HazMat Tool — substance information

Sulfur

HMT 15 June 2026

UN / ID: UN 1350
Hazard class: 4.1
Packing group: III
ERG guide: ERG 133
Special provisions: SP 30, SP B120, SP IB8, SP IP3, SP T1, SP TP33
Source: 49 CFR §172 (15 June 2026)

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Sulfur

Sulfur (American spelling and the preferred IUPAC name) or sulphur (Commonwealth spelling) is a chemical element; it has symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with the chemical formula S8. Elemental sulfur is a bright yellow, crystalline solid at room temperature. Sulfur is the tenth most abundant element by mass in the universe and the fifth most common on Earth Wikipedia

Emergency Response Guide No. 133

Hazardous Materials Table

Source: 49 CFR §172 (15 June 2026)

(3) Hazard Class

4.1
Flammable solids

(4) Identification number

UN 1350

(5) Packing Group

III

(6) Labels

(1) Symbols

This entry is signed with "I". The letter "I" identifies proper shipping names which are appropriate for describing materials in international transportation. An alternate proper shipping name may be selected when only domestic transportation is involved.

(7) Special Provisions (§172.102)

×Note:
Special provisions may be very complex. The extracts are taken from 49 CFR §172.102. Please be careful with the information, as necessary, additional conditions may be applied that are not written here. Please check the original source and report bugs.

Sulfur is not subject to the requirements of this subchapter if transported in a non-bulk packaging or if formed to a specific shape (for example, prills, granules, pellets, pastilles, or flakes). A bulk packaging containing sulfur is not subject to the placarding requirements of subpart F of this part, if it is marked with the appropriate identification number as required by subpart D of this part. Molten sulfur must be marked as required by § 172.325 of this subchapter.

Browse special provision 30

B120

The use of flexible bulk containers conforming to the requirements in subpart R and subpart S of part 178 of this subchapter is permitted.

Browse special provision B120

IB8

_{Authorized IBCs:} Metal (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B and 31N); Rigid plastics (11H1, 11H2, 21H1, 21H2, 31H1 and 31H2 ); Composite (11HZ1, 11HZ2, 21HZ1, 21HZ2 and 31HZ1); Fiberboard (11G); Wooden (11C, 11D and 11F); Flexible (13H1, 13H2, 13H3, 13H4, 13H5, 13L1, 13L2, 13L3, 13L4, 13M1 or 13M2).

Browse special provision IB8

IP3

Flexible IBCs must be sift-proof and water-resistant or must be fitted with a sift-proof and water-resistant liner.

Browse special provision IP3

Minimum test pressure (bar)	1.5
Minimum shell thickness	§ 178.274(d)(2)
Pressure-relief requirements	Normal
Bottom opening requirements	§ 178.275(d)(2)

Browse special provision T1

TP33

The portable tank instruction assigned for this substance applies for granular and powdered solids and for solids which are filled and discharged at temperatures above their melting point which are cooled and transported as a solid mass. Solid substances transported or offered for transport above their melting point are authorized for transportation in portable tanks conforming to the provisions of portable tank instruction T4 for solid substances of packing group III or T7 for solid substances of packing group II, unless a tank with more stringent requirements for minimum shell thickness, maximum allowable working pressure, pressure-relief devices or bottom outlets are assigned in which case the more stringent tank instruction and special provisions shall apply. Filling limits must be in accordance with portable tank special provision TP3. Solids meeting the definition of an elevated temperature material must be transported in accordance with the applicable requirements of this subchapter.

Browse special provision TP33

(8) Packing Authorizations (§173.***)

(8A) Exceptions	151	see 49 CFR §173.151
(8B) Non-bulk	None
(8C) Bulk	240	see 49 CFR §173.240

(9) Quantity Limits

(9A) Passenger aircraft/rail	25 kg
(9B) Cargo aircraft only	100 kg

(10) Vessel stowage

(10A) Location

Stowage category “A” means the material may be stowed “on deck” or “under deck” on a cargo vessel or on a passenger vessel.

Source: 49 CFR §172.101(k)

(10B) Other

25	see 49 CFR §176.84
74	see 49 CFR §176.84

Source: 49 CFR §176.84

Segregation chart for load, transport, and storage

This chart shows whether loading, transport, or storage with other hazard classes is permitted, prohibited, or restricted. Based on 49 CFR §177.848.

Hazard class	8	7	6.1	5.2	5.1	4.3	4.2	4.1	3	2.3B	2.3A	2.2	2.1	1.6	1.5	1.4	1.3	1.1/1.2
1.1/1.2
1.3
1.4
1.5
1.6
2.1
2.2
2.3A
2.3B
3
4.1
4.2
4.3
5.1
5.2
6.1
7
8

	Must not be loaded, transported, or stored together in the same vehicle or facility.
	May be loaded, transported, or stored together.
	May be loaded, transported, or stored together only with restrictions.

Similar substances

UN / ID	Proper shipping name	Hazard class
UN 2586	Alkyl sulfonic acids, liquid or Aryl sulfonic acids, liquid with not more than 5 percent free sulfuric acid	8
UN 2585	Alkyl sulfonic acids, solid or Aryl sulfonic acids, solid with not more than 5 percent free sulfuric acid	8
UN 2584	Alkyl sulfonic acids, liquid or Aryl sulfonic acids, liquid with more than 5 percent free sulfuric acid	8
UN 2583	Alkyl sulfonic acids, solid or Aryl sulfonic acids, solid, with more than 5 percent free sulfuric acid	8
UN 1831	Sulfuric acid, fuming with 30 percent or more free sulfur trioxide	8
UN 1831	Sulfuric acid, fuming with less than 30 percent free sulfur trioxide	8
UN 1830	Sulfuric acid with more than 51 percent acid	8
UN 2796	Sulfuric acid with not more than 51% acid	8
	Sulfur and chlorate, loose mixtures of	Forbidden
UN 1832	Sulfuric acid, spent	8
UN 1829	Sulfur trioxide, stabilized	8
UN 2448	Sulfur, molten	4.1
UN 1833	Sulfurous acid	8
UN 1834	Sulfuryl chloride	6.1
UN 2191	Sulfuryl fluoride	2.3