Sodium methylate solutions in alcohol

Substance Data

Source: TOXNET

CAS-Number

124-41-4

Flash Point

n/a

Boiling Point

n/a

Emergency Response Guide No. 132

Data from the Hazardous Materials Table

Source: 49 CFR §172 (2018/07)

Packing Group II
Packing Group III

(3) Hazard Class

3
Flammable liquids

(7) Special Provisions (§172.102)

×Note:
Special provisions may be very complex. The extracts are taken from 49 CFR §172.102. Please be careful with the information, as necessary, additional conditions may be applied that are not written here. Please check the original source and report bugs.

IB2	Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 [deg]C (1.1 bar at 122 [deg]F), or 130 kPa at 55 [deg]C (1.3 bar at 131 [deg]F) are authorized. Browse special provision IB2
T7	see 49 CFR §172.102
TP1	The maximum degree of filling must not exceed the degree of filling determined by the following: Where: t_r is the maximum mean bulk temperature during transport, and t_f is the temperature in degrees celsius of the liquid during filling. Browse special provision TP1
TP8	A portable tank having a minimum test pressure of 1.5 bar (150 kPa) may be used when the flash point of the hazardous material transported is greater than 0 °C (32 °F). Browse special provision TP8

(8) Packing Authorizations (§173.***)

(8A) Exceptions	150	see 49 CFR §173.150
(8B) Non-bulk	202	see 49 CFR §173.202
(8C) Bulk	243	see 49 CFR §173.243

(9) Quantity Limits

(9A) Passenger aircraft/rail	1 L
(9B) Cargo aircraft only	5 L

(10) Vessel stowage

(10A) Location	B Stowage category “B” means (i) The material may be stowed “on deck” or “under deck” on a cargo vessel and on a passenger vessel carrying a number of passengers limited to not more than the larger of 25 passengers, or one passenger per each 3 m of overall vessel length; and (ii) “On deck only” on passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this section is exceeded. Source: 49 CFR §172.101(k)
(10B) Other	n/a

(3) Hazard Class

3
Flammable liquids

(4) Identification number

UN 1289

(5) Packing Group

III

Comparison View of PG

(6) Labels

(7) Special Provisions (§172.102)

B1	If the material has a flash point at or above 38 °C (100 °F) and below 93 °C (200 °F), then the bulk packaging requirements of §173.241 of this subchapter are applicable. If the material has a flash point of less than 38 °C (100 °F), then the bulk packaging requirements of §173.242 of this subchapter are applicable. Browse special provision B1
IB3	Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1 and 31HA2, 31HB2, 31HN2, 31HD2 and 31HH2). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 [deg]C (1.1 bar at 122 [deg]F), or 130 kPa at 55 [deg]C (1.3 bar at 131 [deg]F) are authorized, except for UN2672 (also see Special Provision IP8 for UN2672). Browse special provision IB3
T4	see 49 CFR §172.102
TP1	The maximum degree of filling must not exceed the degree of filling determined by the following: Where: t_r is the maximum mean bulk temperature during transport, and t_f is the temperature in degrees celsius of the liquid during filling. Browse special provision TP1

(8) Packing Authorizations (§173.***)

(8A) Exceptions	150	see 49 CFR §173.150
(8B) Non-bulk	203	see 49 CFR §173.203
(8C) Bulk	242	see 49 CFR §173.242

(9) Quantity Limits

(9A) Passenger aircraft/rail	5 L
(9B) Cargo aircraft only	60 L

(10) Vessel stowage

(10A) Location	A Stowage category “A” means the material may be stowed “on deck” or “under deck” on a cargo vessel or on a passenger vessel. Source: 49 CFR §172.101(k)
(10B) Other	n/a

Comparison View of Different Packing Groups

More than one packing group is indicated for this entry. Criteria for assignment see 49 CFR §173 Subpart D. You can find specific details in the tabs above. Differences are highlighted.

	PG II	PG III
1
2	Sodium methylate solutions in alcohol	Sodium methylate solutions in alcohol
3	3	3
4	UN 1289	UN 1289
5	II	III
6	3, 8	3, 8
7	IB2, T7, TP1, TP8	B1, IB3, T4, TP1
8A	150	150
8B	202	203
8C	243	242
9A	1 L	5 L
9B	5 L	60 L
10A	B	A
10B	n/a	n/a

Segregation Chart for Load, Transport, Storage

In this table a statement is contained for each hazard class whether the loading, transport or storage with other hazard classes is allowed, is not permitted or is restricted. The table is based on U.S.-Code 49 CFR §177.848.

Hazard Class	8	7	6.1	5.2	5.1	4.3	4.2	4.1	3	2.3B	2.3A	2.2	2.1	1.6	1.5	1.4	1.3	1.1/1.2
1.1/1.2
1.3
1.4
1.5
1.6
2.1
2.2
2.3A
2.3B
3
4.1
4.2
4.3
5.1
5.2
6.1
7
8

	May not be loaded, transported, or stored together in the same transport vehicle or storage facility.
	Load, transport, storage together is not restricted.
	Load, transport, storage together is allowed under restrictions.

Substances with similar name

UN-Number	Name	Hazard Class
UN 3065	Alcoholic beverages	3
UN 3206	Alkali metal alcoholates, self-heating, corrosive, n.o.s	4.2
UN 3205	Alkaline earth metal alcoholates, n.o.s	4.2
UN 1098	Allyl alcohol	6.1
UN 3438	alpha-Methylbenzyl alcohol, solid	6.1
NA 1987	Denatured alcohol	3
UN 0074	Diazodinitrophenol, wetted with not less than 40 percent water or mixture of alcohol and water, by mass	1.1A
UN 1170	Ethanol or Ethyl alcohol or Ethanol solutions or Ethyl alcohol solutions	3
	Ethyl alcohol, see Ethanol
UN 2874	Furfuryl alcohol	6.1
UN 1203	Gasoline includes gasoline mixed with ethyl alcohol, with not more than 10% alcohol	3
UN 3294	Hydrogen cyanide, solution in alcohol with not more than 45 percent hydrogen cyanide	6.1
UN 1212	Isobutanol or Isobutyl alcohol	3
	Isobutyl alcohol, see Isobutanol
	Isopropyl alcohol, see Isopropanol
UN 0129	Lead azide, wetted with not less than 20 percent water or mixture of alcohol and water, by mass	1.1A
UN 1274	n-Propanol or Propyl alcohol, normal	3
UN 0340	Nitrocellulose, dry or wetted with less than 25 percent water (or alcohol), by mass	1.1D
UN 0342	Nitrocellulose, wetted with not less than 25 percent alcohol, by mass	1.3C
UN 3064	Nitroglycerin, solution in alcohol, with more than 1 percent but not more than 5 percent nitroglycerin	3
UN 1204	Nitroglycerin solution in alcohol with not more than 1 percent nitroglycerin	3
UN 0433	Powder cake, wetted or Powder paste, wetted with not less than 17 percent alcohol by mass	1.1C
UN 1289	Sodium methylate solutions in alcohol	3
UN 0394	Trinitroresorcinol, wetted or Styphnic acid, wetted with not less than 20 percent water, or mixture of alcohol and water by mass	1.1D
UN 0219	Trinitroresorcinol or Styphnic acid, dry or wetted with less than 20 percent water, or mixture of alcohol and water, by mass	1.1D