HazMat Tool — substance information

Ethylenediamine

HMT May 2026

UN / ID: UN 1604
Hazard class: 8
Packing group: II
ERG guide: ERG 132
Special provisions: SP IB2, SP T7, SP TP2
Source: 49 CFR §172 (2026/05)

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Ethylenediamine

Ethylenediamine (abbreviated as en when a ligand) is the organic compound with the formula C2H4(NH2)2. This colorless liquid with an ammonia-like odor is a basic amine. It is a widely used building block in chemical synthesis, with approximately 500,000 tonnes produced in 1998. Ethylenediamine is the first member of the so-called polyethylene amines. Wikipedia

Substance Data

Source: PubChem

CAS-Number

107-15-3

Flash Point

n/a

Boiling Point

n/a

Emergency Response Guide No. 132

Hazardous Materials Table

Source: 49 CFR §172 (2026/05)

(3) Hazard Class

8
Corrosive liquids

(4) Identification number

UN 1604

(5) Packing Group

(6) Labels

(7) Special Provisions (§172.102)

×Note:
Special provisions may be very complex. The extracts are taken from 49 CFR §172.102. Please be careful with the information, as necessary, additional conditions may be applied that are not written here. Please check the original source and report bugs.

IB2

Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1).
Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 °C (1.1 bar at 122 °F), or 130 kPa at 55 °C (1.3 bar at 131 °F) are authorized.

Browse special provision IB2

Minimum test pressure (bar)	4
Minimum shell thickness	§ 178.274(d)(2)
Pressure-relief requirements	Normal
Bottom opening requirements	§ 178.275(d)(3)

Browse special provision T7

TP2

a. The maximum degree of filling must not exceed the degree of filling determined by the following:
TP2a

Where:
t_r is the maximum mean bulk temperature during transport,
t_f is the temperature in degrees celsius of the liquid during filling, and
α is the mean coefficient of cubical expansion of the liquid between the mean temperature of the liquid during filling (t_f) and the maximum mean bulk temperature during transportation (t_r) both in degrees celsius.
b. For liquids transported under ambient conditions α may be calculated using the formula:
TP2b

Where:
d₁₅ and d₅₀ are the densities (in units of mass per unit volume) of the liquid at 15 °C (59 °F) and 50 °C (122 °F), respectively.

Browse special provision TP2

(8) Packing Authorizations (§173.***)

(8A) Exceptions	154	see 49 CFR §173.154
(8B) Non-bulk	202	see 49 CFR §173.202
(8C) Bulk	243	see 49 CFR §173.243

(9) Quantity Limits

(9A) Passenger aircraft/rail	1 L
(9B) Cargo aircraft only	30 L

(10) Vessel stowage

(10A) Location

Stowage category “A” means the material may be stowed “on deck” or “under deck” on a cargo vessel or on a passenger vessel.

Source: 49 CFR §172.101(k)

(10B) Other

40	see 49 CFR §176.84
52	see 49 CFR §176.84

Source: 49 CFR §176.84

Segregation chart for load, transport, and storage

This chart shows whether loading, transport, or storage with other hazard classes is permitted, prohibited, or restricted. Based on 49 CFR §177.848.

Note: In this segregation and separation chart are HazMat of hazard class 8 considered depending if there are liquid. Currently HazMat Tool is not able to to check if a HazMat is liquid or not. Therefore it is assumed as liquid. See PHMSA Interpretation #09-0252.

Hazard class	8	7	6.1	5.2	5.1	4.3	4.2	4.1	3	2.3B	2.3A	2.2	2.1	1.6	1.5	1.4	1.3	1.1/1.2
1.1/1.2
1.3
1.4
1.5
1.6
2.1
2.2
2.3A
2.3B
3
4.1
4.2
4.3
5.1
5.2
6.1
7
8

	Must not be loaded, transported, or stored together in the same vehicle or facility.
	May be loaded, transported, or stored together.
	May be loaded, transported, or stored together only with restrictions.

Similar substances

UN / ID	Proper shipping name	Hazard class
UN 3138	Ethylene, acetylene and propylene in mixture, refrigerated liquid with at least 71.5 percent ethylene with not more than 22.5 percent acetylene and not more than 6 percent propylene	2.1
UN 0072	Cyclotrimethylenetrinitramine, wetted or Cyclonite, wetted or Hexogen, wetted or RDX, wetted with not less than 15 percent water by mass	1.1D
UN 1040	Ethylene oxide or Ethylene oxide with nitrogen up to a total pressure of 1 MPa (10 bar) at 50 degrees C	2.3
UN 1041	Ethylene oxide and carbon dioxide mixtures with more than 9 percent but not more than 87 percent ethylene oxide	2.1
UN 0226	Cyclotetramethylenetetranitramine, wetted or HMX, wetted or Octogen, wetted with not less than 15 percent water, by mass	1.1D
UN 0075	Diethyleneglycol dinitrate, desensitized with not less than 25 percent non-volatile water-insoluble phlegmatizer, by mass	1.1D
UN 1952	Ethylene oxide and carbon dioxide mixtures with not more than 9 percent ethylene oxide	2.2
UN 2983	Ethylene oxide and propylene oxide mixtures, with not more than 30 percent ethylene oxide	3
UN 3300	Ethylene oxide and carbon dioxide mixture with more than 87 percent ethylene oxide	2.3
UN 3297	Ethylene oxide and chlorotetrafluoroethane mixture with not more than 8.8 percent ethylene oxide	2.2
UN 3070	Ethylene oxide and dichlorodifluoromethane mixture, with not more than 12.5 percent ethylene oxide	2.2
UN 3298	Ethylene oxide and pentafluoroethane mixture with not more than 7.9 percent ethylene oxide	2.2
UN 3299	Ethylene oxide and tetrafluoroethane mixture with not more than 5.6 percent ethylene oxide	2.2
UN 0483	Cyclotrimethylenetrinitramine, desensitized or Cyclonite, desensitized or Hexogen, desensitized or RDX, desensitized	1.1D
UN 1761	Cupriethylenediamine solution	8