Organometallic compound, liquid, toxic, n.o.s

Organometallic chemistry is the study of organometallic compounds, chemical compounds containing at least one chemical bond between a carbon atom of an organic molecule and a metal, including alkali, alkaline earth, and transition metals, and sometimes broadened to include metalloids like boron, silicon, and selenium, as well. Aside from bonds to organyl fragments or molecules, bonds to 'inorganic' carbon, like carbon monoxide (metal carbonyls), cyanide, or carbide, are generally considered to be organometallic as well. Some related compounds such as transition metal hydrides and metal phosphine complexes are often included in discussions of organometallic compounds, though strictly speaking, they are not necessarily organometallic. The related but distinct term "metalorganic compound" refers to metal-containing compounds lacking direct metal-carbon bonds but which contain organic ligands Wikipedia

Hazardous Materials Table

• Packing group I
• Packing group II
• Packing group III

(3) Hazard Class 6.1 Poisonous Material	(4) Identification number UN 3282	(5) Packing Group I Comparison View of PG
(6) Labels
(1) Symbols This entry is signed with "G". The letter "G" identifies proper shipping names for which one or more technical names of the hazardous material must be entered in parentheses, in association with the basic description. (See §172.203(k)). (7) Special Provisions (§172.102) ×Note: Special provisions may be very complex. The extracts are taken from 49 CFR §172.102. Please be careful with the information, as necessary, additional conditions may be applied that are not written here. Please check the original source and report bugs. T14 Minimum test pressure (bar) 6 Minimum shell thickness 6 mm Pressure-relief requirements § 178.275(g)(3) Bottom opening requirements Prohibited Browse special provision T14 TP2 a. The maximum degree of filling must not exceed the degree of filling determined by the following: Where: tr is the maximum mean bulk temperature during transport, tf is the temperature in degrees celsius of the liquid during filling, and α is the mean coefficient of cubical expansion of the liquid between the mean temperature of the liquid during filling (tf) and the maximum mean bulk temperature during transportation (tr) both in degrees celsius. b. For liquids transported under ambient conditions α may be calculated using the formula: Where: d15 and d50 are the densities (in units of mass per unit volume) of the liquid at 15 °C (59 °F) and 50 °C (122 °F), respectively. Browse special provision TP2 TP13 Self-contained breathing apparatus must be provided when this hazardous material is transported by sea. Browse special provision TP13 TP27 A portable tank having a minimum test pressure of 4 bar (400 kPa) may be used provided the calculated test pressure is 4 bar or less based on the MAWP of the hazardous material, as defined in § 178.275 of this subchapter, where the test pressure is 1.5 times the MAWP. Browse special provision TP27
(8) Packing Authorizations (§173.***) (8A) Exceptions None (8B) Non-bulk 201 see 49 CFR §173.201 (8C) Bulk 242 see 49 CFR §173.242
(9) Quantity Limits (9A) Passenger aircraft/rail 1 L (9B) Cargo aircraft only 30 L
(10) Vessel stowage (10A) Location B Stowage category “B” means (i) The material may be stowed “on deck” or “under deck” on a cargo vessel and on a passenger vessel carrying a number of passengers limited to not more than the larger of 25 passengers, or one passenger per each 3 m of overall vessel length; and (ii) “On deck only” on passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this section is exceeded. Source: 49 CFR §172.101(k) (10B) Other n/a

