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HazMat Tool — substance information
Reference only — not a shipping paper, placard mandate, or CVI record.
Phosgene
HMT 15 June 2026
Reference only — HMT snapshot for inspection and audit support; not a shipping paper, placard mandate, or CVI record.
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Phosgene is an organic chemical compound with the formula COCl2. It is a toxic, colorless gas; in low concentrations, its musty odor resembles that of freshly cut hay or grass. It can be thought of chemically as the double acyl chloride analog of carbonic acid, or structurally as formaldehyde with the hydrogen atoms replaced by chlorine atoms. In 2013, about 75–80% of global phosgene was consumed for isocyanates, 18% for polycarbonates and about 5% for other fine chemicals Wikipedia
×Note: Special provisions may be very complex. The extracts are taken from 49 CFR §172.102. Please be careful with the information, as necessary, additional conditions may be applied that are not written here. Please check the original source and report bugs.
This material is poisonous by inhalation (see § 171.8 of this subchapter) in Hazard Zone A (see § 173.116(a) or § 173.133(a) of this subchapter), and must be described as an inhalation hazard under the provisions of this subchapter.
Safety relief devices are not authorized on multi-unit tank car tanks. Openings for safety relief devices on multi-unit tank car tanks shall be plugged or blank flanged.
The detachable protective housing for the loading and unloading valves of multi-unit tank car tanks must withstand tank test pressure and must be approved by the Associate Administrator.
Stowage category “D” means the material must be stowed “on deck only” on a cargo vessel or on a passenger vessel carrying a number of passengers limited to not more than the larger of 25 passengers or one passenger per each 3 m of overall vessel length, but the material is prohibited on a passenger vessel in which the limiting number of passengers is exceeded.
Segregation chart for load, transport, and storage
This chart shows whether loading, transport, or storage with other hazard classes is permitted, prohibited, or restricted. Based on 49 CFR §177.848.
Hinweis: In der Kompatibilitätstabelle sind Stoffe der Gefahrenklasse 2.3 abhängig der Einstufung der inhalativen Giftigkeit zu berücksichtigen (Gefahrenzone A). Siehe Sonderbestimmung 1 sowie PHMSA Interpretation #09-0252.