HazMat Tool — substance information Reference only — not a shipping paper, placard mandate, or CVI record.

Toluidines, solid

HMT 15 June 2026

UN / ID: UN 3451
Hazard class: 6.1
Packing group: II (multiple — see tabs)
ERG guide: ERG 153
Special provisions: SP IB8, SP IP2, SP IP4, SP T3, SP TP33
Source: 49 CFR §172 (15 June 2026)

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Toluidines, solid

There are three isomers of toluidine, which are organic compounds discovered and named by James Sheridan Muspratt and August Wilhelm von Hofmann in 1845. These isomers are o-toluidine, m-toluidine, and p-toluidine, with the prefixed letter abbreviating, respectively, ortho; meta; and para. All three are aryl amines whose chemical structures are similar to aniline except that a methyl group is substituted onto the benzene ring. The difference between these three isomers is the position where the methyl group (–CH3) is bonded to the ring relative to the amino functional group (–NH2); see illustration of the chemical structures below Wikipedia

Emergency Response Guide No. 153

Hazardous Materials Table

Source: 49 CFR §172 (15 June 2026)

Packing group II
Packing group III
Packing group

(3) Hazard class

6.1
Poisonous Material

(4) Identification number

UN 3451

(5) Packing Group

Comparison View of PG

(6) Labels

(7) Special Provisions (§172.102)

×Note:
Special provisions may be very complex. The extracts are taken from 49 CFR §172.102. Please be careful with the information, as necessary, additional conditions may be applied that are not written here. Please check the original source and report bugs.

IB8

_{Authorized IBCs:} Metal (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B and 31N); Rigid plastics (11H1, 11H2, 21H1, 21H2, 31H1 and 31H2 ); Composite (11HZ1, 11HZ2, 21HZ1, 21HZ2 and 31HZ1); Fiberboard (11G); Wooden (11C, 11D and 11F); Flexible (13H1, 13H2, 13H3, 13H4, 13H5, 13L1, 13L2, 13L3, 13L4, 13M1 or 13M2).

Browse special provision IB8

IP2

When IBCs other than metal or rigid plastics IBCs are used, they must be offered for transportation in a closed freight container or a closed transport vehicle.

Browse special provision IP2

IP4

Flexible, fiberboard or wooden IBCs must be sift-proof and water-resistant or be fitted with a sift-proof and water-resistant liner.

Browse special provision IP4

Minimum test pressure (bar)	2.65
Minimum shell thickness	§ 178.274(d)(2)
Pressure-relief requirements	Normal
Bottom opening requirements	§ 178.275(d)(2)

Browse special provision T3

TP33

The portable tank instruction assigned for this substance applies for granular and powdered solids and for solids which are filled and discharged at temperatures above their melting point which are cooled and transported as a solid mass. Solid substances transported or offered for transport above their melting point are authorized for transportation in portable tanks conforming to the provisions of portable tank instruction T4 for solid substances of packing group III or T7 for solid substances of packing group II, unless a tank with more stringent requirements for minimum shell thickness, maximum allowable working pressure, pressure-relief devices or bottom outlets are assigned in which case the more stringent tank instruction and special provisions shall apply. Filling limits must be in accordance with portable tank special provision TP3. Solids meeting the definition of an elevated temperature material must be transported in accordance with the applicable requirements of this subchapter.

Browse special provision TP33

(8) Packing Authorizations (§173.***)

(8A) Exceptions	153	see 49 CFR §173.153
(8B) Non-bulk	212	see 49 CFR §173.212
(8C) Bulk	242	see 49 CFR §173.242

(9) Quantity Limits

(9A) Passenger aircraft/rail	25 kg
(9B) Cargo aircraft only	100 kg

(10) Vessel stowage

(10A) Location	A Stowage category “A” means the material may be stowed “on deck” or “under deck” on a cargo vessel or on a passenger vessel. Source: 49 CFR §172.101(k)
(10B) Other	—

(3) Hazard class

6.1
Poisonous Material

(4) Identification number

UN 2239

(5) Packing Group

III

Comparison View of PG

(6) Labels

(7) Special Provisions (§172.102)

IB8

Browse special provision IB8

IP3

Flexible IBCs must be sift-proof and water-resistant or must be fitted with a sift-proof and water-resistant liner.

