Phenyl mercaptan
HMT 15 June 2026Phenyl mercaptan
Thiophenol is an organosulfur compound with the formula C6H5SH, sometimes abbreviated as PhSH. This foul-smelling colorless liquid is the simplest aromatic thiol. The chemical structures of thiophenol and its derivatives are analogous to phenols, where the oxygen atom in the hydroxyl group (−OH) bonded to the aromatic ring in phenol is replaced by a sulfur atom. The prefix thio- implies a sulfur-containing compound and when used before a root word name for a compound which would normally contain an oxygen atom, in the case of 'thiol' that the alcohol oxygen atom is replaced by a sulfur atom Wikipedia
Substance Data
Source: PubChem (HSDB, 22.10.2026)CAS-Number108-98-5 |
Flash Point50 ° C | Boiling Point169.1 ° C |
| Emergency Response Guide No. 131 |
Hazardous Materials Table
Source: 49 CFR §172 (15 June 2026)(3) Hazard class6.1Poisonous Material |
(4) Identification number |
(5) Packing Group |
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(6) Labels |
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(7) Special Provisions (§172.102)
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| 2 | |
|---|---|
| B9 | |
| B14 | |
| B32 | |
| B77 | |
| T20 | |
| TP2 | |
| TP13 | |
| TP38 | |
| TP45 |
(8) Packing Authorizations (§173.***) 
| (8A) Exceptions | None | |
|---|---|---|
| (8B) Non-bulk | 227 | see 49 CFR §173.227 |
| (8C) Bulk | 244 | see 49 CFR §173.244 |
(9) Quantity Limits 
| (9A) Passenger aircraft/rail | Forbidden |
|---|---|
| (9B) Cargo aircraft only | Forbidden |
(10) Vessel stowage 
| (10A) Location | |
|---|---|
| (10B) Other |
Segregation chart for load, transport, and storage
This chart shows whether loading, transport, or storage with other hazard classes is permitted, prohibited, or restricted. Based on 49 CFR §177.848.
Scope & sources (important)Click to show CFR references
This check evaluates segregation per 49 CFR §177.848. Additional loading/unloading and handling requirements may still apply; see 49 CFR §177 Subpart B (Loading and Unloading):
- §177.834 - General requirements
- §177.835 - Class 1 materials
- §177.837 - Class 3 materials
- §177.838 - Class 4 (flammable solid) materials, Class 5 (oxidizing) materials, and Division 4.2 (pyroforic liquid) materials
- §177.839 - Class 8 (corrosive) materials
- §177.840 - Class 2 (gases) materials
- §177.841 - Division 6.1 and Division 2.3 materials
- §177.842 - Class 7 (radioactive) material
- §177.843 - Contamination of vehicles

