HazMat Tool — substance information

Methyl formate

HMT 15 June 2026
Reference only — HMT snapshot for inspection and audit support; not a shipping paper, placard mandate, or CVI record. Use Print / PDF below for field notes.
UN / ID
UN 1243
Hazard class
3
Packing group
I (multiple — see tabs)
ERG guide
ERG 129
Special provisions
SP T11, SP TP2
Source
49 CFR §172 (15 June 2026)

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Methyl formate


Methyl formate, also called methyl methanoate, is the methyl ester of formic acid. It has the chemical formula HCOOCH3. The simplest example of a carboxylate ester, it is a colourless liquid with an ethereal odour, high vapor pressure, and low surface tension. It is a precursor to many other compounds of commercial interest Wikipedia

Substance Data

Source: PubChem (HSDB, 26.11.2019)

CAS-Number

107-31-3

Flash Point

n/a

Boiling Point

n/a

Emergency Response Guide No. 129

Hazardous Materials Table

Source: 49 CFR §172 (15 June 2026)

(3) Hazard Class

3
Flammable liquids

(4) Identification number Help

UN 1243

(5) Packing Group Help

I

(6) Labels Help

Flammable liquids (3)

(7) Special Provisions (§172.102) Help

×Note:
Special provisions may be very complex. The extracts are taken from 49 CFR §172.102. Please be careful with the information, as necessary, additional conditions may be applied that are not written here. Please check the original source and report bugs.
T11
TP2

(8) Packing Authorizations (§173.***) Help

(8A) Exceptions150see 49 CFR §173.150
(8B) Non-bulk201see 49 CFR §173.201
(8C) Bulk243see 49 CFR §173.243

(9) Quantity Limits Help

(9A) Passenger aircraft/rail1 L
(9B) Cargo aircraft only30 L

(10) Vessel stowage Help

(10A) Location
(10B) Other n/a

(3) Hazard Class

3
Flammable liquids

(4) Identification number Help

UN 1190

(5) Packing Group Help

II

(6) Labels Help

Flammable liquids (3)

(7) Special Provisions (§172.102) Help

×Note:
Special provisions may be very complex. The extracts are taken from 49 CFR §172.102. Please be careful with the information, as necessary, additional conditions may be applied that are not written here. Please check the original source and report bugs.
IB2
T4
TP1

(8) Packing Authorizations (§173.***) Help

(8A) Exceptions150see 49 CFR §173.150
(8B) Non-bulk202see 49 CFR §173.202
(8C) Bulk242see 49 CFR §173.242

(9) Quantity Limits Help

(9A) Passenger aircraft/rail5 L
(9B) Cargo aircraft only60 L

(10) Vessel stowage Help

(10A) Location
(10B) Other n/a

Packing group comparison

Multiple packing groups apply to this entry. See assignment criteria in 49 CFR §173 Subpart D. Details are in the tabs above; differences are highlighted.

PG I PG II
1
2Methyl formateEthyl formate
333
4UN 1243UN 1190
5III
633
7T11, TP2IB2, T4, TP1
8A150150
8B201202
8C243242
9A1 L5 L
9B30 L60 L
10AEE
10B n/a n/a

Segregation chart for load, transport, and storage

This chart shows whether loading, transport, or storage with other hazard classes is permitted, prohibited, or restricted. Based on 49 CFR §177.848.

Prohibited Must not be loaded, transported, or stored together in the same vehicle or facility.
Permitted May be loaded, transported, or stored together.
Restricted May be loaded, transported, or stored together only with restrictions.