Toluidines, liquid

There are three isomers of toluidine, which are organic compounds discovered and named by James Sheridan Muspratt and August Wilhelm von Hofmann in 1845. These isomers are o-toluidine, m-toluidine, and p-toluidine, with the prefixed letter abbreviating, respectively, ortho; meta; and para. All three are aryl amines whose chemical structures are similar to aniline except that a methyl group is substituted onto the benzene ring. The difference between these three isomers is the position where the methyl group (–CH3) is bonded to the ring relative to the amino functional group (–NH2); see illustration of the chemical structures below Wikipedia

Substance Data

Hazardous Materials Table

• Packing group II
• Packing group III

(3) Hazard class 6.1 Poisonous Material	(4) Identification number UN 1708	(5) Packing Group II Comparison View of PG
(6) Labels
(1) Symbols This entry is signed with plus (+). The plus (+) sign fixes the proper shipping name, hazard class and packing group for that entry without regard to whether the material meets the definition of that class, packing group or any other hazard class definition. When the plus sign is assigned, it means that the material is known to pose a risk to humans. When a plus sign is assigned to mixtures or solutions containing a material where the hazard to humans is significantly different from that of the pure material or where no hazard to humans is posed, the material may be described using an alternative shipping name that represents the hazards posed by the material. An appropriate alternate proper shipping name and hazard class may be authorized by the Associate Administrator. (7) Special Provisions (§172.102) ×Note: Special provisions may be very complex. The extracts are taken from 49 CFR §172.102. Please be careful with the information, as necessary, additional conditions may be applied that are not written here. Please check the original source and report bugs. IB2 Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 °C (1.1 bar at 122 °F), or 130 kPa at 55 °C (1.3 bar at 131 °F) are authorized. Browse special provision IB2 T7 Minimum test pressure (bar) 4 Minimum shell thickness § 178.274(d)(2) Pressure-relief requirements Normal Bottom opening requirements § 178.275(d)(3) Browse special provision T7 TP2 a. The maximum degree of filling must not exceed the degree of filling determined by the following: Where: tr is the maximum mean bulk temperature during transport, tf is the temperature in degrees celsius of the liquid during filling, and α is the mean coefficient of cubical expansion of the liquid between the mean temperature of the liquid during filling (tf) and the maximum mean bulk temperature during transportation (tr) both in degrees celsius. b. For liquids transported under ambient conditions α may be calculated using the formula: Where: d15 and d50 are the densities (in units of mass per unit volume) of the liquid at 15 °C (59 °F) and 50 °C (122 °F), respectively. Browse special provision TP2
(8) Packing Authorizations (§173.***) (8A) Exceptions 153 see 49 CFR §173.153 (8B) Non-bulk 202 see 49 CFR §173.202 (8C) Bulk 243 see 49 CFR §173.243
(9) Quantity Limits (9A) Passenger aircraft/rail 5 L (9B) Cargo aircraft only 60 L
(10) Vessel stowage (10A) Location A Stowage category “A” means the material may be stowed “on deck” or “under deck” on a cargo vessel or on a passenger vessel. Source: 49 CFR §172.101(k) (10B) Other —

(3) Hazard class 6.1 Poisonous Material	(4) Identification number UN 3429	(5) Packing Group III Comparison View of PG
(6) Labels
(7) Special Provisions (§172.102) ×Note: Special provisions may be very complex. The extracts are taken from 49 CFR §172.102. Please be careful with the information, as necessary, additional conditions may be applied that are not written here. Please check the original source and report bugs. IB3 Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1 and 31HA2, 31HB2, 31HN2, 31HD2 and 31HH2). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 °C (1.1 bar at 122 °F), or 130 kPa at 55 °C (1.3 bar at 131 °F) are authorized, except for UN2672 (also see special provision IP8 in Table 2 for UN2672). Browse special provision IB3 T4 Minimum test pressure (bar) 2.65 Minimum shell thickness § 178.274(d)(2) Pressure-relief requirements Normal Bottom opening requirements § 178.275(d)(3) Browse special provision T4 TP1 The maximum degree of filling must not exceed the degree of filling determined by the following: Where: tr is the maximum mean bulk temperature during transport, and tf is the temperature in degrees celsius of the liquid during filling. Browse special provision TP1
(8) Packing Authorizations (§173.***) (8A) Exceptions 153 see 49 CFR §173.153 (8B) Non-bulk 203 see 49 CFR §173.203 (8C) Bulk 241 see 49 CFR §173.241
(9) Quantity Limits (9A) Passenger aircraft/rail 60 L (9B) Cargo aircraft only 220 L
(10) Vessel stowage (10A) Location A Stowage category “A” means the material may be stowed “on deck” or “under deck” on a cargo vessel or on a passenger vessel. Source: 49 CFR §172.101(k) (10B) Other —