HazMat Tool — substance information

Phosphorus trichloride

HMT May 2026
UN / ID
UN 1809
Hazard class
6.1
Packing group
I
ERG guide
ERG 137
Special provisions
SP 2, SP B9, SP B14, SP B15, SP B32, SP B77, SP N34, SP T20, more…
Source
49 CFR §172 (2026/05)

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Phosphorus trichloride


Phosphorus trichloride is an inorganic compound with the chemical formula PCl3. A colorless liquid when pure, it is an important industrial chemical, being used for the manufacture of phosphites and other organophosphorus compounds. It is toxic and reacts readily with water or air to release hydrogen chloride fumes. Wikipedia

Substance Data

Source: PubChem

CAS-Number

7719-12-2

Flash Point

n/a

Boiling Point

n/a

Emergency Response Guide No. 137

Hazardous Materials Table

Source: 49 CFR §172 (2026/05)

(3) Hazard Class

6.1
Poisonous Material

(4) Identification number Help

UN 1809

(5) Packing Group Help

I

(6) Labels Help

Poisonous liquids PG I Zone A (6.1) Corrosive liquids (8)

(7) Special Provisions (§172.102) Help

×Note:
Special provisions may be very complex. The extracts are taken from 49 CFR §172.102. Please be careful with the information, as necessary, additional conditions may be applied that are not written here. Please check the original source and report bugs.
2
B9
B14
B15
B32
B77
N34
T20
TP2
TP13
TP38
TP45

(8) Packing Authorizations (§173.***) Help

(8A) ExceptionsNone
(8B) Non-bulk227see 49 CFR §173.227
(8C) Bulk244see 49 CFR §173.244

(9) Quantity Limits Help

(9A) Passenger aircraft/railForbidden
(9B) Cargo aircraft onlyForbidden

(10) Vessel stowage Help

(10A) Location
(10B) Other

Segregation chart for load, transport, and storage

This chart shows whether loading, transport, or storage with other hazard classes is permitted, prohibited, or restricted. Based on 49 CFR §177.848.

Scope & sources (important)Click to show CFR references

This check evaluates segregation per 49 CFR §177.848. Additional loading/unloading and handling requirements may still apply; see 49 CFR §177 Subpart B (Loading and Unloading):

  • §177.834 - General requirements
  • §177.835 - Class 1 materials
  • §177.837 - Class 3 materials
  • §177.838 - Class 4 (flammable solid) materials, Class 5 (oxidizing) materials, and Division 4.2 (pyroforic liquid) materials
  • §177.839 - Class 8 (corrosive) materials
  • §177.840 - Class 2 (gases) materials
  • §177.841 - Division 6.1 and Division 2.3 materials
  • §177.842 - Class 7 (radioactive) material
  • §177.843 - Contamination of vehicles

Similar substances

UN / IDProper shipping nameHazard class
UN 1381Phosphorus, white dry or Phosphorus, white, under water or Phosphorus white, in solution or Phosphorus, yellow dry or Phosphorus, yellow, under water or Phosphorus, yellow, in solution4.2
NA 1955Organic phosphate, mixed with compressed gas or Organic phosphate compound, mixed with compressed gas or Organic phosphorus compound, mixed with compressed gas2.3
UN 3017Organophosphorus pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C6.1
UN 2784Organophosphorus pesticides, liquid, flammable, toxic, flash point less than 23 degrees C3
UN 0243Ammunition, incendiary, white phosphorus, with burster, expelling charge or propelling charge1.2H
UN 0244Ammunition, incendiary, white phosphorus, with burster, expelling charge or propelling charge1.3H
Ammunition, smoke (water-activated contrivances), without white phosphorus or phosphides, with burster, expelling charge or propelling charge, see Contrivances, water-activated, etc. (UN 0249)
UN 0245Ammunition smoke, white phosphorus with burster, expelling charge, or propelling charge1.2H
UN 0246Ammunition, smoke, white phosphorus with burster, expelling charge, or propelling charge1.3H
Ammunition, smoke (water-activated contrivances), white phosphorus, with burster, expelling charge or propelling charge, see Contrivances, water-activated, etc. (UN 0248)
Phosphorus (white or red) and a chlorate, mixtures ofForbidden
UN 1339Phosphorus heptasulfide, free from yellow or white phosphorus4.1
UN 1340Phosphorus pentasulfide, free from yellow or white phosphorus4.3
UN 1341Phosphorus sesquisulfide, free from yellow or white phosphorus4.1
UN 1343Phosphorus trisulfide, free from yellow or white phosphorus4.1