HazMat Tool — substance information
Chlorine trifluoride
HMT 15 June 2026Chlorine trifluoride
Chlorine trifluoride is an interhalogen compound with the formula ClF3. It is a colorless, poisonous, corrosive, and extremely reactive gas that condenses to a pale-greenish yellow liquid, the form in which it is most often sold (pressurized at room temperature). It is notable for its extreme oxidation properties. The compound is primarily of interest in plasmaless cleaning and etching operations in the semiconductor industry, in nuclear reactor fuel processing, historically as a component in rocket fuels, and various other industrial operations owing to its corrosive nature. Wikipedia
Substance Data
Source: PubChem (HSDB, 04.12.2019)CAS-Number7790-91-2 |
Flash Pointn/a | Boiling Pointn/a |
| Emergency Response Guide No. 124 |
Hazardous Materials Table
Source: 49 CFR §172 (15 June 2026)(3) Hazard Class2.3Poisonous gas |
(4) Identification number |
(5) Packing Group |
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(6) Labels |
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(7) Special Provisions (§172.102)
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| 2 | |
|---|---|
| B7 | |
| B9 | |
| B14 | |
| N86 |
(8) Packing Authorizations (§173.***) 
| (8A) Exceptions | None | |
|---|---|---|
| (8B) Non-bulk | 304 | see 49 CFR §173.304 |
| (8C) Bulk | 314 | see 49 CFR §173.314 |
(9) Quantity Limits 
| (9A) Passenger aircraft/rail | Forbidden |
|---|---|
| (9B) Cargo aircraft only | Forbidden |
(10) Vessel stowage 
| (10A) Location | |
|---|---|
| (10B) Other |
Segregation chart for load, transport, and storage
This chart shows whether loading, transport, or storage with other hazard classes is permitted, prohibited, or restricted. Based on 49 CFR §177.848.
Note: In this segregation and separation chart are HazMat of hazard class 2.3 considered depending on their poisonousness by inhalation (Hazard zone B). See special provision 2 and PHMSA Interpretation #09-0252.
| Hazard class | 8![]() | 7![]() | 6.1![]() | 5.2![]() | 5.1![]() | 4.3![]() | 4.2![]() | 4.1![]() | 3![]() | 2.3B![]() | 2.3A![]() | 2.2![]() | 2.1![]() | 1.6![]() | 1.5![]() | 1.4![]() | 1.3![]() | 1.1/1.2![]() |
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8 ![]() |
| Must not be loaded, transported, or stored together in the same vehicle or facility. | |
| May be loaded, transported, or stored together. | |
| May be loaded, transported, or stored together only with restrictions. |