Browse special provision IP3

Minimum test pressure (bar)	1.5
Minimum shell thickness	§ 178.274(d)(2)
Pressure-relief requirements	Normal
Bottom opening requirements	§ 178.275(d)(2)

Browse special provision T1

TP33

Browse special provision TP33

(8) Packing Authorizations (§173.***)

(8A) Exceptions	153	see 49 CFR §173.153
(8B) Non-bulk	213	see 49 CFR §173.213
(8C) Bulk	240	see 49 CFR §173.240

(9) Quantity Limits

(9A) Passenger aircraft/rail	100 kg
(9B) Cargo aircraft only	200 kg

(10) Vessel stowage

(10A) Location	A Stowage category “A” means the material may be stowed “on deck” or “under deck” on a cargo vessel or on a passenger vessel. Source: 49 CFR §172.101(k)
(10B) Other	—

(3) Hazard class

6.1
Poisonous Material

(4) Identification number

UN 3460

(5) Packing Group

III

Comparison View of PG

(6) Labels

(7) Special Provisions (§172.102)

IB8

Browse special provision IB8

IP3

Flexible IBCs must be sift-proof and water-resistant or must be fitted with a sift-proof and water-resistant liner.

Browse special provision IP3

Minimum test pressure (bar)	1.5
Minimum shell thickness	§ 178.274(d)(2)
Pressure-relief requirements	Normal
Bottom opening requirements	§ 178.275(d)(2)

Browse special provision T1

TP33

Browse special provision TP33

(8) Packing Authorizations (§173.***)

(8A) Exceptions	153	see 49 CFR §173.153
(8B) Non-bulk	213	see 49 CFR §173.213
(8C) Bulk	240	see 49 CFR §173.240

(9) Quantity Limits

(9A) Passenger aircraft/rail	100 kg
(9B) Cargo aircraft only	200 kg

(10) Vessel stowage

(10A) Location	A Stowage category “A” means the material may be stowed “on deck” or “under deck” on a cargo vessel or on a passenger vessel. Source: 49 CFR §172.101(k)
(10B) Other	—

Packing group comparison

Multiple packing groups apply to this entry. See assignment criteria in 49 CFR §173 Subpart D. Details are in the tabs above; differences are highlighted.

	PG II	PG III	PG III
1
2	Toluidines, solid	Chlorotoluidines, solid	N-Ethylbenzyltoluidines, solid
3	6.1	6.1	6.1
4	UN 3451	UN 2239	UN 3460
5	II	III	III
6	6.1	6.1	6.1
7	IB8, IP2, IP4, T3, TP33	IB8, IP3, T1, TP33	IB8, IP3, T1, TP33
8A	153	153	153
8B	212	213	213
8C	242	240	240
9A	25 kg	100 kg	100 kg
9B	100 kg	200 kg	200 kg
10A	A	A	A
10B	—	—	—

Segregation chart for load, transport, and storage

This chart shows whether loading, transport, or storage with other hazard classes is permitted, prohibited, or restricted. Based on 49 CFR §177.848.

Note: The HMR prohibit only those Division 6.1 liquids that meet the definition of a Packing Group (PG) I and Hazard Zone A. See special provision 1 and PHMSA Interpretation #09-0252.

Packages with POISON or POISON INHALATION HAZARD labels, or a POISON label displaying “PG III,” or “PG III” marked next to a POISON label may not be transported with foodstuffs, feed or any other edible material, intended for humans or animals. For exceptions see 49 CFR §177.841(e).

Scope & sources (important)Click to show CFR references

This check evaluates segregation per 49 CFR §177.848. Additional loading/unloading and handling requirements may still apply; see 49 CFR §177 Subpart B (Loading and Unloading):

§177.834 - General requirements
§177.835 - Class 1 materials
§177.837 - Class 3 materials
§177.838 - Class 4 (flammable solid) materials, Class 5 (oxidizing) materials, and Division 4.2 (pyroforic liquid) materials
§177.839 - Class 8 (corrosive) materials
§177.840 - Class 2 (gases) materials
§177.841 - Division 6.1 and Division 2.3 materials
§177.842 - Class 7 (radioactive) material
§177.843 - Contamination of vehicles

Similar substances

UN / ID	Proper shipping name	Hazard class
UN 2753	N-Ethylbenzyltoluidines liquid	6.1
UN 3438	alpha-Methylbenzyl alcohol, solid	6.1
UN 2937	alpha-Methylbenzyl alcohol, liquid	6.1