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Carbamate pesticides, liquid, flammable, toxic, flash point less than 23 degrees C

HMT 15 June 2026

UN / ID: UN 2758
Hazard class: 3
Packing group: I (multiple — see tabs)
ERG guide: ERG 131
Special provisions: SP T14, SP TP2, SP TP13, SP TP27
Source: 49 CFR §172 (15 June 2026)

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Carbamate pesticides, liquid, flammable, toxic, flash point less than 23 degrees C

In organic chemistry, a carbamate is a category of organic compounds with the general formula R2NC(O)OR and structure >N−C(=O)−O−, which are formally derived from carbamic acid (NH2COOH). The term includes organic compounds (e.g., the ester ethyl carbamate), formally obtained by replacing one or more of the hydrogen atoms by other organic functional groups; as well as salts with the carbamate anion H2NCOO− (e.g. ammonium carbamate). Polymers whose repeat units are joined by carbamate like groups −NH−C(=O)−O− are an important family of plastics, the polyurethanes Wikipedia

Substance Data

Source: PubChem (HSDB, 06.12.2019)

CAS-Number

101-21-3

Flash Point

—

Boiling Point

—

Emergency Response Guide No. 131

Hazardous Materials Table

Source: 49 CFR §172 (15 June 2026)

Packing group I
Packing group II

(3) Hazard class

3
Flammable liquids

(4) Identification number

UN 2758

(5) Packing Group

Comparison View of PG

(6) Labels

Cargo Aircraft Only (Cargo Aircraft Only)

(7) Special Provisions (§172.102)

×Note:
Special provisions may be very complex. The extracts are taken from 49 CFR §172.102. Please be careful with the information, as necessary, additional conditions may be applied that are not written here. Please check the original source and report bugs.

T14

Minimum test pressure (bar)	6
Minimum shell thickness	6 mm
Pressure-relief requirements	§ 178.275(g)(3)
Bottom opening requirements	Prohibited

Browse special provision T14

TP2

a. The maximum degree of filling must not exceed the degree of filling determined by the following:
TP2a

Where:
t_r is the maximum mean bulk temperature during transport,
t_f is the temperature in degrees celsius of the liquid during filling, and
α is the mean coefficient of cubical expansion of the liquid between the mean temperature of the liquid during filling (t_f) and the maximum mean bulk temperature during transportation (t_r) both in degrees celsius.
b. For liquids transported under ambient conditions α may be calculated using the formula:
TP2b

Where:
d₁₅ and d₅₀ are the densities (in units of mass per unit volume) of the liquid at 15 °C (59 °F) and 50 °C (122 °F), respectively.

Browse special provision TP2

TP13

Self-contained breathing apparatus must be provided when this hazardous material is transported by sea.

Browse special provision TP13

TP27

A portable tank having a minimum test pressure of 4 bar (400 kPa) may be used provided the calculated test pressure is 4 bar or less based on the MAWP of the hazardous material, as defined in § 178.275 of this subchapter, where the test pressure is 1.5 times the MAWP.

Browse special provision TP27

(8) Packing Authorizations (§173.***)

(8A) Exceptions	None
(8B) Non-bulk	201	see 49 CFR §173.201
(8C) Bulk	243	see 49 CFR §173.243

(9) Quantity Limits

(9A) Passenger aircraft/rail	Forbidden
(9B) Cargo aircraft only	30 L

(10) Vessel stowage

(10A) Location

Stowage category “B” means

(i) The material may be stowed “on deck” or “under deck” on a cargo vessel and on a passenger vessel carrying a number of passengers limited to not more than the larger of 25 passengers, or one passenger per each 3 m of overall vessel length; and
(ii) “On deck only” on passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this section is exceeded.

Source: 49 CFR §172.101(k)

(10B) Other

40	see 49 CFR §176.84

Source: 49 CFR §176.84

(3) Hazard class

3
Flammable liquids

(4) Identification number

UN 2758

(5) Packing Group

Comparison View of PG

(6) Labels

(7) Special Provisions (§172.102)

IB2

_{Authorized IBCs:} Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1).
_{Additional Requirement:} Only liquids with a vapor pressure less than or equal to 110 kPa at 50 °C (1.1 bar at 122 °F), or 130 kPa at 55 °C (1.3 bar at 131 °F) are authorized.

