HazMat Tool — substance information

Calcium

HMT 15 June 2026

UN / ID: UN 1401
Hazard class: 4.3
Packing group: II
ERG guide: ERG 138
Special provisions: SP IB7, SP IP2, SP IP21, SP T3, SP TP33, SP W31, SP W40
Source: 49 CFR §172 (15 June 2026)

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Calcium

Calcium is a chemical element; it has symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar to its heavier homologues strontium and barium. It is the fifth most abundant element in Earth's crust, and the third most abundant metal, after iron and aluminium Wikipedia

Emergency Response Guide No. 138

Hazardous Materials Table

Source: 49 CFR §172 (15 June 2026)

(3) Hazard Class

4.3
Dangerous when wet materials

(4) Identification number

UN 1401

(5) Packing Group

(6) Labels

(7) Special Provisions (§172.102)

×Note:
Special provisions may be very complex. The extracts are taken from 49 CFR §172.102. Please be careful with the information, as necessary, additional conditions may be applied that are not written here. Please check the original source and report bugs.

IB7

_{Authorized IBCs:} Metal (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B and 31N); Rigid plastics (11H1, 11H2, 21H1, 21H2, 31H1 and 31H2); Composite (11HZ1, 11HZ2, 21HZ1, 21HZ2 and 31HZ1); Wooden (11C, 11D and 11F).
_{Additional Requirement:} Liners of wooden IBCs must be sift-proof.

Browse special provision IB7

IP2

When IBCs other than metal or rigid plastics IBCs are used, they must be offered for transportation in a closed freight container or a closed transport vehicle.

Browse special provision IP2

IP21

When transported by vessel, flexible, fiberboard or wooden IBCs must be sift-proof and water-resistant or be fitted with a sift-proof and water-resistant liner.
Large outer packagings:
Large outer packagings:
§ 178.275(d)(2)
§ 178.275(d)(3)
§ 178.275(d)(2)
§ 178.275(d)(3)
Prohibited
§ 178.275(d)(2)
§ 178.275(d)(3)
Prohibited
Prohibited for liquids.
Prohibited
§ 178.275(d)(3)
§ 178.275(d)(3)
Prohibited
Prohibited
§ 178.275(d)(3)
§ 178.275(d)(3)
§ 178.275(d)(3)
§ 178.275(d)(3)
Prohibited
Prohibited
Prohibited for liquids. § 178.275(d)(2).

Browse special provision IP21

Minimum test pressure (bar)	2.65
Minimum shell thickness	§ 178.274(d)(2)
Pressure-relief requirements	Normal
Bottom opening requirements	§ 178.275(d)(2)

Browse special provision T3

TP33

The portable tank instruction assigned for this substance applies for granular and powdered solids and for solids which are filled and discharged at temperatures above their melting point which are cooled and transported as a solid mass. Solid substances transported or offered for transport above their melting point are authorized for transportation in portable tanks conforming to the provisions of portable tank instruction T4 for solid substances of packing group III or T7 for solid substances of packing group II, unless a tank with more stringent requirements for minimum shell thickness, maximum allowable working pressure, pressure-relief devices or bottom outlets are assigned in which case the more stringent tank instruction and special provisions shall apply. Filling limits must be in accordance with portable tank special provision TP3. Solids meeting the definition of an elevated temperature material must be transported in accordance with the applicable requirements of this subchapter.

Browse special provision TP33

W31

Non-bulk packagings must be hermetically sealed.

Browse special provision W31

W40

Non-bulk bags are not allowed.

Browse special provision W40

(8) Packing Authorizations (§173.***)

(8A) Exceptions	151	see 49 CFR §173.151
(8B) Non-bulk	212	see 49 CFR §173.212
(8C) Bulk	241	see 49 CFR §173.241

(9) Quantity Limits

(9A) Passenger aircraft/rail	15 kg
(9B) Cargo aircraft only	50 kg

(10) Vessel stowage

(10A) Location

Stowage category “E” means the material may be stowed “on deck” or “under deck” on a cargo vessel or on a passenger vessel carrying a number of passengers limited to not more than the larger of 25 passengers, or one passenger per each 3 m of overall vessel length, but is prohibited from carriage on a passenger vessel in which the limiting number of passengers is exceeded.

Source: 49 CFR §172.101(k)

(10B) Other

13	see 49 CFR §176.84
52	see 49 CFR §176.84
148	see 49 CFR §176.84

Source: 49 CFR §176.84

Segregation chart for load, transport, and storage

This chart shows whether loading, transport, or storage with other hazard classes is permitted, prohibited, or restricted. Based on 49 CFR §177.848.

Hazard class	8	7	6.1	5.2	5.1	4.3	4.2	4.1	3	2.3B	2.3A	2.2	2.1	1.6	1.5	1.4	1.3	1.1/1.2
1.1/1.2
1.3
1.4
1.5
1.6
2.1
2.2
2.3A
2.3B
3
4.1
4.2
4.3
5.1
5.2
6.1
7
8

	Must not be loaded, transported, or stored together in the same vehicle or facility.
	May be loaded, transported, or stored together.
	May be loaded, transported, or stored together only with restrictions.

Similar substances

UN / ID	Proper shipping name	Hazard class
UN 3487	Calcium hypochlorite, hydrated, corrosive or Calcium hypochlorite, hydrated mixture, corrosive with not less than 5.5% but not more than 16% water	5.1
UN 3485	Calcium hypochlorite, dry, corrosive or Calcium hypochlorite mixture, dry, corrosive with more than 39% available chlorine (8.8% available oxygen)	5.1
UN 2880	Calcium hypochlorite, hydrated or Calcium hypochlorite, hydrated mixture, with not less than 5.5% but not more than 16% water	5.1
UN 3486	Calcium hypochlorite mixture, dry, corrosive with more than 10% but not more than 39% available chlorine	5.1
UN 1748	Calcium hypochlorite, dry or Calcium hypochlorite mixture dry with more than 39% available chlorine (8.8% available oxygen)	5.1
UN 2208	Calcium hypochlorite mixture, dry, with more than 10% but not more than 39% available chlorine	5.1
UN 2907	Isosorbide dinitrate mixture with not less than 60 percent lactose, mannose, starch or calcium hydrogen phosphate	4.1
UN 1403	Calcium cyanamide with more than 0.1 percent of calcium carbide	4.3
UN 1574	Calcium arsenate and calcium arsenite, mixtures, solid	6.1
UN 1855	Calcium, pyrophoric or Calcium alloys, pyrophoric	4.2
UN 2429	Calcium chlorate aqueous solution	5.1
UN 1923	Calcium dithionite or Calcium hydrosulfite	4.2
UN 2844	Calcium manganese silicon	4.3
UN 1314	Calcium resinate, fused	4.1
UN 1573	Calcium arsenate	6.1