Ethyl bromoacetate

Ethyl bromoacetate is the chemical compound with the formula BrCH2CO2CH2CH3. It is the ethyl ester of bromoacetic acid and is prepared in two steps from acetic acid. It is a lachrymator and has a fruity, pungent odor. It is also a highly toxic alkylating agent and may be fatal if inhaled. Wikipedia

Emergency Response Guide No. 155

Data from the Hazardous Materials Table

Source: 49 CFR §172 (2026/05)

Packing Group II
Packing Group III

(3) Hazard Class

6.1
Poisonous Material

(4) Identification number

UN 1603

(5) Packing Group

Comparison View of PG

(6) Labels

(7) Special Provisions (§172.102)

×Note:
Special provisions may be very complex. The extracts are taken from 49 CFR §172.102. Please be careful with the information, as necessary, additional conditions may be applied that are not written here. Please check the original source and report bugs.

IB2

Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1).
Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 °C (1.1 bar at 122 °F), or 130 kPa at 55 °C (1.3 bar at 131 °F) are authorized.

Browse special provision IB2

Minimum test pressure (bar)	4
Minimum shell thickness	§ 178.274(d)(2)
Pressure-relief requirements	Normal
Bottom opening requirements	§ 178.275(d)(3)

Browse special provision T7

TP2

a. The maximum degree of filling must not exceed the degree of filling determined by the following:
TP2a

Where:
t_r is the maximum mean bulk temperature during transport,
t_f is the temperature in degrees celsius of the liquid during filling, and
α is the mean coefficient of cubical expansion of the liquid between the mean temperature of the liquid during filling (t_f) and the maximum mean bulk temperature during transportation (t_r) both in degrees celsius.
b. For liquids transported under ambient conditions α may be calculated using the formula:
TP2b

Where:
d₁₅ and d₅₀ are the densities (in units of mass per unit volume) of the liquid at 15 °C (59 °F) and 50 °C (122 °F), respectively.

Browse special provision TP2

(8) Packing Authorizations (§173.***)

(8A) Exceptions	153	see 49 CFR §173.153
(8B) Non-bulk	202	see 49 CFR §173.202
(8C) Bulk	243	see 49 CFR §173.243

(9) Quantity Limits

(9A) Passenger aircraft/rail	Forbidden
(9B) Cargo aircraft only	Forbidden

(10) Vessel stowage

(10A) Location

Stowage category “D” means the material must be stowed “on deck only” on a cargo vessel or on a passenger vessel carrying a number of passengers limited to not more than the larger of 25 passengers or one passenger per each 3 m of overall vessel length, but the material is prohibited on a passenger vessel in which the limiting number of passengers is exceeded.

Source: 49 CFR §172.101(k)

(10B) Other

40	see 49 CFR §176.84

Source: 49 CFR §176.84

(3) Hazard Class

6.1
Poisonous Material

(4) Identification number

UN 2643

(5) Packing Group

Comparison View of PG

(6) Labels

(7) Special Provisions (§172.102)

IB2

Browse special provision IB2

Minimum test pressure (bar)	4
Minimum shell thickness	§ 178.274(d)(2)
Pressure-relief requirements	Normal
Bottom opening requirements	§ 178.275(d)(3)

Browse special provision T7

TP2

a. The maximum degree of filling must not exceed the degree of filling determined by the following:
TP2a

Where:
d₁₅ and d₅₀ are the densities (in units of mass per unit volume) of the liquid at 15 °C (59 °F) and 50 °C (122 °F), respectively.

Browse special provision TP2

(8) Packing Authorizations (§173.***)

(8A) Exceptions	153	see 49 CFR §173.153
(8B) Non-bulk	202	see 49 CFR §173.202
(8C) Bulk	243	see 49 CFR §173.243

(9) Quantity Limits

(9A) Passenger aircraft/rail	5 L
(9B) Cargo aircraft only	60 L

(10) Vessel stowage

(10A) Location

Source: 49 CFR §172.101(k)

(10B) Other

40	see 49 CFR §176.84

Source: 49 CFR §176.84

Comparison View of Different Packing Groups

More than one packing group is indicated for this entry. Criteria for assignment see 49 CFR §173 Subpart D. You can find specific details in the tabs above. Differences are highlighted.

	PG II	PG II
1
2	Ethyl bromoacetate	Methyl bromoacetate
3	6.1	6.1
4	UN 1603	UN 2643
5	II	II
6	6.1, 3	6.1
7	IB2, T7, TP2	IB2, T7, TP2
8A	153	153
8B	202	202
8C	243	243
9A	Forbidden	5 L
9B	Forbidden	60 L
10A	D	D
10B	40	40

Segregation Chart for Load, Transport, Storage

In this table a statement is contained for each hazard class whether the loading, transport or storage with other hazard classes is allowed, is not permitted or is restricted. The table is based on U.S.-Code 49 CFR §177.848.

Note: The HMR prohibit only those Division 6.1 liquids that meet the definition of a Packing Group (PG) I and Hazard Zone A. See special provision 1 and PHMSA Interpretation #09-0252.

Packages with POISON or POISON INHALATION HAZARD labels, or a POISON label displaying “PG III,” or “PG III” marked next to a POISON label may not be transported with foodstuffs, feed or any other edible material, intended for humans or animals. For exceptions see 49 CFR §177.841(e).

There are no restrictions with hazardous materials, as pointed out in the instructions for using the Segregation Table (see 49 CFR §177.848(e)). But please, refer to following requirements in 49 CFR §177 Subpart B (Loading and Unloading):

§177.834 - General requirements
§177.835 - Class 1 materials
§177.837 - Class 3 materials
§177.838 - Class 4 (flammable solid) materials, Class 5 (oxidizing) materials, and Division 4.2 (pyroforic liquid) materials.
§177.839 - Class 8 (corrosive) materials
§177.840 - Class 2 (gases) materials
§177.841 - Division 6.1 and Division 2.3 materials
§177.842 - Class 7 (radioactive) material
§177.843 - Contamination of vehicles.

Substances with similar name

UN-Number	Name	Hazard Class
UN 1938	Bromoacetic acid solution	8
UN 1569	Bromoacetone	6.1
	Dibromoacetylene	Forbidden
UN 1603	Ethyl bromoacetate	6.1
UN 2643	Methyl bromoacetate	6.1