Hydrochloric acid

Hydrochloric acid, also known as muriatic acid or spirits of salt, is an aqueous solution of hydrogen chloride (HCl). It is a colorless solution with a distinctive pungent smell. It is classified as a strong acid. It is a component of the gastric acid in the digestive systems of most animal species, including humans. Wikipedia

Emergency Response Guide No. 157

Data from the Hazardous Materials Table

Source: 49 CFR §172 (2018/07)

Packing Group II
Packing Group III

(3) Hazard Class

8
Corrosive liquids

(4) Identification number

UN 1789

(5) Packing Group

Comparison View of PG

(6) Labels

(7) Special Provisions (§172.102)

×Note:
Special provisions may be very complex. The extracts are taken from 49 CFR §172.102. Please be careful with the information, as necessary, additional conditions may be applied that are not written here. Please check the original source and report bugs.

386	When transported by private motor carrier only, the following corrosive liquids may be packaged in polyethylene bottles with a capacity no greater than 3.785L (one gallon), further packed inside an open-top, heavy wall, high density polyethylene box (i.e., crate) in a manner that the polyethylene bottles are not subjected to any superimposed weight, and the boxes must be reasonably secured against movement within the transport vehicle and loaded so as to minimize the possibility of coming in contact with other lading: Compounds, cleaning liquid, NA1760, PG II or III; Corrosive liquid, acidic, inorganic, n.o.s., UN3264, PG II; Corrosive liquid, acidic, organic, n.o.s., UN3265, PG III; Corrosive liquid, basic, inorganic, n.o.s., UN3266, PG II; Hypochlorite solutions, UN1791, PG III; Hydrochloric acid solution, UN1789, PG II; and Sulfuric acid, UN2796, PG II. a. No more than four bottles, securely closed with threaded caps, may be packed in each box. b. Each empty bottle must have a minimum weight of not less than 140 grams and a minimum wall thickness of not less than 0.020 inch (0.508 mm). c. The completed package must meet the Packing Group II performance level, as applicable for combination packagings with a plastic box outer packaging, in accordance with subpart M of part 178 of this subchapter. (i) Tests must be performed on each type and size of bottle, for each manufacturing location. Samples taken at random must withstand the prescribed tests without breakage or leakage. (ii) One bottle for every two hours of production, or for every 2500 bottles produced, must be tested by dropping a bottle filled to 98% capacity with water from a height of 1.2 meters (3.9 feet) onto solid concrete directly on the closure. (iii) A copy of the test results must be kept on file at each facility where packagings are offered for transportation, and must be made available to a representative of the Department upon request. (iv) The name or symbol of the bottle producer, and the month and year of manufacture, must be marked by embossing, ink-jet printing of permanent ink, or other permanent means on the face or bottom of each bottle, in letters and numbers at least 6 mm (0.2 inch) high. Symbols, if used, must be registered with the Associate Administrator. (v) The box must be constructed from high-density polyethylene in the density range 0.950-0.962, and be capable of holding liquid when in the upright position. Browse special provision 386
A3	For combination packagings, if glass inner packagings (including ampoules) are used, they must be packed with absorbent material in tightly closed metal receptacles before packing in outer packagings. Browse special provision A3
A6	For combination packagings, if plastic inner packagings are used, they must be packed in tightly closed metal receptacles before packing in outer packagings. Browse special provision A6
B3	MC 300, MC 301, MC 302, MC 303, MC 305, and MC 306 and DOT 406 cargo tanks and DOT 57 portable tanks are not authorized. Browse special provision B3
B15	Packagings must be protected with non-metallic linings impervious to the lading or have a suitable corrosion allowance. Browse special provision B15
B133	Hydrochloric acid concentration not exceeding 38%, in Packing Group II, is authorized to be packaged in UN31H1 or UN31HH1 intermediate bulk containers when loaded in accordance with the requirements of Sec. 173.35(h) of this subchapter. Browse special provision B133
IB2	Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 [deg]C (1.1 bar at 122 [deg]F), or 130 kPa at 55 [deg]C (1.3 bar at 131 [deg]F) are authorized. Browse special provision IB2
N41	Metal construction materials are not authorized for any part of a packaging which is normally in contact with the hazardous material. Browse special provision N41
T8	see 49 CFR §172.102
TP2	a. The maximum degree of filling must not exceed the degree of filling determined by the following: Where: t_r is the maximum mean bulk temperature during transport, t_f is the temperature in degrees celsius of the liquid during filling, and α is the mean coefficient of cubical expansion of the liquid between the mean temperature of the liquid during filling (t_f) and the maximum mean bulk temperature during transportation (t_r) both in degrees celsius. b. For liquids transported under ambient conditions α may be calculated using the formula: Where: d₁₅ and d₅₀ are the densities (in units of mass per unit volume) of the liquid at 15 °C (59 °F) and 50 °C (122 °F), respectively. Browse special provision TP2

