HazMat Tool — substance information

Hexafluoroacetone hydrate, liquid

HMT 15 June 2026
Reference only — HMT snapshot for inspection and audit support; not a shipping paper, placard mandate, or CVI record. Use Print / PDF below for field notes.
UN / ID
UN 2552
Hazard class
6.1
Packing group
II
ERG guide
ERG 151
Special provisions
SP IB2, SP T7, SP TP2
Source
49 CFR §172 (15 June 2026)

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Hexafluoroacetone hydrate, liquid


Hexafluoroacetone (HFA) is a chemical compound with the formula (CF3)2CO. It is structurally similar to acetone; however, its reactivity is markedly different. It is a colourless, hygroscopic, nonflammable, highly reactive gas characterized by a musty odour. According to electron diffraction, HFA and acetone adopt very similar structures, the C-O distance being only longer in the fluorinated compound (124.6 vs 121.0 pm), possibly due to steric effects Wikipedia

Emergency Response Guide No. 151

Hazardous Materials Table

Source: 49 CFR §172 (15 June 2026)

(3) Hazard Class

6.1
Poisonous Material

(4) Identification number Help

UN 2552

(5) Packing Group Help

II

(6) Labels Help

Poisonous liquids PG I Zone A (6.1)

(7) Special Provisions (§172.102) Help

×Note:
Special provisions may be very complex. The extracts are taken from 49 CFR §172.102. Please be careful with the information, as necessary, additional conditions may be applied that are not written here. Please check the original source and report bugs.
IB2
T7
TP2

(8) Packing Authorizations (§173.***) Help

(8A) Exceptions153see 49 CFR §173.153
(8B) Non-bulk202see 49 CFR §173.202
(8C) Bulk243see 49 CFR §173.243

(9) Quantity Limits Help

(9A) Passenger aircraft/rail5 L
(9B) Cargo aircraft only60 L

(10) Vessel stowage Help

(10A) Location
(10B) Other

Segregation chart for load, transport, and storage

This chart shows whether loading, transport, or storage with other hazard classes is permitted, prohibited, or restricted. Based on 49 CFR §177.848.

Scope & sources (important)Click to show CFR references

This check evaluates segregation per 49 CFR §177.848. Additional loading/unloading and handling requirements may still apply; see 49 CFR §177 Subpart B (Loading and Unloading):

  • §177.834 - General requirements
  • §177.835 - Class 1 materials
  • §177.837 - Class 3 materials
  • §177.838 - Class 4 (flammable solid) materials, Class 5 (oxidizing) materials, and Division 4.2 (pyroforic liquid) materials
  • §177.839 - Class 8 (corrosive) materials
  • §177.840 - Class 2 (gases) materials
  • §177.841 - Division 6.1 and Division 2.3 materials
  • §177.842 - Class 7 (radioactive) material
  • §177.843 - Contamination of vehicles