Trimethyl borate

Trimethyl borate is the organoboron compound with the formula B(OCH3)3. It is a colourless liquid that burns with a green flame. It is an intermediate in the preparation of sodium borohydride and is a popular reagent in organic chemistry. It is a weak Lewis acid (AN = 23, Gutmann-Beckett method). Borate esters are prepared by heating boric acid or related boron oxides with alcohols under conditions where water is removed by azeotropic distillation. Wikipedia

Substance Data

Hazardous Materials Table

(3) Hazard Class 3 Flammable liquids	(4) Identification number UN 2416	(5) Packing Group II
(6) Labels
(7) Special Provisions (§172.102) ×Note: Special provisions may be very complex. The extracts are taken from 49 CFR §172.102. Please be careful with the information, as necessary, additional conditions may be applied that are not written here. Please check the original source and report bugs. IB2 Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 °C (1.1 bar at 122 °F), or 130 kPa at 55 °C (1.3 bar at 131 °F) are authorized. Browse special provision IB2 T7 Minimum test pressure (bar) 4 Minimum shell thickness § 178.274(d)(2) Pressure-relief requirements Normal Bottom opening requirements § 178.275(d)(3) Browse special provision T7 TP1 The maximum degree of filling must not exceed the degree of filling determined by the following: Where: tr is the maximum mean bulk temperature during transport, and tf is the temperature in degrees celsius of the liquid during filling. Browse special provision TP1
(8) Packing Authorizations (§173.***) (8A) Exceptions 150 see 49 CFR §173.150 (8B) Non-bulk 202 see 49 CFR §173.202 (8C) Bulk 242 see 49 CFR §173.242
(9) Quantity Limits (9A) Passenger aircraft/rail 5 L (9B) Cargo aircraft only 60 L
(10) Vessel stowage (10A) Location B Stowage category “B” means (i) The material may be stowed “on deck” or “under deck” on a cargo vessel and on a passenger vessel carrying a number of passengers limited to not more than the larger of 25 passengers, or one passenger per each 3 m of overall vessel length; and (ii) “On deck only” on passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this section is exceeded. Source: 49 CFR §172.101(k) (10B) Other n/a

Segregation chart for load, transport, and storage

This chart shows whether loading, transport, or storage with other hazard classes is permitted, prohibited, or restricted. Based on 49 CFR §177.848.

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Hazard class	8	7	6.1	5.2	5.1	4.3	4.2	4.1	3	2.3B	2.3A	2.2	2.1	1.6	1.5	1.4	1.3	1.1/1.2
1.1/1.2
1.3
1.4
1.5
1.6
2.1
2.2
2.3A
2.3B
3
4.1
4.2
4.3
5.1
5.2
6.1
7
8

	Must not be loaded, transported, or stored together in the same vehicle or facility.
	May be loaded, transported, or stored together.
	May be loaded, transported, or stored together only with restrictions.