(8) Packing Authorizations (§173.***)

(8A) Exceptions	154	see 49 CFR §173.154
(8B) Non-bulk	202	see 49 CFR §173.202
(8C) Bulk	242	see 49 CFR §173.242

(9) Quantity Limits

(9A) Passenger aircraft/rail	1 L
(9B) Cargo aircraft only	30 L

(10) Vessel stowage

(10A) Location	C Stowage category “C” means the material must be stowed “on deck only” on a cargo vessel or on a passenger vessel. Source: 49 CFR §172.101(k)
(10B) Other	n/a

(3) Hazard Class

8
Corrosive liquids

(4) Identification number

UN 1789

(5) Packing Group

III

Comparison View of PG

(6) Labels

(7) Special Provisions (§172.102)

A3	For combination packagings, if glass inner packagings (including ampoules) are used, they must be packed with absorbent material in tightly closed metal receptacles before packing in outer packagings. Browse special provision A3
IB3	Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1 and 31HA2, 31HB2, 31HN2, 31HD2 and 31HH2). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 [deg]C (1.1 bar at 122 [deg]F), or 130 kPa at 55 [deg]C (1.3 bar at 131 [deg]F) are authorized, except for UN2672 (also see Special Provision IP8 for UN2672). Browse special provision IB3
T4	see 49 CFR §172.102
TP1	The maximum degree of filling must not exceed the degree of filling determined by the following: Where: t_r is the maximum mean bulk temperature during transport, and t_f is the temperature in degrees celsius of the liquid during filling. Browse special provision TP1

(8) Packing Authorizations (§173.***)

(8A) Exceptions	154	see 49 CFR §173.154
(8B) Non-bulk	203	see 49 CFR §173.203
(8C) Bulk	241	see 49 CFR §173.241

(9) Quantity Limits

(9A) Passenger aircraft/rail	5 L
(9B) Cargo aircraft only	60 L

(10) Vessel stowage

(10A) Location

Stowage category “C” means the material must be stowed “on deck only” on a cargo vessel or on a passenger vessel.

Source: 49 CFR §172.101(k)

(10B) Other

8	Glass carboys not permitted on passenger vessels.

Source: 49 CFR §176.84

Comparison View of Different Packing Groups

More than one packing group is indicated for this entry. Criteria for assignment see 49 CFR §173 Subpart D. You can find specific details in the tabs above. Differences are highlighted.

	PG II	PG III
1
2	Hydrochloric acid	Hydrochloric acid
3	8	8
4	UN 1789	UN 1789
5	II	III
6	8	8
7	386, A3, A6, B3, B15, B133, IB2, N41, T8, TP2	A3, IB3, T4, TP1
8A	154	154
8B	202	203
8C	242	241
9A	1 L	5 L
9B	30 L	60 L
10A	C	C
10B	n/a	8

Segregation Chart for Load, Transport, Storage

In this table a statement is contained for each hazard class whether the loading, transport or storage with other hazard classes is allowed, is not permitted or is restricted. The table is based on U.S.-Code 49 CFR §177.848.

Note: In this segregation and separation chart are HazMat of hazard class 8 considered depending if there are liquid. Currently HazMat Tool is not able to to check if a HazMat is liquid or not. Therefore it is assumed as liquid. See PHMSA Interpretation #09-0252.

Hazard Class	8	7	6.1	5.2	5.1	4.3	4.2	4.1	3	2.3B	2.3A	2.2	2.1	1.6	1.5	1.4	1.3	1.1/1.2
1.1/1.2
1.3
1.4
1.5
1.6
2.1
2.2
2.3A
2.3B
3
4.1
4.2
4.3
5.1
5.2
6.1
7
8

	May not be loaded, transported, or stored together in the same transport vehicle or storage facility.
	Load, transport, storage together is not restricted.
	Load, transport, storage together is allowed under restrictions.

Substances with similar name

UN-Number	Name	Hazard Class
UN 3410	4-Chloro-o-toluidine hydrochloride, solution	6.1
UN 1548	Aniline hydrochloride	6.1
UN 1789	Hydrochloric acid	8
	Muriatic acid, see Hydrochloric acid
UN 3444	Nicotine hydrochloride, solid	6.1
UN 1798	Nitrohydrochloric acid	8
	Nitromuriatic acid, see Nitrohydrochloric acid