Sulfuric acid, fuming with 30 percent or more free sulfur trioxide

Sulfuric acid (American spelling and the preferred IUPAC name) or sulphuric acid (Commonwealth spelling), known in antiquity as oil of vitriol, is a mineral acid composed of the elements sulfur, oxygen, and hydrogen, with the molecular formula H2SO4. It is a colorless, odorless, and viscous liquid that is miscible with water. Pure sulfuric acid does not occur naturally due to its strong affinity to water vapor; it is hygroscopic and readily absorbs water vapor from the air. Concentrated sulfuric acid is a strong oxidant with powerful dehydrating properties, making it highly corrosive towards other materials, from rocks to metals. Phosphorus pentoxide is a notable exception in that it is not dehydrated by sulfuric acid but, to the contrary, dehydrates sulfuric acid to sulfur trioxide Wikipedia

Substance Data

Hazardous Materials Table

• Packing group I
• Packing group II

(3) Hazard Class 8 Corrosive liquids	(4) Identification number UN 1831	(5) Packing Group I Comparison View of PG
(6) Labels
(7) Special Provisions (§172.102) ×Note: Special provisions may be very complex. The extracts are taken from 49 CFR §172.102. Please be careful with the information, as necessary, additional conditions may be applied that are not written here. Please check the original source and report bugs. 2 This material is poisonous by inhalation (see § 171.8 of this subchapter) in Hazard Zone B (see § 173.116(a) or § 173.133(a) of this subchapter), and must be described as an inhalation hazard under the provisions of this subchapter. Browse special provision 2 B9 Bottom outlets are not authorized. Browse special provision B9 B14 Each bulk packaging, except a tank car or a multi-unit-tank car tank, must be insulated with an insulating material so that the overall thermal conductance at 15.5 °C (60 °F) is no more than 1.5333 kilojoules per hour per square meter per degree Celsius (0.075 Btu per hour per square foot per degree Fahrenheit) temperature differential. Insulating materials must not promote corrosion to steel when wet. Browse special provision B14 B32 MC 312, MC 330, MC 331, DOT 412 cargo tanks and DOT 51 portable tanks must be made of stainless steel, except that steel other than stainless steel may be used in accordance with the provisions of § 173.24b(b) of this subchapter. Thickness of stainless steel for tank shell and heads for cargo tanks and portable tanks must be the greater of 6.35 mm (0.250 inch) or the thickness required for a tank with a design pressure at least equal to 1.3 times the vapor pressure of the lading at 46 °C (115 °F). In addition, MC 312 and DOT 412 cargo tank motor vehicles must: a. Be ASME Code (U) stamped for 100% radiography of all pressure-retaining welds; b. Have accident damage protection which conforms with § 178.345-8 of this subchapter; c. Have a MAWP or design pressure of at least 87 psig; and d. Have a bolted manway cover. Browse special provision B32 B77 Other packaging are authorized when approved by the Associate Administrator. Browse special provision B77 B84 Packagings must be protected with non-metallic linings impervious to the lading or have a suitable corrosion allowance for sulfuric acid or spent sulfuric acid in concentration up to 65.25 percent. Browse special provision B84 N34 Aluminum construction materials are not authorized for any part of a packaging which is normally in contact with the hazardous material. Browse special provision N34 T20 Minimum test pressure (bar) 10 Minimum shell thickness 8 mm Pressure-relief requirements § 178.275(g)(3) Bottom opening requirements Prohibited Browse special provision T20 TP2 a. The maximum degree of filling must not exceed the degree of filling determined by the following: Where: tr is the maximum mean bulk temperature during transport, tf is the temperature in degrees celsius of the liquid during filling, and α is the mean coefficient of cubical expansion of the liquid between the mean temperature of the liquid during filling (tf) and the maximum mean bulk temperature during transportation (tr) both in degrees celsius. b. For liquids transported under ambient conditions α may be calculated using the formula: Where: d15 and d50 are the densities (in units of mass per unit volume) of the liquid at 15 °C (59 °F) and 50 °C (122 °F), respectively. Browse special provision TP2 TP12 This material is considered highly corrosive to steel. Browse special provision TP12 TP13 Self-contained breathing apparatus must be provided when this hazardous material is transported by sea. Browse special provision TP13
(8) Packing Authorizations (§173.***) (8A) Exceptions None (8B) Non-bulk 227 see 49 CFR §173.227 (8C) Bulk 244 see 49 CFR §173.244
(9) Quantity Limits (9A) Passenger aircraft/rail Forbidden (9B) Cargo aircraft only Forbidden
(10) Vessel stowage (10A) Location C Stowage category “C” means the material must be stowed “on deck only” on a cargo vessel or on a passenger vessel. Source: 49 CFR §172.101(k) (10B) Other 53 see 49 CFR §176.84 58 see 49 CFR §176.84 Source: 49 CFR §176.84

