HazMat Tool — substance information

Pyrophoric liquid, inorganic, n.o.s

HMT 15 June 2026
Reference only — HMT snapshot for inspection and audit support; not a shipping paper, placard mandate, or CVI record. Use Print / PDF below for field notes.
UN / ID
UN 3194
Hazard class
4.2
Packing group
I
ERG guide
ERG 135
Special provisions
Source
49 CFR §172 (15 June 2026)

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Pyrophoric liquid, inorganic, n.o.s


A substance is pyrophoric (from Ancient Greek: πυροφόρος, pyrophoros, 'fire-bearing') if it ignites spontaneously in air at or below 54 °C (129 °F) (for gases) or within five minutes after coming into contact with air (for liquids and solids). Examples are organolithium compounds and triethylborane, as well as actinides. Pyrophoric materials are often water-reactive as well and will ignite when they contact water or humid air. They can be handled safely in atmospheres of argon or (with a few exceptions) nitrogen Wikipedia

Emergency Response Guide No. 135

Hazardous Materials Table

Source: 49 CFR §172 (15 June 2026)

(3) Hazard Class

4.2
Spontaneously combustible materials

(4) Identification number Help

UN 3194

(5) Packing Group Help

I

(6) Labels Help

Spontaneously combustible materials (4.2)

(1) Symbols Help


This entry is signed with "G". The letter "G" identifies proper shipping names for which one or more technical names of the hazardous material must be entered in parentheses, in association with the basic description. (See §172.203(k)).

(7) Special Provisions (§172.102) Help

(8) Packing Authorizations (§173.***) Help

(8A) ExceptionsNone
(8B) Non-bulk181see 49 CFR §173.181
(8C) Bulk244see 49 CFR §173.244

(9) Quantity Limits Help

(9A) Passenger aircraft/railForbidden
(9B) Cargo aircraft onlyForbidden

(10) Vessel stowage Help

(10A) Location
(10B) Other

Segregation chart for load, transport, and storage

This chart shows whether loading, transport, or storage with other hazard classes is permitted, prohibited, or restricted. Based on 49 CFR §177.848.

Prohibited Must not be loaded, transported, or stored together in the same vehicle or facility.
Permitted May be loaded, transported, or stored together.
Restricted May be loaded, transported, or stored together only with restrictions.