Ammonia, anhydrous

This material is poisonous by inhalation (see §171.8) in Hazard Zone D (see §173.116), and must be described as an inhalation hazard under the provisions of this subchapter.

Browse special provision 4

When offered for transport by highway, rail, or cargo vessel, anhydrous ammonia adsorbed or absorbed on a solid contained in ammonia dispensing systems or receptacles intended to form part of such systems is not subject to the requirements of this subchapter if the following conditions in this provision are met. In addition to meeting the conditions in this provision, transport on cargo aircraft only may be authorized with prior approval of the Associate Administrator.
a. The adsorption or absorption presents the following properties:
(1) The pressure at a temperature of 20 °C (68 °F) in the receptacle is less than 0.6 bar (60 kPa);
(2) The pressure at a temperature of 35 °C (95 °F) in the receptacle is less than 1 bar (100 kPa);
(3) The pressure at a temperature of 85 °C (185 °F) in the receptacle is less than 12 bar (1200 kPa).
b. The adsorbent or absorbent material shall not meet the definition or criteria for inclusion in Classes 1 to 8;
c. The maximum contents of a receptacle shall be 10 kg of ammonia; and
d. Receptacles containing adsorbed or absorbed ammonia shall meet the following conditions:
(1) Receptacles shall be made of a material compatible with ammonia as specified in ISO 11114-1:2012(E) and ISO 11114-1:2012/Amd 1:2017(E) (IBR, see §171.7);
(2) Receptacles and their means of closure shall be hermetically sealed and able to contain the generated ammonia;
(3) Each receptacle shall be able to withstand the pressure generated at 85 °C (185 °F) with a volumetric expansion no greater than 0.1%;
(4) Each receptacle shall be fitted with a device that allows for gas evacuation once pressure exceeds 15 bar (1500 kPa) without violent rupture, explosion or projection; and
(5) Each receptacle shall be able to withstand a pressure of 20 bar (2000 kPa) without leakage when the pressure relief device is deactivated.
e. When offered for transport in an ammonia dispenser, the receptacles shall be connected to the dispenser in such a way that the assembly is guaranteed to have the same strength as a single receptacle.
f. The properties of mechanical strength mentioned in this special provision shall be tested using a prototype of a receptacle and/or dispenser filled to nominal capacity, by increasing the temperature until the specified pressures are reached.
g. The test results shall be documented, shall be traceable, and shall be made available to a representative of the Department upon request.

Browse special provision 379

The use of copper valves on UN pressure receptacles is prohibited.

Browse special provision N87

When portable tank instruction T50 is indicated in Column (7) of the §172.101 Hazardous Materials Table, the applicable liquefied compressed gas and chemical under pressure descriptions are authorized to be transported in portable tanks in accordance with the requirements of §173.313.

Browse special provision T50

D

Stowage category “D” means the material must be stowed “on deck only” on a cargo vessel or on a passenger vessel carrying a number of passengers limited to not more than the larger of 25 passengers or one passenger per each 3 m of overall vessel length, but the material is prohibited on a passenger vessel in which the limiting number of passengers is exceeded.

Source: 49 CFR §172.101(k)

The words “Inhalation Hazard” shall be entered on each shipping paper in association with the shipping description, shall be marked on each non-bulk package in association with the proper shipping name and identification number, and shall be marked on two opposing sides of each bulk package. Size of marking on bulk package must conform to §172.302. The requirements of §172.203 and §172.505 do not apply.

Browse special provision 13

When offered for transport by highway, rail, or cargo vessel, anhydrous ammonia adsorbed or absorbed on a solid contained in ammonia dispensing systems or receptacles intended to form part of such systems is not subject to the requirements of this subchapter if the following conditions in this provision are met. In addition to meeting the conditions in this provision, transport on cargo aircraft only may be authorized with prior approval of the Associate Administrator.
a. The adsorption or absorption presents the following properties:
(1) The pressure at a temperature of 20 °C (68 °F) in the receptacle is less than 0.6 bar (60 kPa);
(2) The pressure at a temperature of 35 °C (95 °F) in the receptacle is less than 1 bar (100 kPa);
(3) The pressure at a temperature of 85 °C (185 °F) in the receptacle is less than 12 bar (1200 kPa).
b. The adsorbent or absorbent material shall not meet the definition or criteria for inclusion in Classes 1 to 8;
c. The maximum contents of a receptacle shall be 10 kg of ammonia; and
d. Receptacles containing adsorbed or absorbed ammonia shall meet the following conditions:
(1) Receptacles shall be made of a material compatible with ammonia as specified in ISO 11114-1:2012(E) and ISO 11114-1:2012/Amd 1:2017(E) (IBR, see §171.7);
(2) Receptacles and their means of closure shall be hermetically sealed and able to contain the generated ammonia;
(3) Each receptacle shall be able to withstand the pressure generated at 85 °C (185 °F) with a volumetric expansion no greater than 0.1%;
(4) Each receptacle shall be fitted with a device that allows for gas evacuation once pressure exceeds 15 bar (1500 kPa) without violent rupture, explosion or projection; and
(5) Each receptacle shall be able to withstand a pressure of 20 bar (2000 kPa) without leakage when the pressure relief device is deactivated.
e. When offered for transport in an ammonia dispenser, the receptacles shall be connected to the dispenser in such a way that the assembly is guaranteed to have the same strength as a single receptacle.
f. The properties of mechanical strength mentioned in this special provision shall be tested using a prototype of a receptacle and/or dispenser filled to nominal capacity, by increasing the temperature until the specified pressures are reached.
g. The test results shall be documented, shall be traceable, and shall be made available to a representative of the Department upon request.

Browse special provision 379

When portable tank instruction T50 is indicated in Column (7) of the §172.101 Hazardous Materials Table, the applicable liquefied compressed gas and chemical under pressure descriptions are authorized to be transported in portable tanks in accordance with the requirements of §173.313.

Browse special provision T50

D

Stowage category “D” means the material must be stowed “on deck only” on a cargo vessel or on a passenger vessel carrying a number of passengers limited to not more than the larger of 25 passengers or one passenger per each 3 m of overall vessel length, but the material is prohibited on a passenger vessel in which the limiting number of passengers is exceeded.

Source: 49 CFR §172.101(k)