Browse special provision IB2

T11

Minimum test pressure (bar)	6
Minimum shell thickness	§ 178.274(d)(2)
Pressure-relief requirements	Normal
Bottom opening requirements	§ 178.275(d)(3)

Browse special provision T11

TP2

a. The maximum degree of filling must not exceed the degree of filling determined by the following:
TP2a

Where:
d₁₅ and d₅₀ are the densities (in units of mass per unit volume) of the liquid at 15 °C (59 °F) and 50 °C (122 °F), respectively.

Browse special provision TP2

TP13

Self-contained breathing apparatus must be provided when this hazardous material is transported by sea.

Browse special provision TP13

TP27

Browse special provision TP27

(8) Packing Authorizations (§173.***)

(8A) Exceptions	150	see 49 CFR §173.150
(8B) Non-bulk	202	see 49 CFR §173.202
(8C) Bulk	243	see 49 CFR §173.243

(9) Quantity Limits

(9A) Passenger aircraft/rail	1 L
(9B) Cargo aircraft only	60 L

(10) Vessel stowage

(10A) Location

Stowage category “B” means

(i) The material may be stowed “on deck” or “under deck” on a cargo vessel and on a passenger vessel carrying a number of passengers limited to not more than the larger of 25 passengers, or one passenger per each 3 m of overall vessel length; and
(ii) “On deck only” on passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this section is exceeded.

Source: 49 CFR §172.101(k)

(10B) Other

40	see 49 CFR §176.84

Source: 49 CFR §176.84

Packing group comparison

Multiple packing groups apply to this entry. See assignment criteria in 49 CFR §173 Subpart D. Details are in the tabs above; differences are highlighted.

	PG I	PG II
1
2	Carbamate pesticides, liquid, flammable, toxic, flash point less than 23 degrees C	Carbamate pesticides, liquid, flammable, toxic, flash point less than 23 degrees C
3	3	3
4	UN 2758	UN 2758
5	I	II
6	3, 6.1	3, 6.1
7	T14, TP2, TP13, TP27	IB2, T11, TP2, TP13, TP27
8A	None	150
8B	201	202
8C	243	243
9A	Forbidden	1 L
9B	30 L	60 L
10A	B	B
10B	40	40

Segregation chart for load, transport, and storage

This chart shows whether loading, transport, or storage with other hazard classes is permitted, prohibited, or restricted. Based on 49 CFR §177.848.

Hazard class	8	7	6.1	5.2	5.1	4.3	4.2	4.1	3	2.3B	2.3A	2.2	2.1	1.6	1.5	1.4	1.3	1.1/1.2
1.1/1.2
1.3
1.4
1.5
1.6
2.1
2.2
2.3A
2.3B
3
4.1
4.2
4.3
5.1
5.2
6.1
7
8

	Must not be loaded, transported, or stored together in the same vehicle or facility.
	May be loaded, transported, or stored together.
	May be loaded, transported, or stored together only with restrictions.

Similar substances

UN / ID	Proper shipping name	Hazard class
UN 2776	Copper based pesticides, liquid, flammable, toxic, flash point less than 23 degrees C	3
UN 3019	Organotin pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C	6.1
UN 2903	Pesticides, liquid, toxic, flammable, n.o.s. flash point not less than 23 degrees C	6.1
UN 2997	Triazine pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C	6.1
UN 2772	Thiocarbamate pesticide, liquid, flammable, toxic, flash point less than 23 degrees C	3
UN 2760	Arsenical pesticides, liquid, flammable, toxic, flash point less than 23 degrees C	3
UN 2782	Bipyridilium pesticides, liquid, flammable, toxic, flash point less than 23 degrees C	3
UN 2787	Organotin pesticides, liquid, flammable, toxic, flash point less than 23 degrees C	3
UN 2764	Triazine pesticides, liquid, flammable, toxic, flash point less than 23 degrees C	3
UN 3021	Pesticides, liquid, flammable, toxic, flash point less than 23 degrees C	3
UN 3350	Pyrethroid pesticide, liquid, flammable, toxic, flash point less than 23 degrees C	3
UN 2771	Thiocarbamate pesticides, solid, toxic	6.1
UN 2992	Carbamate pesticides, liquid, toxic	6.1
UN 3010	Copper based pesticides, liquid, toxic	6.1
UN 3026	Coumarin derivative pesticides, liquid, toxic	6.1