HazMat Tool — substance information
Phenylhydrazine
HMT 15 June 2026- UN / ID
- UN 2572
- Hazard class
- 6.1
- Packing group
- II
- ERG guide
- ERG 153
- Special provisions
- SP IB2, SP T7, SP TP2
- Source
- 49 CFR §172 (15 June 2026)
Phenylhydrazine
Phenylhydrazine is the chemical compound with the formula C6H5NHNH2. It is often abbreviated as PhNHNH2. It is also found in edible mushrooms Wikipedia
Substance Data
Source: PubChemCAS-Number100-63-0 |
Flash Pointn/a | Boiling Pointn/a |
| Emergency Response Guide No. 153 |
Hazardous Materials Table
Source: 49 CFR §172 (15 June 2026)(3) Hazard Class6.1Poisonous Material |
(4) Identification number |
(5) Packing Group |
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(6) Labels |
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(7) Special Provisions (§172.102)
|
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| IB2 | |
|---|---|
| T7 | |
| TP2 |
(8) Packing Authorizations (§173.***) 
| (8A) Exceptions | 153 | see 49 CFR §173.153 |
|---|---|---|
| (8B) Non-bulk | 202 | see 49 CFR §173.202 |
| (8C) Bulk | 243 | see 49 CFR §173.243 |
(9) Quantity Limits 
| (9A) Passenger aircraft/rail | 5 L |
|---|---|
| (9B) Cargo aircraft only | 60 L |
(10) Vessel stowage 
| (10A) Location | |
|---|---|
| (10B) Other |
Segregation chart for load, transport, and storage
This chart shows whether loading, transport, or storage with other hazard classes is permitted, prohibited, or restricted. Based on 49 CFR §177.848.
Note: The HMR prohibit only those Division 6.1 liquids that meet the definition of a Packing Group (PG) I and Hazard Zone A. See special provision 1 and PHMSA Interpretation #09-0252.
Packages with POISON or POISON INHALATION HAZARD labels, or a POISON label displaying “PG III,” or “PG III” marked next to a POISON label may not be transported with foodstuffs, feed or any other edible material, intended for humans or animals. For exceptions see 49 CFR §177.841(e).
Scope & sources (important)Click to show CFR references
This check evaluates segregation per 49 CFR §177.848. Additional loading/unloading and handling requirements may still apply; see 49 CFR §177 Subpart B (Loading and Unloading):
- §177.834 - General requirements
- §177.835 - Class 1 materials
- §177.837 - Class 3 materials
- §177.838 - Class 4 (flammable solid) materials, Class 5 (oxidizing) materials, and Division 4.2 (pyroforic liquid) materials
- §177.839 - Class 8 (corrosive) materials
- §177.840 - Class 2 (gases) materials
- §177.841 - Division 6.1 and Division 2.3 materials
- §177.842 - Class 7 (radioactive) material
- §177.843 - Contamination of vehicles
Similar substances
| UN / ID | Proper shipping name | Hazard class |
|---|---|---|
| UN 3376 | 4-Nitrophenylhydrazine, with not less than 30 percent water, by mass | 4.1 |

