HazMat Tool — substance information

Alkyl sulfonic acids, liquid or Aryl sulfonic acids, liquid with not more than 5 percent free sulfuric acid

HMT May 2026

UN / ID: UN 2586
Hazard class: 8
Packing group: III
ERG guide: ERG 153
Special provisions: SP IB3, SP T4, SP TP1
Source: 49 CFR §172 (2026/05)

Spot an error in this entry?

On this page

Alkyl sulfonic acids, liquid or Aryl sulfonic acids, liquid with not more than 5 percent free sulfuric acid

Emergency Response Guide No. 153

Hazardous Materials Table

Source: 49 CFR §172 (2026/05)

(3) Hazard Class

8
Corrosive liquids

(7) Special Provisions (§172.102)

×Note:
Special provisions may be very complex. The extracts are taken from 49 CFR §172.102. Please be careful with the information, as necessary, additional conditions may be applied that are not written here. Please check the original source and report bugs.

IB3

Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1 and 31HA2, 31HB2, 31HN2, 31HD2 and 31HH2).
Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 °C (1.1 bar at 122 °F), or 130 kPa at 55 °C (1.3 bar at 131 °F) are authorized, except for UN2672 (also see special provision IP8 in Table 2 for UN2672).

Browse special provision IB3

Minimum test pressure (bar)	2.65
Minimum shell thickness	§ 178.274(d)(2)
Pressure-relief requirements	Normal
Bottom opening requirements	§ 178.275(d)(3)

Browse special provision T4

TP1

The maximum degree of filling must not exceed the degree of filling determined by the following:
TP1

Where:
t_r is the maximum mean bulk temperature during transport, and t_f is the temperature in degrees celsius of the liquid during filling.

Browse special provision TP1

(8) Packing Authorizations (§173.***)

(8A) Exceptions	154	see 49 CFR §173.154
(8B) Non-bulk	203	see 49 CFR §173.203
(8C) Bulk	241	see 49 CFR §173.241

(9) Quantity Limits

(9A) Passenger aircraft/rail	5 L
(9B) Cargo aircraft only	60 L

(10) Vessel stowage

(10A) Location

Stowage category “B” means

(i) The material may be stowed “on deck” or “under deck” on a cargo vessel and on a passenger vessel carrying a number of passengers limited to not more than the larger of 25 passengers, or one passenger per each 3 m of overall vessel length; and
(ii) “On deck only” on passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this section is exceeded.

Source: 49 CFR §172.101(k)

(10B) Other

53	see 49 CFR §176.84
58	see 49 CFR §176.84

Source: 49 CFR §176.84

Segregation chart for load, transport, and storage

This chart shows whether loading, transport, or storage with other hazard classes is permitted, prohibited, or restricted. Based on 49 CFR §177.848.

Note: In this segregation and separation chart are HazMat of hazard class 8 considered depending if there are liquid. Currently HazMat Tool is not able to to check if a HazMat is liquid or not. Therefore it is assumed as liquid. See PHMSA Interpretation #09-0252.

Hazard class	8	7	6.1	5.2	5.1	4.3	4.2	4.1	3	2.3B	2.3A	2.2	2.1	1.6	1.5	1.4	1.3	1.1/1.2
1.1/1.2
1.3
1.4
1.5
1.6
2.1
2.2
2.3A
2.3B
3
4.1
4.2
4.3
5.1
5.2
6.1
7
8

	Must not be loaded, transported, or stored together in the same vehicle or facility.
	May be loaded, transported, or stored together.
	May be loaded, transported, or stored together only with restrictions.

Similar substances

UN / ID	Proper shipping name	Hazard class
UN 2585	Alkyl sulfonic acids, solid or Aryl sulfonic acids, solid with not more than 5 percent free sulfuric acid	8
UN 2583	Alkyl sulfonic acids, solid or Aryl sulfonic acids, solid, with more than 5 percent free sulfuric acid	8
UN 2584	Alkyl sulfonic acids, liquid or Aryl sulfonic acids, liquid with more than 5 percent free sulfuric acid	8
UN 1754	Chlorosulfonic acid (with or without sulfur trioxide)	8
UN 1803	Phenolsulfonic acid, liquid	8
	6-Nitro-4-diazotoluene-3-sulfonic acid (dry)	Forbidden
UN 1777	Fluorosulfonic acid	8
UN 2305	Nitrobenzenesulfonic acid	8
UN 0386	Trinitrobenzenesulfonic acid	1.1D