(3) Hazard Class 6.1 Poisonous Material	(4) Identification number UN 3282	(5) Packing Group II Comparison View of PG
(6) Labels
(1) Symbols This entry is signed with "G". The letter "G" identifies proper shipping names for which one or more technical names of the hazardous material must be entered in parentheses, in association with the basic description. (See §172.203(k)). (7) Special Provisions (§172.102) ×Note: Special provisions may be very complex. The extracts are taken from 49 CFR §172.102. Please be careful with the information, as necessary, additional conditions may be applied that are not written here. Please check the original source and report bugs. IB2 Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 °C (1.1 bar at 122 °F), or 130 kPa at 55 °C (1.3 bar at 131 °F) are authorized. Browse special provision IB2 T11 Minimum test pressure (bar) 6 Minimum shell thickness § 178.274(d)(2) Pressure-relief requirements Normal Bottom opening requirements § 178.275(d)(3) Browse special provision T11 TP2 a. The maximum degree of filling must not exceed the degree of filling determined by the following: Where: tr is the maximum mean bulk temperature during transport, tf is the temperature in degrees celsius of the liquid during filling, and α is the mean coefficient of cubical expansion of the liquid between the mean temperature of the liquid during filling (tf) and the maximum mean bulk temperature during transportation (tr) both in degrees celsius. b. For liquids transported under ambient conditions α may be calculated using the formula: Where: d15 and d50 are the densities (in units of mass per unit volume) of the liquid at 15 °C (59 °F) and 50 °C (122 °F), respectively. Browse special provision TP2 TP27 A portable tank having a minimum test pressure of 4 bar (400 kPa) may be used provided the calculated test pressure is 4 bar or less based on the MAWP of the hazardous material, as defined in § 178.275 of this subchapter, where the test pressure is 1.5 times the MAWP. Browse special provision TP27
(8) Packing Authorizations (§173.***) (8A) Exceptions 153 see 49 CFR §173.153 (8B) Non-bulk 202 see 49 CFR §173.202 (8C) Bulk 242 see 49 CFR §173.242
(9) Quantity Limits (9A) Passenger aircraft/rail 5 L (9B) Cargo aircraft only 60 L
(10) Vessel stowage (10A) Location B Stowage category “B” means (i) The material may be stowed “on deck” or “under deck” on a cargo vessel and on a passenger vessel carrying a number of passengers limited to not more than the larger of 25 passengers, or one passenger per each 3 m of overall vessel length; and (ii) “On deck only” on passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this section is exceeded. Source: 49 CFR §172.101(k) (10B) Other n/a

(3) Hazard Class 6.1 Poisonous Material	(4) Identification number UN 3282	(5) Packing Group III Comparison View of PG
(6) Labels
(1) Symbols This entry is signed with "G". The letter "G" identifies proper shipping names for which one or more technical names of the hazardous material must be entered in parentheses, in association with the basic description. (See §172.203(k)). (7) Special Provisions (§172.102) ×Note: Special provisions may be very complex. The extracts are taken from 49 CFR §172.102. Please be careful with the information, as necessary, additional conditions may be applied that are not written here. Please check the original source and report bugs. IB3 Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1 and 31HA2, 31HB2, 31HN2, 31HD2 and 31HH2). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 °C (1.1 bar at 122 °F), or 130 kPa at 55 °C (1.3 bar at 131 °F) are authorized, except for UN2672 (also see special provision IP8 in Table 2 for UN2672). Browse special provision IB3 T7 Minimum test pressure (bar) 4 Minimum shell thickness § 178.274(d)(2) Pressure-relief requirements Normal Bottom opening requirements § 178.275(d)(3) Browse special provision T7 TP1 The maximum degree of filling must not exceed the degree of filling determined by the following: Where: tr is the maximum mean bulk temperature during transport, and tf is the temperature in degrees celsius of the liquid during filling. Browse special provision TP1 TP28 A portable tank having a minimum test pressure of 2.65 bar (265 kPa) may be used provided the calculated test pressure is 2.65 bar or less based on the MAWP of the hazardous material, as defined in § 178.275 of this subchapter, where the test pressure is 1.5 times the MAWP. Browse special provision TP28
(8) Packing Authorizations (§173.***) (8A) Exceptions 153 see 49 CFR §173.153 (8B) Non-bulk 203 see 49 CFR §173.203 (8C) Bulk 241 see 49 CFR §173.241
(9) Quantity Limits (9A) Passenger aircraft/rail 60 L (9B) Cargo aircraft only 220 L
(10) Vessel stowage (10A) Location A Stowage category “A” means the material may be stowed “on deck” or “under deck” on a cargo vessel or on a passenger vessel. Source: 49 CFR §172.101(k) (10B) Other n/a