Methylhydrazine

Methylhydrazines are hydrazines that have additional methyl groups. Heavily methylated versions exist as hydrazinium salts. Members of this class include: Monomethylhydrazine Monomethylhydrazinium (cationic and exists as a variety of salts) Dimethylhydrazines Symmetrical dimethylhydrazine (1,2-dimethylhydrazine) Unsymmetrical dimethylhydrazine (1,1-dimethylhydrazine) Trimethylhydrazine 1,1,2-trimethylhydrazine 1,1,1-trimethylhydrazinium (cationic and exists as a variety of salts e.g. 1,1,1-trimethylhydrazinium iodide) Tetramethylhydrazine 1,1,2,2-tetramethylhydrazine 1,1,1,2-tetramethylhydrazinium (cationic and exists as a variety of salts) Pentamethylhydrazinium (cationic and exists as a variety of salts) Hexamethylhydrazinediium (dication, exists as a variety of salts) Wikipedia

Substance Data

Hazardous Materials Table

(3) Hazard class 6.1 Poisonous Material	(4) Identification number UN 1244	(5) Packing Group I
(6) Labels
(7) Special Provisions (§172.102) ×Note: Special provisions may be very complex. The extracts are taken from 49 CFR §172.102. Please be careful with the information, as necessary, additional conditions may be applied that are not written here. Please check the original source and report bugs. 1 This material is poisonous by inhalation (see § 171.8 of this subchapter) in Hazard Zone A (see § 173.116(a) or § 173.133(a) of this subchapter), and must be described as an inhalation hazard under the provisions of this subchapter. Browse special provision 1 B7 Safety relief devices are not authorized on multi-unit tank car tanks. Openings for safety relief devices on multi-unit tank car tanks shall be plugged or blank flanged. Browse special provision B7 B9 Bottom outlets are not authorized. Browse special provision B9 B14 Each bulk packaging, except a tank car or a multi-unit-tank car tank, must be insulated with an insulating material so that the overall thermal conductance at 15.5 °C (60 °F) is no more than 1.5333 kilojoules per hour per square meter per degree Celsius (0.075 Btu per hour per square foot per degree Fahrenheit) temperature differential. Insulating materials must not promote corrosion to steel when wet. Browse special provision B14 B30 MC 312, MC 330, MC 331 and DOT 412 cargo tanks and DOT 51 portable tanks must be made of stainless steel, except that steel other than stainless steel may be used in accordance with the provisions of § 173.24b(b) of this subchapter. Thickness of stainless steel for tank shell and heads for cargo tanks and portable tanks must be the greater of 7.62 mm (0.300 inch) or the thickness required for a tank with a design pressure at least equal to 1.5 times the vapor pressure of the lading at 46 °C (115 °F). In addition, MC 312 and DOT 412 cargo tank motor vehicles must: a. Be ASME Code (U) stamped for 100% radiography of all pressure-retaining welds; b. Have accident damage protection which conforms with § 178.345-8 of this subchapter; c. Have a MAWP or design pressure of at least 87 psig: and d. Have a bolted manway cover. Browse special provision B30 B77 Other packaging are authorized when approved by the Associate Administrator. Browse special provision B77 N34 Aluminum construction materials are not authorized for any part of a packaging which is normally in contact with the hazardous material. Browse special provision N34 T22 Minimum test pressure (bar) 10 Minimum shell thickness 10 mm Pressure-relief requirements § 178.275(g)(3) Bottom opening requirements Prohibited Browse special provision T22 TP2 a. The maximum degree of filling must not exceed the degree of filling determined by the following: Where: tr is the maximum mean bulk temperature during transport, tf is the temperature in degrees celsius of the liquid during filling, and α is the mean coefficient of cubical expansion of the liquid between the mean temperature of the liquid during filling (tf) and the maximum mean bulk temperature during transportation (tr) both in degrees celsius. b. For liquids transported under ambient conditions α may be calculated using the formula: Where: d15 and d50 are the densities (in units of mass per unit volume) of the liquid at 15 °C (59 °F) and 50 °C (122 °F), respectively. Browse special provision TP2 TP13 Self-contained breathing apparatus must be provided when this hazardous material is transported by sea. Browse special provision TP13 TP38 Each portable tank must be insulated with an insulating material so that the overall thermal conductance at 15.5 °C (60 °F) is no more than 1.5333 kilojoules per hour per square meter per degree Celsius (0.075 Btu per hour per square foot per degree Fahrenheit) temperature differential. Insulating materials may not promote corrosion to steel when wet. Browse special provision TP38 TP44 Each portable tank must be made of stainless steel, except that steel other than stainless steel may be used in accordance with the provisions of § 173.24b(b) of this subchapter. Thickness of stainless steel for tank shell and heads must be the greater of 7.62 mm (0.300 inch) or the thickness required for a portable tank with a design pressure at least equal to 1.5 times the vapor pressure of the hazardous material at 46 °C (115 °F). Browse special provision TP44
(8) Packing Authorizations (§173.***) (8A) Exceptions None (8B) Non-bulk 226 see 49 CFR §173.226 (8C) Bulk 244 see 49 CFR §173.244
(9) Quantity Limits (9A) Passenger aircraft/rail Forbidden (9B) Cargo aircraft only Forbidden
(10) Vessel stowage (10A) Location D Stowage category “D” means the material must be stowed “on deck only” on a cargo vessel or on a passenger vessel carrying a number of passengers limited to not more than the larger of 25 passengers or one passenger per each 3 m of overall vessel length, but the material is prohibited on a passenger vessel in which the limiting number of passengers is exceeded. Source: 49 CFR §172.101(k) (10B) Other 21 see 49 CFR §176.84 40 see 49 CFR §176.84 49 see 49 CFR §176.84 52 and 100 see 49 CFR §176.84 Source: 49 CFR §176.84

Segregation chart for load, transport, and storage

This chart shows whether loading, transport, or storage with other hazard classes is permitted, prohibited, or restricted. Based on 49 CFR §177.848.

Note: The HMR prohibit only those Division 6.1 liquids that meet the definition of a Packing Group (PG) I and Hazard Zone A. See special provision 1 and PHMSA Interpretation #09-0252.

Packages with POISON or POISON INHALATION HAZARD labels, or a POISON label displaying “PG III,” or “PG III” marked next to a POISON label may not be transported with foodstuffs, feed or any other edible material, intended for humans or animals. For exceptions see 49 CFR §177.841(e).

Currently HazMat Tool is not able to to check if a HazMat is liquid or not. Therefore it is assumed as liquid.

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Hazard class	8	7	6.1	5.2	5.1	4.3	4.2	4.1	3	2.3B	2.3A	2.2	2.1	1.6	1.5	1.4	1.3	1.1/1.2
1.1/1.2
1.3
1.4
1.5
1.6
2.1
2.2
2.3A
2.3B
3
4.1
4.2
4.3
5.1
5.2
6.1
7
8

	Must not be loaded, transported, or stored together in the same vehicle or facility.
	May be loaded, transported, or stored together.
	May be loaded, transported, or stored together only with restrictions.