bar) 1.5 Minimum shell thickness § 178.274(d)(2) Pressure-relief requirements Normal Bottom opening requirements § 178.275(d)(3) Browse special provision T2 TP1 The maximum degree of filling must not exceed the degree of filling determined by the following: Where: tr is the maximum mean bulk temperature during transport, and tf is the temperature in degrees celsius of the liquid during filling. Browse special provision TP1
(8) Packing Authorizations (§173.***) (8A) Exceptions 150 see 49 CFR §173.150 (8B) Non-bulk 203 see 49 CFR §173.203 (8C) Bulk 242 see 49 CFR §173.242
(9) Quantity Limits (9A) Passenger aircraft/rail 60 L (9B) Cargo aircraft only 220 L
(10) Vessel stowage (10A) Location A Stowage category “A” means the material may be stowed “on deck” or “under deck” on a cargo vessel or on a passenger vessel. Source: 49 CFR §172.101(k) (10B) Other 40 see 49 CFR §176.84 Source: 49 CFR §176.84

Segregation chart for load, transport, and storage

This chart shows whether loading, transport, or storage with other hazard classes is permitted, prohibited, or restricted. Based on 49 CFR §177.848.

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Hazard class	8	7	6.1	5.2	5.1	4.3	4.2	4.1	3	2.3B	2.3A	2.2	2.1	1.6	1.5	1.4	1.3	1.1/1.2
1.1/1.2
1.3
1.4
1.5
1.6
2.1
2.2
2.3A
2.3B
3
4.1
4.2
4.3
5.1
5.2
6.1
7
8

	Must not be loaded, transported, or stored together in the same vehicle or facility.
	May be loaded, transported, or stored together.
	May be loaded, transported, or stored together only with restrictions.