HazMat Tool — substance information

Lithium hydroxide, solution

HMT 15 June 2026

UN / ID: UN 2679
Hazard class: 8
Packing group: II (multiple — see tabs)
ERG guide: ERG 154
Special provisions: SP B2, SP IB2, SP T7, SP TP2
Source: 49 CFR §172 (15 June 2026)

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Lithium hydroxide, solution

Lithium hydroxide is an inorganic compound with the formula LiOH. It can exist as anhydrous or hydrated, and both forms are white hygroscopic solids. They are soluble in water and slightly soluble in ethanol. Both are available commercially Wikipedia

Emergency Response Guide No. 154

Hazardous Materials Table

Source: 49 CFR §172 (15 June 2026)

Packing group II
Packing group III

(3) Hazard Class

8
Corrosive liquids

(4) Identification number

UN 2679

(5) Packing Group

Comparison View of PG

(6) Labels

(7) Special Provisions (§172.102)

×Note:
Special provisions may be very complex. The extracts are taken from 49 CFR §172.102. Please be careful with the information, as necessary, additional conditions may be applied that are not written here. Please check the original source and report bugs.

MC 300, MC 301, MC 302, MC 303, MC 305, and MC 306 and DOT 406 cargo tanks are not authorized.

Browse special provision B2

IB2

_{Authorized IBCs:} Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1).
_{Additional Requirement:} Only liquids with a vapor pressure less than or equal to 110 kPa at 50 °C (1.1 bar at 122 °F), or 130 kPa at 55 °C (1.3 bar at 131 °F) are authorized.

Browse special provision IB2

Minimum test pressure (bar)	4
Minimum shell thickness	§ 178.274(d)(2)
Pressure-relief requirements	Normal
Bottom opening requirements	§ 178.275(d)(3)

Browse special provision T7

TP2

a. The maximum degree of filling must not exceed the degree of filling determined by the following:
TP2a

Where:
t_r is the maximum mean bulk temperature during transport,
t_f is the temperature in degrees celsius of the liquid during filling, and
α is the mean coefficient of cubical expansion of the liquid between the mean temperature of the liquid during filling (t_f) and the maximum mean bulk temperature during transportation (t_r) both in degrees celsius.
b. For liquids transported under ambient conditions α may be calculated using the formula:
TP2b

Where:
d₁₅ and d₅₀ are the densities (in units of mass per unit volume) of the liquid at 15 °C (59 °F) and 50 °C (122 °F), respectively.

Browse special provision TP2

(8) Packing Authorizations (§173.***)

(8A) Exceptions	154	see 49 CFR §173.154
(8B) Non-bulk	202	see 49 CFR §173.202
(8C) Bulk	242	see 49 CFR §173.242

(9) Quantity Limits

(9A) Passenger aircraft/rail	1 L
(9B) Cargo aircraft only	30 L

(10) Vessel stowage

(10A) Location

Stowage category “A” means the material may be stowed “on deck” or “under deck” on a cargo vessel or on a passenger vessel.

Source: 49 CFR §172.101(k)

(10B) Other

29	see 49 CFR §176.84
52	see 49 CFR §176.84

Source: 49 CFR §176.84

(3) Hazard Class

8
Corrosive liquids

(4) Identification number

UN 2679

(5) Packing Group

III

Comparison View of PG

(6) Labels

(7) Special Provisions (§172.102)

IB3

_{Authorized IBCs:} Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1 and 31HA2, 31HB2, 31HN2, 31HD2 and 31HH2).
_{Additional Requirement:} Only liquids with a vapor pressure less than or equal to 110 kPa at 50 °C (1.1 bar at 122 °F), or 130 kPa at 55 °C (1.3 bar at 131 °F) are authorized, except for UN2672 (also see special provision IP8 in Table 2 for UN2672).

Browse special provision IB3

Minimum test pressure (bar)	2.65
Minimum shell thickness	§ 178.274(d)(2)
Pressure-relief requirements	Normal
Bottom opening requirements	§ 178.275(d)(3)

Browse special provision T4

TP2

a. The maximum degree of filling must not exceed the degree of filling determined by the following:
TP2a

Where:
d₁₅ and d₅₀ are the densities (in units of mass per unit volume) of the liquid at 15 °C (59 °F) and 50 °C (122 °F), respectively.

Browse special provision TP2

(8) Packing Authorizations (§173.***)

(8A) Exceptions	154	see 49 CFR §173.154
(8B) Non-bulk	203	see 49 CFR §173.203
(8C) Bulk	241	see 49 CFR §173.241

(9) Quantity Limits

(9A) Passenger aircraft/rail	5 L
(9B) Cargo aircraft only	60 L

(10) Vessel stowage

(10A) Location

Stowage category “A” means the material may be stowed “on deck” or “under deck” on a cargo vessel or on a passenger vessel.

Source: 49 CFR §172.101(k)

(10B) Other

29	see 49 CFR §176.84
52	see 49 CFR §176.84
96	see 49 CFR §176.84

Source: 49 CFR §176.84

Packing group comparison

Multiple packing groups apply to this entry. See assignment criteria in 49 CFR §173 Subpart D. Details are in the tabs above; differences are highlighted.

	PG II	PG III
1
2	Lithium hydroxide, solution	Lithium hydroxide, solution
3	8	8
4	UN 2679	UN 2679
5	II	III
6	8	8
7	B2, IB2, T7, TP2	IB3, T4, TP2
8A	154	154
8B	202	203
8C	242	241
9A	1 L	5 L
9B	30 L	60 L
10A	A	A
10B	29, 52	29, 52, 96

Segregation chart for load, transport, and storage

This chart shows whether loading, transport, or storage with other hazard classes is permitted, prohibited, or restricted. Based on 49 CFR §177.848.

Note: In this segregation and separation chart are HazMat of hazard class 8 considered depending if there are liquid. Currently HazMat Tool is not able to to check if a HazMat is liquid or not. Therefore it is assumed as liquid. See PHMSA Interpretation #09-0252.

Hazard class	8	7	6.1	5.2	5.1	4.3	4.2	4.1	3	2.3B	2.3A	2.2	2.1	1.6	1.5	1.4	1.3	1.1/1.2
1.1/1.2
1.3
1.4
1.5
1.6
2.1
2.2
2.3A
2.3B
3
4.1
4.2
4.3
5.1
5.2
6.1
7
8

	Must not be loaded, transported, or stored together in the same vehicle or facility.
	May be loaded, transported, or stored together.
	May be loaded, transported, or stored together only with restrictions.

Similar substances

UN / ID	Proper shipping name	Hazard class
UN 3536	Lithium batteries installed in cargo transport unit lithium ion batteries or lithium metal batteries	9
UN 3481	Lithium ion batteries contained in equipment including lithium ion polymer batteries	9
UN 3481	Lithium ion batteries packed with equipment including lithium ion polymer batteries	9
UN 3091	Lithium metal batteries contained in equipment including lithium alloy batteries	9
UN 3091	Lithium metal batteries packed with equipment including lithium alloy batteries	9
UN 3480	Lithium ion batteries including lithium ion polymer batteries	9
UN 1471	Lithium hypochlorite, dry or Lithium hypochlorite mixture	5.1
UN 3090	Lithium metal batteries including lithium alloy batteries	9
UN 1411	Lithium aluminum hydride, ethereal	4.3
UN 2805	Lithium hydride, fused solid	4.3
UN 1410	Lithium aluminum hydride	4.3
UN 1413	Lithium borohydride	4.3
UN 1414	Lithium hydride	4.3
UN 2680	Lithium hydroxide	8