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Chlorophenyltrichlorosilane

HMT 15 June 2026

UN / ID: UN 1753
Hazard class: 8
Packing group: II (multiple — see tabs)
ERG guide: ERG 156
Special provisions: SP A7, SP B2, SP B6, SP N34, SP T10, SP TP2, SP TP7
Source: 49 CFR §172 (15 June 2026)

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Chlorophenyltrichlorosilane

Emergency Response Guide No. 156

Hazardous Materials Table

Source: 49 CFR §172 (15 June 2026)

Packing group II
Packing group III
Packing group

(3) Hazard class

8
Corrosive liquids

(7) Special Provisions (§172.102)

×Note:
Special provisions may be very complex. The extracts are taken from 49 CFR §172.102. Please be careful with the information, as necessary, additional conditions may be applied that are not written here. Please check the original source and report bugs.

Steel packagings must be corrosion-resistant or have protection against corrosion.

Browse special provision A7

MC 300, MC 301, MC 302, MC 303, MC 305, and MC 306 and DOT 406 cargo tanks are not authorized.

Browse special provision B2

Packagings shall be made of steel.

Browse special provision B6

N34

Aluminum construction materials are not authorized for any part of a packaging which is normally in contact with the hazardous material.

Browse special provision N34

T10

Minimum test pressure (bar)	4
Minimum shell thickness	6 mm
Pressure-relief requirements	§ 178.275(g)(3)
Bottom opening requirements	Prohibited

Browse special provision T10

TP2

a. The maximum degree of filling must not exceed the degree of filling determined by the following:
TP2a

Where:
t_r is the maximum mean bulk temperature during transport,
t_f is the temperature in degrees celsius of the liquid during filling, and
α is the mean coefficient of cubical expansion of the liquid between the mean temperature of the liquid during filling (t_f) and the maximum mean bulk temperature during transportation (t_r) both in degrees celsius.
b. For liquids transported under ambient conditions α may be calculated using the formula:
TP2b

Where:
d₁₅ and d₅₀ are the densities (in units of mass per unit volume) of the liquid at 15 °C (59 °F) and 50 °C (122 °F), respectively.

Browse special provision TP2

TP7

The vapor space must be purged of air by nitrogen or other means.

Browse special provision TP7

(8) Packing Authorizations (§173.***)

(8A) Exceptions	None
(8B) Non-bulk	206	see 49 CFR §173.206
(8C) Bulk	242	see 49 CFR §173.242

(9) Quantity Limits

(9A) Passenger aircraft/rail	Forbidden
(9B) Cargo aircraft only	30 L

(10) Vessel stowage

(10A) Location

Stowage category “C” means the material must be stowed “on deck only” on a cargo vessel or on a passenger vessel.

Source: 49 CFR §172.101(k)

(10B) Other

40	see 49 CFR §176.84
53	see 49 CFR §176.84
58	see 49 CFR §176.84

Source: 49 CFR §176.84

(3) Hazard class

8
Corrosive liquids

(4) Identification number

UN 1766

(5) Packing Group

Comparison View of PG

(6) Labels

Cargo Aircraft Only (Cargo Aircraft Only)

(7) Special Provisions (§172.102)

Steel packagings must be corrosion-resistant or have protection against corrosion.

Browse special provision A7

MC 300, MC 301, MC 302, MC 303, MC 305, and MC 306 and DOT 406 cargo tanks are not authorized.

Browse special provision B2

Packagings shall be made of steel.

Browse special provision B6

N34

Aluminum construction materials are not authorized for any part of a packaging which is normally in contact with the hazardous material.

Browse special provision N34

T10

Minimum test pressure (bar)	4
Minimum shell thickness	6 mm
Pressure-relief requirements	§ 178.275(g)(3)
Bottom opening requirements	Prohibited

Browse special provision T10

TP2

a. The maximum degree of filling must not exceed the degree of filling determined by the following:
TP2a

Where:
d₁₅ and d₅₀ are the densities (in units of mass per unit volume) of the liquid at 15 °C (59 °F) and 50 °C (122 °F), respectively.

Browse special provision TP2

TP7

The vapor space must be purged of air by nitrogen or other means.

Browse special provision TP7

TP13

Self-contained breathing apparatus must be provided when this hazardous material is transported by sea.