(3) Hazard Class 8 Corrosive liquids	(4) Identification number UN 1831	(5) Packing Group I Comparison View of PG
(6) Labels
(7) Special Provisions (§172.102) ×Note: Special provisions may be very complex. The extracts are taken from 49 CFR §172.102. Please be careful with the information, as necessary, additional conditions may be applied that are not written here. Please check the original source and report bugs. A7 Steel packagings must be corrosion-resistant or have protection against corrosion. Browse special provision A7 N34 Aluminum construction materials are not authorized for any part of a packaging which is normally in contact with the hazardous material. Browse special provision N34 T20 Minimum test pressure (bar) 10 Minimum shell thickness 8 mm Pressure-relief requirements § 178.275(g)(3) Bottom opening requirements Prohibited Browse special provision T20 TP2 a. The maximum degree of filling must not exceed the degree of filling determined by the following: Where: tr is the maximum mean bulk temperature during transport, tf is the temperature in degrees celsius of the liquid during filling, and α is the mean coefficient of cubical expansion of the liquid between the mean temperature of the liquid during filling (tf) and the maximum mean bulk temperature during transportation (tr) both in degrees celsius. b. For liquids transported under ambient conditions α may be calculated using the formula: Where: d15 and d50 are the densities (in units of mass per unit volume) of the liquid at 15 °C (59 °F) and 50 °C (122 °F), respectively. Browse special provision TP2 TP13 Self-contained breathing apparatus must be provided when this hazardous material is transported by sea. Browse special provision TP13
(8) Packing Authorizations (§173.***) (8A) Exceptions None (8B) Non-bulk 201 see 49 CFR §173.201 (8C) Bulk 243 see 49 CFR §173.243
(9) Quantity Limits (9A) Passenger aircraft/rail Forbidden (9B) Cargo aircraft only 2.5 L
(10) Vessel stowage (10A) Location C Stowage category “C” means the material must be stowed “on deck only” on a cargo vessel or on a passenger vessel. Source: 49 CFR §172.101(k) (10B) Other 14 see 49 CFR §176.84 40 see 49 CFR §176.84 53 see 49 CFR §176.84 58 see 49 CFR §176.84 Source: 49 CFR §176.84

Segregation chart for load, transport, and storage

This chart shows whether loading, transport, or storage with other hazard classes is permitted, prohibited, or restricted. Based on 49 CFR §177.848.

Note: In this segregation and separation chart are HazMat of hazard class 8 considered depending if there are liquid. Currently HazMat Tool is not able to to check if a HazMat is liquid or not. Therefore it is assumed as liquid. See PHMSA Interpretation #09-0252.

Add to my HazMat & segregation check & load inspector

Hazard class	8	7	6.1	5.2	5.1	4.3	4.2	4.1	3	2.3B	2.3A	2.2	2.1	1.6	1.5	1.4	1.3	1.1/1.2
1.1/1.2
1.3
1.4
1.5
1.6
2.1
2.2
2.3A
2.3B
3
4.1
4.2
4.3
5.1
5.2
6.1
7
8

	Must not be loaded, transported, or stored together in the same vehicle or facility.
	May be loaded, transported, or stored together.
	May be loaded, transported, or stored together only with restrictions.