HazMat Tool — substance information
Reference only — not a shipping paper, placard mandate, or CVI record.
Difluorophosphoric acid, anhydrous
HMT 15 June 2026Difluorophosphoric acid, anhydrous
Difluorophosphoric acid is an inorganic compound with the formula HPO2F2. It is a mobile colorless strongly fuming liquid. The acid has limited applications, in part because it is thermally and hydrolytically unstable. Difluorophosphoric acid is corrosive to glass, fabric, metals and living tissue Wikipedia
| Emergency Response Guide No. 154 |
Hazardous Materials Table
Source: 49 CFR §172 (15 June 2026)(3) Hazard class8Corrosive liquids |
(4) Identification number |
(5) Packing Group |
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(6) Labels |
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(7) Special Provisions (§172.102)
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| A7 | |
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| B2 | |
| IB2 | |
| N5 | |
| N34 | |
| T8 | |
| TP2 |
(8) Packing Authorizations (§173.***) 
| (8A) Exceptions | 154 | see 49 CFR §173.154 |
|---|---|---|
| (8B) Non-bulk | 202 | see 49 CFR §173.202 |
| (8C) Bulk | 242 | see 49 CFR §173.242 |
(9) Quantity Limits 
| (9A) Passenger aircraft/rail | 1 L |
|---|---|
| (9B) Cargo aircraft only | 30 L |
(10) Vessel stowage 
| (10A) Location | |
|---|---|
| (10B) Other |
Segregation chart for load, transport, and storage
This chart shows whether loading, transport, or storage with other hazard classes is permitted, prohibited, or restricted. Based on 49 CFR §177.848.
Note: In this segregation and separation chart are HazMat of hazard class 8 considered depending if there are liquid. Currently HazMat Tool is not able to to check if a HazMat is liquid or not. Therefore it is assumed as liquid. See PHMSA Interpretation #09-0252.
| Hazard class | 8![]() | 7![]() | 6.1![]() | 5.2![]() | 5.1![]() | 4.3![]() | 4.2![]() | 4.1![]() | 3![]() | 2.3B![]() | 2.3A![]() | 2.2![]() | 2.1![]() | 1.6![]() | 1.5![]() | 1.4![]() | 1.3![]() | 1.1/1.2![]() |
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| Must not be loaded, transported, or stored together in the same vehicle or facility. | |
| May be loaded, transported, or stored together. | |
| May be loaded, transported, or stored together only with restrictions. |
Similar substances
| UN / ID | Proper shipping name | Hazard class |
|---|---|---|
| UN 1776 | Fluorophosphoric acid anhydrous | 8 |
| UN 1782 | Hexafluorophosphoric acid | 8 |

