Thionyl chloride

Thionyl chloride is an inorganic compound with the chemical formula SOCl2. It is a moderately volatile, colourless liquid with an unpleasant acrid odour. Thionyl chloride is primarily used as a chlorinating reagent, with approximately 45,000 tonnes (50,000 short tons) per year being produced during the early 1990s, but is occasionally also used as a solvent. It is toxic, reacts with water, and is also listed under the Chemical Weapons Convention as it may be used for the production of chemical weapons. Thionyl chloride is sometimes confused with sulfuryl chloride, SO2Cl2, but the properties of these compounds differ significantly. Wikipedia

Substance Data

Hazardous Materials Table

(3) Hazard Class 8 Corrosive liquids	(4) Identification number UN 1836	(5) Packing Group I
(6) Labels
(7) Special Provisions (§172.102) ×Note: Special provisions may be very complex. The extracts are taken from 49 CFR §172.102. Please be careful with the information, as necessary, additional conditions may be applied that are not written here. Please check the original source and report bugs. B6 Packagings shall be made of steel. Browse special provision B6 B10 MC 300, MC 301, MC 302, MC 303, MC 305, and MC 306 and DOT 406 cargo tanks, and DOT 57 portable tanks are not authorized. Browse special provision B10 N34 Aluminum construction materials are not authorized for any part of a packaging which is normally in contact with the hazardous material. Browse special provision N34 T10 Minimum test pressure (bar) 4 Minimum shell thickness 6 mm Pressure-relief requirements § 178.275(g)(3) Bottom opening requirements Prohibited Browse special provision T10 TP2 a. The maximum degree of filling must not exceed the degree of filling determined by the following: Where: tr is the maximum mean bulk temperature during transport, tf is the temperature in degrees celsius of the liquid during filling, and α is the mean coefficient of cubical expansion of the liquid between the mean temperature of the liquid during filling (tf) and the maximum mean bulk temperature during transportation (tr) both in degrees celsius. b. For liquids transported under ambient conditions α may be calculated using the formula: Where: d15 and d50 are the densities (in units of mass per unit volume) of the liquid at 15 °C (59 °F) and 50 °C (122 °F), respectively. Browse special provision TP2 TP13 Self-contained breathing apparatus must be provided when this hazardous material is transported by sea. Browse special provision TP13
(8) Packing Authorizations (§173.***) (8A) Exceptions None (8B) Non-bulk 201 see 49 CFR §173.201 (8C) Bulk 243 see 49 CFR §173.243
(9) Quantity Limits (9A) Passenger aircraft/rail Forbidden (9B) Cargo aircraft only Forbidden
(10) Vessel stowage (10A) Location C Stowage category “C” means the material must be stowed “on deck only” on a cargo vessel or on a passenger vessel. Source: 49 CFR §172.101(k) (10B) Other 40 see 49 CFR §176.84 53 see 49 CFR §176.84 58 see 49 CFR §176.84 Source: 49 CFR §176.84

Segregation chart for load, transport, and storage

This chart shows whether loading, transport, or storage with other hazard classes is permitted, prohibited, or restricted. Based on 49 CFR §177.848.

Note: In this segregation and separation chart are HazMat of hazard class 8 considered depending if there are liquid. Currently HazMat Tool is not able to to check if a HazMat is liquid or not. Therefore it is assumed as liquid. See PHMSA Interpretation #09-0252.

Add to my HazMat & segregation check

Hazard class	8	7	6.1	5.2	5.1	4.3	4.2	4.1	3	2.3B	2.3A	2.2	2.1	1.6	1.5	1.4	1.3	1.1/1.2
1.1/1.2
1.3
1.4
1.5
1.6
2.1
2.2
2.3A
2.3B
3
4.1
4.2
4.3
5.1
5.2
6.1
7
8

	Must not be loaded, transported, or stored together in the same vehicle or facility.
	May be loaded, transported, or stored together.
	May be loaded, transported, or stored together only with restrictions.