Self-heating liquid, toxic, inorganic, n.o.s
HMT 15 June 2026- UN / ID
- UN 3187
- Hazard class
- 4.2
- Packing group
- II (multiple — see tabs)
- ERG guide
- ERG 136
- Special provisions
- SP IB2, SP W31
- Source
- 49 CFR §172 (15 June 2026)
Self-heating liquid, toxic, inorganic, n.o.s
Self-heating food packaging is active packaging with the ability to heat food contents without external heat sources or power, usually using an exothermic chemical reaction. Packets can also be self-cooling. These packages are useful for military operations, during natural disasters, or whenever conventional cooking is not available. They are often used for military field rations, camping food, instant food, or other types of food intended for preparation where proper cooking facilities or methods are unavailable or less ideal Wikipedia
| Emergency Response Guide No. 136 |
Hazardous Materials Table
Source: 49 CFR §172 (15 June 2026)(3) Hazard Class4.2Spontaneously combustible materials |
(4) Identification number |
(5) Packing Group |
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(6) Labels |
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(1) Symbols |
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| IB2 | |
|---|---|
| W31 |
(8) Packing Authorizations (§173.***) 
| (8A) Exceptions | None | |
|---|---|---|
| (8B) Non-bulk | 202 | see 49 CFR §173.202 |
| (8C) Bulk | 243 | see 49 CFR §173.243 |
(9) Quantity Limits 
| (9A) Passenger aircraft/rail | 1 L |
|---|---|
| (9B) Cargo aircraft only | 5 L |
(10) Vessel stowage 
| (10A) Location | |
|---|---|
| (10B) Other | n/a |
(3) Hazard Class4.2Spontaneously combustible materials |
(4) Identification number |
(5) Packing Group |
||||||||
(6) Labels |
||||||||||
(1) Symbols |
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| IB2 | |
|---|---|
| W31 |
(8) Packing Authorizations (§173.***) 
| (8A) Exceptions | None | |
|---|---|---|
| (8B) Non-bulk | 203 | see 49 CFR §173.203 |
| (8C) Bulk | 241 | see 49 CFR §173.241 |
(9) Quantity Limits 
| (9A) Passenger aircraft/rail | 5 L |
|---|---|
| (9B) Cargo aircraft only | 60 L |
(10) Vessel stowage 
| (10A) Location | |
|---|---|
| (10B) Other | n/a |
Packing group comparison
Multiple packing groups apply to this entry. See assignment criteria in 49 CFR §173 Subpart D. Details are in the tabs above; differences are highlighted.
Segregation chart for load, transport, and storage
This chart shows whether loading, transport, or storage with other hazard classes is permitted, prohibited, or restricted. Based on 49 CFR §177.848.
| Hazard class | 8![]() | 7![]() | 6.1![]() | 5.2![]() | 5.1![]() | 4.3![]() | 4.2![]() | 4.1![]() | 3![]() | 2.3B![]() | 2.3A![]() | 2.2![]() | 2.1![]() | 1.6![]() | 1.5![]() | 1.4![]() | 1.3![]() | 1.1/1.2![]() |
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1.3 ![]() | ||||||||||||||||||
1.4 ![]() | ||||||||||||||||||
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1.6 ![]() | ||||||||||||||||||
2.1 ![]() | ||||||||||||||||||
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2.3A ![]() | ||||||||||||||||||
2.3B ![]() | ||||||||||||||||||
3 ![]() | ||||||||||||||||||
4.1 ![]() | ||||||||||||||||||
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5.1 ![]() | ||||||||||||||||||
5.2 ![]() | ||||||||||||||||||
6.1 ![]() | ||||||||||||||||||
7 ![]() | ||||||||||||||||||
8 ![]() |
| Must not be loaded, transported, or stored together in the same vehicle or facility. | |
| May be loaded, transported, or stored together. | |
| May be loaded, transported, or stored together only with restrictions. |