Emergency Response Guide No. 147 for LITHIUM ION BATTERIES


Source: Emergency Response Guidebook (ERG)
POTENTIAL HAZARDS

FIRE OR EXPLOSION
  • Lithium ion batteries contain flammable liquid electrolyte that may vent, ignite and produce sparks when subjected to high temperatures (> 150 °C (302 °F)), when damaged or abused (e.g., mechanical damage or electrical overcharging).
  • May burn rapidly with flare-burning effect.
  • May ignite other batteries in close proximity.
HEALTH
  • Contact with battery electrolyte may be irritating to skin, eyes and mucous membranes.
  • Fire will produce irritating, corrosive and/or toxic gases.
  • Burning batteries may produce toxic hydrogen fluoride gas (see GUIDE 125).
  • Fumes may cause dizziness or suffocation.
PUBLIC SAFETY

  • CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.
  • As an immediate precautionary measure, isolate spill or leak area for at least 25 meters (75 feet) in all directions.
  • Keep unauthorized personnel away.
  • Stay upwind, uphill and/or upstream.
  • Ventilate closed spaces before entering.
PROTECTIVE CLOTHING
  • Wear positive pressure self-contained breathing apparatus (SCBA).
  • Structural firefighters' protective clothing will only provide limited protection.
EVACUATION
Large Spill
  • Consider initial downwind evacuation for at least 100 meters (330 feet).
Fire
  • If rail car or trailer is involved in a fire, ISOLATE for 500 meters (1/3 mile) in all directions; also initiate evacuation including emergency responders for 500 meters (1/3 mile) in all directions.
EMERGENCY RESPONSE

FIRE
Small Fire
  • Dry chemical, CO2, water spray or regular foam.
Large Fire
  • Water spray, fog or regular foam.
  • Move containers from fire area if you can do it without risk.
SPILL OR LEAK
  • ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).
  • Do not touch or walk through spilled material.
  • Absorb with earth, sand or other non-combustible material.
  • Leaking batteries and contaminated absorbent material should be placed in metal containers.
FIRST AID
  • Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves.
  • Move victim to fresh air.
  • Call 911 or emergency medical service.
  • Give artificial respiration if victim is not breathing.
  • Administer oxygen if breathing is difficult.
  • Remove and isolate contaminated clothing and shoes.
  • In case of contact with substance, immediately flush skin or eyes with running water for at least 20 minutes.