HazMat Tool — substance information

Sodium hydride

HMT May 2026
UN / ID
UN 1427
Hazard class
4.3
Packing group
I
ERG guide
ERG 138
Special provisions
SP A19, SP N40, SP W31
Source
49 CFR §172 (2026/05)

Spot an error in this entry?

Sodium hydride


Sodium hydride is the chemical compound with the empirical formula NaH. This alkali metal hydride is primarily used as a strong yet combustible base in organic synthesis. NaH is a saline (salt-like) hydride, composed of Na+ and H− ions, in contrast to molecular hydrides such as borane, silane, germane, ammonia, and methane. It is an ionic material that is insoluble in all solvents (other than molten sodium metal), consistent with the fact that H− ions do not exist in solution. Wikipedia

Substance Data

Source: PubChem

CAS-Number

7646-69-7

Flash Point

n/a

Boiling Point

n/a

Emergency Response Guide No. 138

Hazardous Materials Table

Source: 49 CFR §172 (2026/05)

(3) Hazard Class

4.3
Dangerous when wet materials

(4) Identification number Help

UN 1427

(5) Packing Group Help

I

(6) Labels Help

Dangerous when wet materials (4.3) Cargo Aircraft Only (Cargo Aircraft Only)

(7) Special Provisions (§172.102) Help

×Note:
Special provisions may be very complex. The extracts are taken from 49 CFR §172.102. Please be careful with the information, as necessary, additional conditions may be applied that are not written here. Please check the original source and report bugs.
A19
N40
W31

(8) Packing Authorizations (§173.***) Help

(8A) ExceptionsNone
(8B) Non-bulk211see 49 CFR §173.211
(8C) Bulk242see 49 CFR §173.242

(9) Quantity Limits Help

(9A) Passenger aircraft/railForbidden
(9B) Cargo aircraft only15 kg

(10) Vessel stowage Help

(10A) Location
(10B) Other

Segregation chart for load, transport, and storage

This chart shows whether loading, transport, or storage with other hazard classes is permitted, prohibited, or restricted. Based on 49 CFR §177.848.

Prohibited Must not be loaded, transported, or stored together in the same vehicle or facility.
Permitted May be loaded, transported, or stored together.
Restricted May be loaded, transported, or stored together only with restrictions.