Browse special provision TP13

(8) Packing Authorizations (§173.***)

(8A) Exceptions	None
(8B) Non-bulk	206	see 49 CFR §173.206
(8C) Bulk	242	see 49 CFR §173.242

(9) Quantity Limits

(9A) Passenger aircraft/rail	Forbidden
(9B) Cargo aircraft only	30 L

(10) Vessel stowage

(10A) Location

Stowage category “C” means the material must be stowed “on deck only” on a cargo vessel or on a passenger vessel.

Source: 49 CFR §172.101(k)

(10B) Other

40	see 49 CFR §176.84
53	see 49 CFR §176.84
58	see 49 CFR §176.84

Source: 49 CFR §176.84

(3) Hazard class

8
Corrosive liquids

(4) Identification number

UN 1804

(5) Packing Group

Comparison View of PG

(6) Labels

(7) Special Provisions (§172.102)

Steel packagings must be corrosion-resistant or have protection against corrosion.

Browse special provision A7

Packagings shall be made of steel.

Browse special provision B6

N34

Aluminum construction materials are not authorized for any part of a packaging which is normally in contact with the hazardous material.

Browse special provision N34

T10

Minimum test pressure (bar)	4
Minimum shell thickness	6 mm
Pressure-relief requirements	§ 178.275(g)(3)
Bottom opening requirements	Prohibited

Browse special provision T10

TP2

a. The maximum degree of filling must not exceed the degree of filling determined by the following:
TP2a

Where:
d₁₅ and d₅₀ are the densities (in units of mass per unit volume) of the liquid at 15 °C (59 °F) and 50 °C (122 °F), respectively.

Browse special provision TP2

TP7

The vapor space must be purged of air by nitrogen or other means.

Browse special provision TP7

TP13

Self-contained breathing apparatus must be provided when this hazardous material is transported by sea.

Browse special provision TP13

(8) Packing Authorizations (§173.***)

(8A) Exceptions	None
(8B) Non-bulk	206	see 49 CFR §173.206
(8C) Bulk	242	see 49 CFR §173.242

(9) Quantity Limits

(9A) Passenger aircraft/rail	Forbidden
(9B) Cargo aircraft only	30 L

(10) Vessel stowage

(10A) Location

Stowage category “C” means the material must be stowed “on deck only” on a cargo vessel or on a passenger vessel.

Source: 49 CFR §172.101(k)

(10B) Other

40	see 49 CFR §176.84
53	see 49 CFR §176.84
58	see 49 CFR §176.84

Source: 49 CFR §176.84

Packing group comparison

Multiple packing groups apply to this entry. See assignment criteria in 49 CFR §173 Subpart D. Details are in the tabs above; differences are highlighted.

	PG II	PG II	PG II
1
2	Chlorophenyltrichlorosilane	Dichlorophenyltrichlorosilane	Phenyltrichlorosilane
3	8	8	8
4	UN 1753	UN 1766	UN 1804
5	II	II	II
6	8	8	8
7	A7, B2, B6, N34, T10, TP2, TP7	A7, B2, B6, N34, T10, TP2, TP7, TP13	A7, B6, N34, T10, TP2, TP7, TP13
8A	None	None	None
8B	206	206	206
8C	242	242	242
9A	Forbidden	Forbidden	Forbidden
9B	30 L	30 L	30 L
10A	C	C	C
10B	40, 53, 58	40, 53, 58	40, 53, 58

Segregation chart for load, transport, and storage

This chart shows whether loading, transport, or storage with other hazard classes is permitted, prohibited, or restricted. Based on 49 CFR §177.848.

Note: In this segregation and separation chart are HazMat of hazard class 8 considered depending if there are liquid. Currently HazMat Tool is not able to to check if a HazMat is liquid or not. Therefore it is assumed as liquid. See PHMSA Interpretation #09-0252.

Hazard class	8	7	6.1	5.2	5.1	4.3	4.2	4.1	3	2.3B	2.3A	2.2	2.1	1.6	1.5	1.4	1.3	1.1/1.2
1.1/1.2
1.3
1.4
1.5
1.6
2.1
2.2
2.3A
2.3B
3
4.1
4.2
4.3
5.1
5.2
6.1
7
8

	Must not be loaded, transported, or stored together in the same vehicle or facility.
	May be loaded, transported, or stored together.
	May be loaded, transported, or stored together only with restrictions.

Similar substances

UN / ID	Proper shipping name	Hazard class
UN 1753	Chlorophenyltrichlorosilane	8
UN 1766	Dichlorophenyltrichlorosilane	8